Metal carbide/carbon composite body having porous structure by three-dimensional connection of core-shell unit particles, preparation method thereof, and use of the composite body
    8.
    发明授权
    Metal carbide/carbon composite body having porous structure by three-dimensional connection of core-shell unit particles, preparation method thereof, and use of the composite body 有权
    具有通过核 - 壳单元颗粒的三维连接的多孔结构的金属碳化物/碳复合体,其制备方法和复合体的使用

    公开(公告)号:US09517452B2

    公开(公告)日:2016-12-13

    申请号:US14839320

    申请日:2015-08-28

    摘要: The present invention relates to a metal carbide/carbon composite body having a porous structure, in which core-shell unit particles are three-dimensionally connected, a preparation method thereof, and the use of the composite body. More specifically, the present invention provides a metal carbide/carbon composite body, a preparation method thereof, and the use of the composite body, wherein the composite body is formed by high-temperature calcination of a metal oxalate hydrate body under a carbon monoxide-containing gas atmosphere, wherein the metal carbide/carbon composite body has a porous structure in which core-shell unit particles are three-dimensionally connected, wherein the core-shell unit particles comprise a metal carbide core formed by thermal decomposition of a metal oxalate hydrate; and a graphitic carbon shell, the product resulting from Boudouard reaction of carbon monoxide, formed on the metal carbide core.

    摘要翻译: 本发明涉及具有多孔结构的金属碳化物/碳复合体,其中核 - 壳单元颗粒是三维连接的,其制备方法以及复合体的用途。 更具体地说,本发明提供了一种金属碳化物/碳复合体,其制备方法和复合体的用途,其中复合体是通过在一氧化碳一氧化碳气氛下高温煅烧草酸金属水合物体而形成的, 其中所述金属碳化物/碳复合体具有其中核 - 壳单元颗粒是三维连接的多孔结构,其中所述核 - 壳单元颗粒包含通过草酸金属氢氧化物的热分解形成的金属碳化物核心 ; 和石墨碳壳,由金属碳化物芯上形成的一氧化碳的Boudouard反应产生的产物。