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19 条记录 (耗时 0.021 秒)

    Metal carbide/carbon composite body having porous structure by three-dimensional connection of core-shell unit particles, preparation method thereof, and use of the composite body
    3.
    发明授权
    Metal carbide/carbon composite body having porous structure by three-dimensional connection of core-shell unit particles, preparation method thereof, and use of the composite body 有权
    具有通过核 - 壳单元颗粒的三维连接的多孔结构的金属碳化物/碳复合体，其制备方法和复合体的使用

    公开(公告)号：US09517452B2

    公开(公告)日：2016-12-13

    申请号：US14839320

    申请日：2015-08-28

    申请人： Korea Institute of Energy Research

    发明人： Ji Chan Park ,  Heon Jung ,  Ho Tae Lee ,  Jung Il Yang ,  Dong Hyun Chun ,  Sung Jun Hong ,  Seok Yong Hong

    IPC分类号： B01J27/22 ,  B01J37/03 ,  B01J37/08 ,  B01J37/10 ,  B01J35/00 ,  C10G2/00

    CPC分类号： B01J27/22 ,  B01J35/0013 ,  B01J37/031 ,  B01J37/08 ,  B01J37/082 ,  B01J37/10 ,  C10G2/332

    摘要： The present invention relates to a metal carbide/carbon composite body having a porous structure, in which core-shell unit particles are three-dimensionally connected, a preparation method thereof, and the use of the composite body. More specifically, the present invention provides a metal carbide/carbon composite body, a preparation method thereof, and the use of the composite body, wherein the composite body is formed by high-temperature calcination of a metal oxalate hydrate body under a carbon monoxide-containing gas atmosphere, wherein the metal carbide/carbon composite body has a porous structure in which core-shell unit particles are three-dimensionally connected, wherein the core-shell unit particles comprise a metal carbide core formed by thermal decomposition of a metal oxalate hydrate; and a graphitic carbon shell, the product resulting from Boudouard reaction of carbon monoxide, formed on the metal carbide core.

    摘要翻译： 本发明涉及具有多孔结构的金属碳化物/碳复合体，其中核 - 壳单元颗粒是三维连接的，其制备方法以及复合体的用途。 更具体地说，本发明提供了一种金属碳化物/碳复合体，其制备方法和复合体的用途，其中复合体是通过在一氧化碳一氧化碳气氛下高温煅烧草酸金属水合物体而形成的， 其中所述金属碳化物/碳复合体具有其中核 - 壳单元颗粒是三维连接的多孔结构，其中所述核 - 壳单元颗粒包含通过草酸金属氢氧化物的热分解形成的金属碳化物核心 ; 和石墨碳壳，由金属碳化物芯上形成的一氧化碳的Boudouard反应产生的产物。

    Method of manufacturing iron-base catalysts and methods of manufacturing hydrocarbons using iron-base catalysts made by the method
    5.
    发明授权
    Method of manufacturing iron-base catalysts and methods of manufacturing hydrocarbons using iron-base catalysts made by the method 有权

    公开(公告)号：US10508243B2

    公开(公告)日：2019-12-17

    申请号：US15568538

    申请日：2016-04-22

    申请人： KOREA INSTITUTE OF ENERGY RESEARCH

    发明人： Dong Hyun Chun ,  Heon Jung ,  Sung Jun Hong ,  Ji Chan Park ,  Ho Tae Lee ,  Jung Il Yang

    IPC分类号： B01J23/94 ,  B01J37/08 ,  C10G2/00 ,  B01J37/03 ,  B01J23/745 ,  B01J8/22 ,  B01J21/08 ,  B01J37/02 ,  B01J37/04

    摘要： The present invention relates to a method for producing liquid or solid hydrocarbons from a synthesis gas via Fischer-Tropsch synthesis which does not carry out a separate reduction pre-treatment for catalyst activation. The method for producing liquid or solid hydrocarbons from a synthesis gas using Fischer-Tropsch synthesis according to the present invention comprises: a first step of applying an iron-based catalyst for the Fischer-Tropsch synthesis in which the number of iron atoms in the ferrihydrite phase fraction equals 10 to 100% and the number of iron atoms in the hematite phase fraction equals 0 to 90%, with respect to 100% of the number of the number of iron atoms, to a Fischer-Tropsch synthesis reactor; and a second step of activating the catalyst for the Fischer-Tropsch synthesis by a synthesis gas which is a reactant under the conditions of the Fischer-Tropsch synthesis and carrying out the Fischer-Tropsch synthesis by means of the activated catalyst for the Fischer-Tropsch synthesis. As such, the present invention is capable of efficiently producing liquid or solid hydrocarbons from a synthesis gas via Fischer-Tropsch synthesis, even without a separate reduction pre-treatment.

    Method of preparing iron carbide/carbon nanocomposite catalyst containing potassium for high temperature fischer-tropsch synthesis reaction and the iron carbide/carbon nanocomposite catalyst prepared thereby, and method of manufacturing liquid hydrocarbon using the same and liquid hydrocarbon manufactured thereby
    8.
    发明授权
    Method of preparing iron carbide/carbon nanocomposite catalyst containing potassium for high temperature fischer-tropsch synthesis reaction and the iron carbide/carbon nanocomposite catalyst prepared thereby, and method of manufacturing liquid hydrocarbon using the same and liquid hydrocarbon manufactured thereby 有权
    制备用于高温费 - 托合成反应的含有碳的碳化铁/碳纳米复合催化剂的方法和由此制备的碳化铁/碳纳米复合催化剂的方法以及由此制备的液体烃的方法

    公开(公告)号：US09533292B2

    公开(公告)日：2017-01-03

    申请号：US14099083

    申请日：2013-12-06

    申请人： KOREA INSTITUTE OF ENERGY RESEARCH

    发明人： Ji Chan Park ,  Heon Jung ,  Ho Tae Lee ,  Jung Il Yang ,  Dong Hyun Chun ,  Sung Jun Hong

    IPC分类号： B01J21/18 ,  B01J27/22 ,  B01J33/00 ,  B01J35/00 ,  B01J37/00 ,  B01J37/08 ,  C10G2/00

    CPC分类号： B01J27/22 ,  B01J21/18 ,  B01J33/00 ,  B01J35/002 ,  B01J37/0036 ,  B01J37/08 ,  C10G2/332

    摘要： This invention relates to a method of preparing an iron carbide/carbon nanocomposite catalyst containing potassium for high temperature Fischer-Tropsch (FT) synthesis reaction and the iron carbide/carbon nanocomposite catalyst prepared thereby, and a method of manufacturing a liquid hydrocarbon using the same and a liquid hydrocarbon manufactured thereby, wherein a porous carbon support is uniformly impregnated with an iron hydrate using melt infiltration, and potassium is also supported together via various addition processes, including a pre-addition process of a potassium salt which is ground upon impregnation with the iron hydrate, or a mid- or post-addition process of a potassium solution using incipient wetness impregnation after impregnation with the iron hydrate. Accordingly, the highly active iron carbide/potassium/carbon composite catalyst for high temperature FT reaction in which 5˜30 wt % of active iron carbide particles are supported on the porous carbon support can be obtained and is structurally stable to heat even in high temperature FT reaction of 300° C. or more, and liquid hydrocarbons can be selectively obtained at high yields.

    摘要翻译： 本发明涉及一种制备含有用于高温费 - 托（FT）合成反应的钾的碳化铁/碳纳米复合催化剂和由其制备的碳化铁/碳纳米复合催化剂的方法，以及使用其制备液体烃的方法 以及由此制造的液体烃，其中多孔碳载体用熔融浸渍的铁水合物均匀地浸渍，并且钾也通过各种添加方法负载在一起，包括在浸渍后研磨的钾盐的预加工过程 铁水合物，或在用铁水合物浸渍之后使用初始湿浸渍的钾溶液的中或后添加方法。 因此，可以得到在多孔碳载体上负载有活性碳化铁颗粒5〜30重量％的高温FT反应的高活性碳化铁/钾/碳复合催化剂，即使在高温下也具有结构稳定的热稳定性 300℃以上的FT反应可以以高收率有选择地获得。