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公开(公告)号：US06503866B1
公开(公告)日：2003-01-07
申请号：US09754677
申请日：2001-01-04
IPC分类号： B01J2356
CPC分类号： C10G35/09 , B01J21/04 , B01J23/40 , B01J23/62 , B01J23/63 , B01J35/002 , B01J35/1019 , B01J37/08
摘要： A process for preparing a catalyst, the catalyst itself, and a process for using the catalyst are disclosed generally for the conversion of hydrocarbons. By the use of at least one high temperature calcination under substantially dry conditions, a catalyst with a beneficial combination of lowered surface area and excellent piece crush is created. X-ray diffraction pattern information is used to distinguish the resulting product.
摘要翻译： 通常用于制备催化剂的方法，催化剂本身以及使用该催化剂的方法用于烃的转化。 通过在基本上干燥的条件下使用至少一种高温煅烧，产生具有降低的表面积和优异的碎片粉碎的有利组合的催化剂。 使用X射线衍射图案信息来区分所得到的产品。
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公开(公告)号：US06514904B1
公开(公告)日：2003-02-04
申请号：US10154059
申请日：2002-05-22
IPC分类号： B01J2300
CPC分类号： B01J21/04 , B01J23/40 , B01J23/62 , B01J23/63 , B01J35/002 , B01J35/0026 , B01J35/1019 , B01J37/08 , C10G35/09
摘要： A catalyst and a process for using the catalyst are disclosed generally for the conversion of hydrocarbons. By the use of at least one high temperature calcination under dry conditions, a catalyst with a beneficial combination of lowered surface area and excellent piece crush is created. X-ray diffraction pattern information is used to distinguish the resulting product.
摘要翻译： 通常用于转化烃的催化剂和使用该催化剂的方法。 通过在干燥条件下使用至少一次高温煅烧，产生具有降低的表面积和优异的碎片粉碎的有益组合的催化剂。 使用X射线衍射图案信息来区分所得到的产品。
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3.发明申请公开(公告)号：US20090321313A1
公开(公告)日：2009-12-31
申请号：US12165168
申请日：2008-06-30
IPC分类号： C10G47/36
CPC分类号： C10G47/36 , C10G47/04 , C10G47/26 , C10G2300/708
摘要： A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The slurry hydrocracking reaction can be controlled by measuring the production of mesophase using X-ray diffraction. Upon a mesophase yield fraction reaching a predetermined level, reaction conditions should be moderated to avoid excessive coke production.
摘要翻译： 公开了用于将重质烃进料转化为较轻质烃产品的方法和装置。 重烃进料用包含氧化铁和氧化铝的催化剂进行浆化以形成重质烃浆料并加氢裂化以产生较轻质的烃。 可以通过使用X射线衍射测量中间相的产生来控制浆料加氢裂化反应。 当中间相产率达到预定水平时，应当调节反应条件以避免过度的焦炭生成。
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公开(公告)号：US09732284B2
公开(公告)日：2017-08-15
申请号：US13329874
申请日：2011-12-19
CPC分类号： C10G47/36 , C10G47/04 , C10G47/26 , C10G2300/708
摘要： A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The slurry hydrocracking reaction can be controlled by measuring the production of mesophase using X-ray diffraction. Upon a mesophase yield fraction reaching a predetermined level, reaction conditions should be moderated to avoid excessive coke production.
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5.发明申请公开(公告)号：US20120085680A1
公开(公告)日：2012-04-12
申请号：US13329874
申请日：2011-12-19
IPC分类号： C10G47/36
CPC分类号： C10G47/36 , C10G47/04 , C10G47/26 , C10G2300/708
摘要： A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The slurry hydrocracking reaction can be controlled by measuring the production of mesophase using X-ray diffraction. Upon a mesophase yield fraction reaching a predetermined level, reaction conditions should be moderated to avoid excessive coke production.
摘要翻译： 公开了用于将重质烃进料转化为较轻质烃产品的方法和装置。 重烃进料用包含氧化铁和氧化铝的催化剂进行浆化以形成重质烃浆料并加氢裂化以产生较轻质的烃。 可以通过使用X射线衍射测量中间相的产生来控制浆料加氢裂化反应。 当中间相产率达到预定水平时，应当调节反应条件以避免过度的焦炭生成。
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公开(公告)号：US06806093B2
公开(公告)日：2004-10-19
申请号：US09969670
申请日：2001-10-03
申请人： Rune Wendelbo , Duncan E. Akporiaye , Ivar M. Dahl , Arne Karlsson , Gregory J. Lewis , David S. Bem , Andrzej Z. Ringwelski , Richard C. Murray, Jr. , Cheryl M. Surman
发明人： Rune Wendelbo , Duncan E. Akporiaye , Ivar M. Dahl , Arne Karlsson , Gregory J. Lewis , David S. Bem , Andrzej Z. Ringwelski , Richard C. Murray, Jr. , Cheryl M. Surman
IPC分类号： B01L300
CPC分类号： B01L3/50255 , B01J19/0046 , B01J2219/00313 , B01J2219/00333 , B01J2219/00351 , B01J2219/00585 , B01J2219/00659 , B01J2219/00702 , B01J2219/00707 , B01J2219/00745 , B01J2219/00747 , B01J2219/00756 , B01L3/0289 , B01L3/5085 , B01L2200/0657 , B01L2300/0829 , B02C2017/065 , C40B30/08 , C40B40/18 , C40B60/14 , G01N23/20 , G01N23/20025 , Y10T436/25
摘要： An apparatus and process for forming an array of powder samples arranged in predefined locations where all samples have a flat surface in a common plane has been developed. A monolithic block having a main support section having at least N perforations from a first surface of the main support through a second surface of the main support in predefined locations, where N is the number of samples in the array is provided. The monolithic block also has a flat support section covering the perforations of the main support section. All N samples are loaded simultaneously with sample X in perforation X of the main support where X is an integer from 1 to N. A flat surface of each sample where the flat surfaces are a common plane is formed by forcing the samples within the perforations against the flat support. The samples are retained in position within the perforations against the flat support, and are made ready for analysis since the flat surfaces of the samples are in predefined locations and are all in a common plane.
摘要翻译： 已经开发了用于形成布置在所有样品在共同平面中具有平坦表面的预定位置的粉末样品阵列的装置和方法。 具有主支撑部分的单块块，其具有至少N个穿过主支撑件的第一表面穿过主支撑件的第二表面的预定位置，其中N是阵列中的样本数量。 整体式块体还具有覆盖主支撑部分的穿孔的平坦支撑部分。 所有N个样品与主支架的穿孔X中的样品X同时加载，其中X是从1到N的整数。平坦表面是共同平面的每个样品的平坦表面是通过迫使穿孔中的样品抵抗 平坦的支持。 样品保持在穿孔内的位置上抵抗平坦支撑，并且准备好进行分析，因为样品的平坦表面在预定位置并且都在共同的平面中。
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公开(公告)号：US5059737A
公开(公告)日：1991-10-22
申请号：US546971
申请日：1990-07-02
IPC分类号： B01J27/16 , B01J27/182 , B01J29/82 , B01J29/85 , C07C2/18
CPC分类号： B01J27/16 , B01J29/82 , B01J29/85 , C07C2/18 , B01J2229/36 , B01J27/182 , C07C2527/173
摘要： A hydrocarbon conversion process which utilizes a solid phosphoric acid catalyst having a total X-ray intensity of at least 40 percent relative to alpha-alumina. The solid phosphoric acid catalyst is produced by crystallizing an amorphous mixture of an acid oxide of phosphorus and a siliceous material at a temperature of from 350.degree. to 450.degree. C. and in the presence of from 10 to 50 mole percent water vapor based upon the total vapor rate to the crystallizing means. Embodiments of the new hydrocarbon conversion process include alkylation, oligomerization, and hydration, of hydrocarbons and oxygenated hydrocarbons.
摘要翻译： 烃转化方法，其使用相对于α-氧化铝具有至少40％的总X射线强度的固体磷酸催化剂。 固体磷酸催化剂是通过在350-450℃的温度下和在10-50摩尔％水蒸气存在下，将磷和二氧化硅材料的无定形混合物结晶在基于 与结晶装置的总蒸气速率。 新的烃转化方法的实施方案包括烃和氧化烃的烷基化，低聚和水合。
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公开(公告)号：US4946815A
公开(公告)日：1990-08-07
申请号：US288921
申请日：1988-12-23
IPC分类号： B01J20060101 , B01J27/16 , B01J27/182 , B01J29/82 , B01J29/85 , B01J37/10 , C07C20060101 , C07C2/18 , C07C2/70 , C07C11/02 , C07C15/02 , C10G45/32 , C10G45/46
CPC分类号： B01J27/16 , B01J29/82 , B01J29/85 , C07C2/18 , B01J2229/36 , B01J27/182 , C07C2527/173 , Y02P20/584
摘要： A solid phosphoric acid catalyst having a total X-ray intensity of at least 30 percent relative to alpha-alumina. The solid phosphoric acid catalyst is produced by crystallizing an amorphous mixture of an acid oxide of phosphorus and a siliceous material at a temperature of from 250.degree. to 450.degree. C. and in the presence of from 3 to 50 mole percent water vapor based upon the total vapor rate to the crystallizing means.
摘要翻译： 相对于α-氧化铝，其总X射线强度为至少30％的固体磷酸催化剂。 固体磷酸催化剂是通过在250-450℃的温度和3至50摩尔％的水蒸气存在下，将磷酸和氧化硅材料的无定形混合物结晶在基于 与结晶装置的总蒸气速率。
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9.发明申请Molecular sieves with high selectivity towards light olefins in methanol to olefin conversion 审中-公开分子筛对甲醇中的轻质烯烃具有高选择性至烯烃转化率公开(公告)号：US20070059236A1
公开(公告)日：2007-03-15
申请号：US11222619
申请日：2005-09-09
申请人： Robert W. Broach , Mary A. Vanek , Andrzej Z. Ringwelski , Stephen T. Wilson , Raelynn M. Miller , John Q. Chen
发明人： Robert W. Broach , Mary A. Vanek , Andrzej Z. Ringwelski , Stephen T. Wilson , Raelynn M. Miller , John Q. Chen
IPC分类号： B01J27/182 , C01B39/00
CPC分类号： C10G3/49 , B01J29/85 , C07C1/20 , C07C2529/85 , C10G2400/20 , Y02P30/42 , C07C11/02
摘要： A catalyst for the use in methanol to olefin conversion is identified, and a process for identifying the structure of the catalyst is presented, which is used to determine the quality of the catalyst for its selectivity for producing high light olefins yield.
摘要翻译： 鉴定了用于甲醇至烯烃转化的催化剂，并且提出了用于鉴定催化剂结构的方法，其用于确定催化剂的质量，以获得其产生高轻质烯烃产率的选择性。
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10.发明授权Lithium aluminate layered catalyst and a selective oxidation process using the catalyst 失效铝酸锂层状催化剂和使用该催化剂的选择性氧化方法公开(公告)号：US06858769B2
公开(公告)日：2005-02-22
申请号：US10274693
申请日：2002-10-18
IPC分类号： B01D53/86 , B01J21/04 , B01J23/00 , B01J23/58 , B01J23/60 , B01J23/62 , B01J23/63 , B01J23/644 , B01J23/656 , B01J35/00 , B01J35/02 , B01J35/08 , B01J37/00 , B01J37/02 , C01B5/00 , C07C5/48 , C10G29/20 , C10G45/00 , C10G45/62 , C07C5/42 , C07C5/333 , C10G47/10 , C10G47/14
CPC分类号： C10G45/62 , B01D53/86 , B01J21/04 , B01J23/005 , B01J23/58 , B01J23/60 , B01J23/62 , B01J23/626 , B01J23/63 , B01J23/6447 , B01J23/6567 , B01J35/0006 , B01J35/023 , B01J35/08 , B01J37/0009 , B01J37/0219 , B01J37/0221 , B01J37/0223 , B01J37/0236 , B01J37/024 , B01J37/0242 , B01J37/0248 , C01B5/00 , C07C5/48 , C10G29/205 , C10G45/00 , C10G2300/1096 , C10G2400/30 , C07C15/46
摘要： A catalyst for the selective oxidation of hydrogen has been developed. It comprises an inert core such as cordierite and an outer layer comprising a lithium aluminate support. The support has dispersed thereon a platinum group metal and a promoter metal, e.g. platinum and tin respectively. This catalyst is particularly effective in the selective oxidation of hydrogen in a dehydrogenation process.
摘要翻译： 已经开发了用于选择性氧化氢的催化剂。 它包括惰性核心如堇青石和包含铝酸锂载体的外层。 载体上分散有铂族金属和助催化剂金属，例如， 铂和锡分别。 该催化剂在脱氢过程中对氢的选择性氧化特别有效。
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