公开(公告)号：US06245419B1

公开(公告)日：2001-06-12

申请号：US09390767

申请日：1999-09-07

申请人： Masahiro Hakotani ,  Koichi Akiyama ,  Takashi Shibata ,  Kaneo Hamajima ,  Osamu Kito ,  Hiroyuki Takahashi ,  Kazuhiro Uchida

发明人： Masahiro Hakotani ,  Koichi Akiyama ,  Takashi Shibata ,  Kaneo Hamajima ,  Osamu Kito ,  Hiroyuki Takahashi ,  Kazuhiro Uchida

IPC分类号： B32B700

CPC分类号： C08G63/52 ,  C08L67/06 ,  Y10T428/249921

摘要： An unsaturated polyester resin composition having excellent vibration-damping properties, comprising an unsaturated polyester resin (A) having a glass transition temperature (Tg) of 0° C. or more and less than 60° C. In the composition, the unsaturated polyester resin (A) may be blended with an unsaturated polyester resin (B) having a glass transition temperature (Tg) of 150° C. or more and less than 200° C. or an unsaturated polyester resin (C) having a glass transition temperature (Tg) of 200° C. or more. Further, the composition may contain an elastomer (D) having a glass transition temperature (Tg) of −50° C. or more and less than 100° C. Since the unsaturated polyester resin composition has excellent vibration-damping properties and moldability in a wide temperature range, it is very useful to provide molded articles such as vibration-damping structural components, especially automobile engine-related components, having excellent heat resistance and chemical resistance as well as having excellent vibration-damping properties and moldability.

摘要翻译： 具有优异的阻尼性能的不饱和聚酯树脂组合物，其包含玻璃化转变温度（Tg）为0℃以上且小于60℃的不饱和聚酯树脂（A）。在该组合物中，不饱和聚酯树脂 （A）可以与玻璃化转变温度（Tg）为150℃以上且小于200℃的不饱和聚酯树脂（B）或具有玻璃化转变温度的不饱和聚酯树脂（C） Tg）为200℃以上。 此外，组合物可以含有玻璃化转变温度（Tg）为-50℃以上且小于100℃的弹性体（D）。由于不饱和聚酯树脂组合物具有优异的阻尼性和成型性 宽的温度范围，提供具有优异的耐热性和耐化学性以及具有优异的减振性和成型性的减振结构部件，特别是汽车发动机相关部件的模制品非常有用。

公开(公告)号：US06592986B1

公开(公告)日：2003-07-15

申请号：US09701135

申请日：2000-11-24

申请人： Masahiro Hakotani ,  Koichi Akiyama ,  Hiromu Miyashita ,  Takashi Shibata

发明人： Masahiro Hakotani ,  Koichi Akiyama ,  Hiromu Miyashita ,  Takashi Shibata

IPC分类号： B32B2738

CPC分类号： H05K9/0088 ,  B29C70/025 ,  B29C70/502 ,  B29C70/882 ,  C08K7/04 ,  H01B1/22 ,  H01B1/24 ,  H05K9/009 ,  Y10T428/249933 ,  Y10T428/24994 ,  Y10T428/249952 ,  Y10T428/26 ,  Y10T428/31511

摘要： The present invention presents an SMC with which the electrically conductive layer does not break down or become non-uniform during molding and with which molded articles with excellent electromagnetic wave shielding capability and electric conductivity can be produced. This SMC is a thermosetting resin sheet molding compound having at least one continuous layer of electrically conductive fibers with a fiber length of 50 &mgr; to 5 mm, and it is further preferred that electrically conductive powder is uniformly dispersed throughout the entire molding compound. These SMCs can be produced by impregnating a reinforcing material with a thermosetting resin composition which is combined with the above-mentioned electrically conductive fibers, or the electrically conductive fibers and electrically conductive powder, and forming at least one continuous layer of these electrically conductive fibers adjacent to this reinforcement layer.

摘要翻译： 本发明提出了一种SMC，其导电层在成型期间不会分解或变得不均匀，并且可以制造具有优异的电磁波屏蔽能力和导电性的模制品。 该SMC是具有纤维长度为50〜5mm的至少一层连续导电性纤维的热固性树脂片状成型用化合物，进一步优选导电性粉末均匀地分散在整个成型料中。 这些SMC可以通过用与上述导电纤维或导电纤维和导电粉末组合的热固性树脂组合物浸渍增强材料并且形成相邻的这些导电纤维的至少一个连续层来生产 到这个加强层。

公开(公告)号：US5756600A

公开(公告)日：1998-05-26

申请号：US694688

申请日：1996-08-09

申请人： Hiroya Okumura ,  Toshiaki Uchida ,  Koichi Akiyama ,  Kenichi Morita ,  Takashi Shibata

发明人： Hiroya Okumura ,  Toshiaki Uchida ,  Koichi Akiyama ,  Kenichi Morita ,  Takashi Shibata

IPC分类号： C08F8/30 ,  C08F290/14 ,  C08G18/67 ,  C08K3/22 ,  C08K7/14 ,  C08L63/10

CPC分类号： C08G18/6705 ,  C08F290/14 ,  C08F8/30 ,  C08G18/672 ,  Y10T428/24994

摘要： A composition useful as a sheet or bulk molding compound comprises a urethane-modified vinyl ester resin (A), or acid-addition vinyl ester resn (A') obtained by reacting the hydroxyl groups in (A) with a polybasic acid anhydride (B), and a double bond(s)-containing monomer (C), wherein (A) is prepared by reacting a vinyl ester resin (F) derived from the reaction of an epoxy resin (D) and an unsaturated monobasic acid (E), with a polyisocyanate (H) and, optionally, a hydroxyl group(s)-containing (meth)acrylate (G) in an isocyanate:hydroxyl groups equivalent ratio of from 0.01-1.2:1.

摘要翻译： 可用作片或模塑料的组合物包含通过使（A）中的羟基与多元酸酐（B）反应获得的氨基甲酸酯改性的乙烯基酯树脂（A）或酸加成乙烯基酯（A'） ）和含双键的单体（C），其中（A）通过使来自环氧树脂（D）的反应的乙烯基酯树脂（F）与不饱和一元酸（E）的反应制备， ，异氰酸酯（H）和任选的含有（甲基）丙烯酸酯的羟基（G）的异氰酸酯：羟基当量比为0.01-1.2:1。

公开(公告)号：US5077326A

公开(公告)日：1991-12-31

申请号：US363215

申请日：1989-06-08

申请人： Takashi Shibata ,  Koichi Akiyama ,  Sanzi Aoki ,  Yasuhiro Mishima ,  Hisayuki Iwai ,  Ken Hatta

发明人： Takashi Shibata ,  Koichi Akiyama ,  Sanzi Aoki ,  Yasuhiro Mishima ,  Hisayuki Iwai ,  Ken Hatta

IPC分类号： C08L67/06

CPC分类号： C08L67/06

摘要： A quickly curable unsaturated polyester composition with high surface quality contains an unsaturated polyester, a vinyl monomer, either an alkane polyol polyacrylate or an alkane polyol polymethylacrylate, a thermoplastic resin, and one or more curing catalysts selected from t-butylperoxy benzoate, t-butylperoxy octoate and 2,5-dimethyl-2,5-di(benzoilperoxy) hexane. Molding compounds are obtained by impregnating glass fibers with such composition and molded products obtained by curing such molding material have improved surface smoothness.

摘要翻译： 具有高表面质量的快速固化不饱和聚酯组合物包含不饱和聚酯，乙烯基单体，烷基多元醇聚丙烯酸酯或烷基多元醇聚甲基丙烯酸酯，热塑性树脂和一种或多种选自叔丁基过氧苯甲酸酯，叔丁基过氧化物 辛酸酯和2,5-二甲基-2,5-二（苯甲酰过氧）己烷。 通过用这种组合物浸渍玻璃纤维获得成型化合物，并且通过固化这种成型材料获得的模制产品具有改善的表面平滑度。

公开(公告)号：US5395865A

公开(公告)日：1995-03-07

申请号：US973056

申请日：1992-11-06

申请人： Koichi Akiyama ,  Takashi Shibata ,  Hiroma Miyashita ,  Sanji Aoki ,  Ken Hatta ,  Takashi Ino ,  Yasuhiro Mishima

发明人： Koichi Akiyama ,  Takashi Shibata ,  Hiroma Miyashita ,  Sanji Aoki ,  Ken Hatta ,  Takashi Ino ,  Yasuhiro Mishima

IPC分类号： C08K5/13 ,  C08L67/06

CPC分类号： C08K5/13

摘要： Quickly curable unsaturated polyester composition with improved surface characteristics and stability in storage contains 20-40 weight parts of unsaturated polyester, 20-60 weight parts of vinyl monomer, 0.01-1.0 weight parts of BHT (ditertiary butyl hydroxy toluene), and 10-40 weight parts of thermoplastic resin such that the total is 100 weight parts. In addition, 0.001-0.1 weight parts of compound with effect of inhibiting polymerization at temperatures over 100.degree. C. are contained against the total of 100 weight parts. Molding materials are obtained by impregnating glass fibers with such compositions and products are obtained by curing such molding materials.

摘要翻译： 具有改善的表面特性和储存稳定性的快速固化的不饱和聚酯组合物包含20-40重量份的不饱和聚酯，20-60重量份的乙烯基单体，0.01-1.0重量份的BHT（二叔丁基羟基甲苯）和10-40 重量份的热塑性树脂，总共为100重量份。 此外，相对于总共100重量份，含有0.001-0.1重量份的在100℃以上抑制聚合作用的化合物。 通过用这种组合物浸渍玻璃纤维获得成型材料，并且通过固化这种成型材料获得产品。

公开(公告)号：US5354585A

公开(公告)日：1994-10-11

申请号：US834822

申请日：1992-02-13

申请人： Takashi Shibata ,  Koichi Akiyama ,  Shinichiro Asao

发明人： Takashi Shibata ,  Koichi Akiyama ,  Shinichiro Asao

IPC分类号： B29C70/02 ,  B32B27/12 ,  B32B5/18 ,  B32B5/16

CPC分类号： B32B27/12 ,  B29C70/025 ,  B29C70/026 ,  Y10T428/1359 ,  Y10T428/1362 ,  Y10T428/1372 ,  Y10T428/1376 ,  Y10T428/249971 ,  Y10T428/249972 ,  Y10T428/249979 ,  Y10T428/24998 ,  Y10T428/249988 ,  Y10T428/252 ,  Y10T428/2982 ,  Y10T428/2996 ,  Y10T442/675 ,  Y10T442/676

摘要： A molding material is disclosed, comprising a film (A) coated on one surface with a thermosetting resin composition containing a hollow filler, a film (B) on which no resin composition is applied, and a reinforcing fiber layer positioned between the coated surface of film (A) and film (B), wherein the reinforcing fiber layer is impregnated with the liquid component of the resin composition coated on film (A). A piled material is also disclosed, comprising the two portions of the said molding material, wherein the respective molding materials are positioned on top of the other portion in a face-to-face relationship having their respective film (A) sides facing inwardly to each other, where the respective films (A) have been stripped off prior to positioning. A molded product prepared by curing the said piled material from which the films (B) have been stipped off prior to curing, under heating and compressing conditions are very useful for preparing a structural member which is lightweight and has high mechanical strength, due to its lower specific gravity and higher mechanical strength.

摘要翻译： 公开了一种成型材料，其包括在一个表面上涂覆有含有中空填料的热固性树脂组合物的膜（A），其上没有施加树脂组合物的膜（B）和位于涂覆表面之间的增强纤维层 膜（A）和膜（B），其中，所述增强纤维层浸渍有涂覆在膜（A）上的树脂组合物的液体成分。 还公开了一种堆叠材料，其包括所述模制材料的两个部分，其中相应的模制材料以面对面关系定位在另一部分的顶部上，其中它们各自的膜（A）侧面向内朝向每个 另一方面，在定位之前已经剥离各个膜（A）。 在加热和压缩条件下固化所述薄膜（B）已被固化的所述堆叠材料制成的模制产品对于制备重量轻且机械强度高的结构件是非常有用的， 较低的比重和较高的机械强度。

公开(公告)号：US5246983A

公开(公告)日：1993-09-21

申请号：US717818

申请日：1991-06-19

申请人： Takashi Shibata ,  Hiromu Miyashita ,  Sanzi Aoki ,  Koichi Akiyama

发明人： Takashi Shibata ,  Hiromu Miyashita ,  Sanzi Aoki ,  Koichi Akiyama

IPC分类号： C08J9/32

CPC分类号： C08J9/32 ,  C08J2367/00

摘要： A resin composition comprising (a) an unsaturated polyester, (b) a vinyl monomer, (c) a thermoplastic resin, (d) a curing agent and (e) a hollow filler with a number average particle diameter of not more than 20 .mu., wherein (e) occurs in a proportion of 10 to 150 parts by weight to 100 parts by weight of (a), (b) and (c) combined, and the molding compounds obtainable by impregnating glass fiber with the said resin composition are very useful in that, because of their lower specific gravity, they provide lightweight products with excellent surface quality which are great use as automotive exterior body panels and other parts.

摘要翻译： 一种树脂组合物，其包含（a）不饱和聚酯，（b）乙烯基单体，（c）热塑性树脂，（d）固化剂和（e）数均粒径不大于20微米的中空填料 其中（e）以（a），（b）和（c）的100重量份的比例为10〜150重量份的组合，通过与所述树脂组合物浸渍玻璃纤维而获得的成型化合物为 非常有用，因为它们的比重较低，它们提供具有优异表面质量的轻质产品，其作为汽车外壳面板和其它部件是非常有用的。

公开(公告)号：US09436981B2

公开(公告)日：2016-09-06

申请号：US14363367

申请日：2012-12-10

申请人： Takashi Shibata ,  Akihiko Iketani ,  Shuji Senda

发明人： Takashi Shibata ,  Akihiko Iketani ,  Shuji Senda

IPC分类号： G06K9/00 ,  G06T5/00 ,  G06N99/00

CPC分类号： G06T5/003 ,  G06K9/00275 ,  G06N99/005 ,  G06T2207/20081 ,  G06T2207/20084

摘要： A dictionary creation device including a blurred image generation unit which outputs a blurred image generated by performing a blurring process to a learning image together with a blur parameter indicating a blurring state of the blurred image, a patch pair generation unit which generates a restoration patch and a blurred patch as a patch pair that is composed of the patches located at the corresponding positions of the learning image and the blurred image, and a registration unit which associates the patch pair with a blur parameter corresponding to the blurred patch in the patch pair and registers them in a dictionary.

摘要翻译： 一种词典创作装置，包括模糊图像生成单元，其通过对学习图像进行模糊处理而生成的模糊图像以及表示模糊图像的模糊状态的模糊参数，生成恢复贴片的贴片对生成单元， 由位于学习图像和模糊图像的对应位置处的贴片组成的贴片对的模糊贴片，以及配准单元，其将贴片对与对应于贴片对中的模糊贴片的模糊参数相关联， 将其注册在字典中。

公开(公告)号：US20140355900A1

公开(公告)日：2014-12-04

申请号：US14233973

申请日：2012-06-21

申请人： Takashi Shibata ,  Akihiko Iketani ,  Shuji Senda

发明人： Takashi Shibata ,  Akihiko Iketani ,  Shuji Senda

IPC分类号： G06T5/00

CPC分类号： G06T5/003 ,  G06T5/002 ,  G06T2207/20192 ,  H04N5/217

摘要： For each pixel of an input image, a direction toward which variation in pixel value between the relevant pixel and its peripheral pixels is largest and an amount of the variation in pixel value are computed, where a direction unit vector that indicates the direction toward which the variation is largest and a variation vector that represents the amount of the largest variation in the pixel value are computed. For each pixel, a regularization strength is computed utilizing the direction unit vector, the variation vector, and a regularization strength computing formula so that the larger the amount of the variation in pixel value toward a direction indicated by the direction unit vector, the less the regularization strength. An optimization function is determined based on the input image and the regularization strength for each pixel thereof and assigns a value for each pixel, by which the determined optimization function has the minimum value, to the corresponding pixel of a restored image to be generated.

摘要翻译： 对于输入图像的每个像素，计算相关像素和其周边像素之间的像素值的变化最大并且计算像素值的变化量的方向，其中指示方向的方向单位向量 变化最大，并且计算表示像素值中最大变化量的变化矢量。 对于每个像素，使用方向单位矢量，变化矢量和正则化强度计算公式来计算正则化强度，使得朝向由方向单位向量指示的方向的像素值的变化量越大，则越小 正规化实力。 基于输入图像和其每个像素的正则化强度来确定优化函数，并且将所确定的优化函数具有最小值的每个像素的值分配给要生成的恢复图像的相应像素。

公开(公告)号：US08845938B2

公开(公告)日：2014-09-30

申请号：US13990540

申请日：2011-11-28

申请人： Tomoko Ichikawa ,  Takashi Ochi ,  Akira Kishiro ,  Yasutaka Kato ,  Takashi Shibata ,  Masafumi Ise

发明人： Tomoko Ichikawa ,  Takashi Ochi ,  Akira Kishiro ,  Yasutaka Kato ,  Takashi Shibata ,  Masafumi Ise

IPC分类号： D02J1/22 ,  D01D10/00 ,  D01D5/16 ,  D01F6/18 ,  D01F9/22 ,  D01D10/02

CPC分类号： D01D10/00 ,  D01D5/16 ,  D01D10/02 ,  D01F6/18 ,  D01F9/22 ,  D02J1/228

摘要： A method of manufacturing a polyacrylonitrile fiber includes a spinning process in which a spinning dope including polyacrylonitrile is spun; a first drawing process; a drying process; and a second hot drawing process in this order.

摘要翻译： 制造聚丙烯腈纤维的方法包括纺丝纺丝方法，其中包括聚丙烯腈的纺丝原液纺丝; 第一个绘图过程; 干燥过程; 并按此顺序进行第二次热拉伸处理。