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1.发明授权Catalysts for converting alcohols and/or aliphatic ether to unsaturated hydrocarbons and process for their production 失效用于将醇和/或脂肪族醚转化为不饱和烃的催化剂及其生产方法
公开(公告)号：US4861937A
公开(公告)日：1989-08-29
申请号：US518402
申请日：1983-07-29
CPC分类号： C01B39/026 , B01J29/70 , C07C1/20 , B01J2229/26 , B01J2229/42 , C07C2529/40
摘要： Alcohols and/or aliphatic ethers are converted to hydrocarbons employing catalysts consisting of crystalline aluminum silicate, a compound of zinc and/or cadmium and additional silica. The catalyst is produced by treating a crystalline aluminum silicate, in a given case, partially or completely converted into the hydrogen form with a zinc or cadmium compound and shaping with a silica containing binder.
摘要翻译： 使用由结晶硅酸铝，锌和/或镉化合物和另外的二氧化硅组成的催化剂将醇和/或脂族醚转化为烃。 催化剂是通过在一定情况下处理结晶硅酸铝，用锌或镉化合物部分或完全转化为氢形式并用含二氧化硅的粘合剂进行成型来制备的。
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2.发明授权
公开(公告)号：US4563480A
公开(公告)日：1986-01-07
申请号：US621460
申请日：1984-06-18
CPC分类号： C07C1/043 , B01J29/08 , B01J29/185 , B01J29/70 , C07C2523/06 , C07C2529/08 , C07C2529/18 , C07C2529/40 , Y10S423/22 , Y10S423/34
摘要： A catalyst for the production of hydrocarbon consists essentially of crystalline aluminum silicate, at least one compound of the metal zinc and/or cadmium and additionally silica. The catalyst is produced by heating a crystalline aluminum silicate, in a given case partially or completely converted to the hydrogen form, with a zinc and/or cadmium compound and molding with a silica containing binder.
摘要翻译： 用于生产烃的催化剂基本上由结晶硅酸铝，金属锌和/或镉的至少一种化合物和另外的二氧化硅组成。 催化剂是通过在一定情况下用锌和/或镉化合物加热结晶硅酸铝，部分或完全转化为氢形式，并用含二氧化硅的粘合剂进行成型制备的。
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3.发明授权
公开(公告)号：US4935218A
公开(公告)日：1990-06-19
申请号：US518403
申请日：1983-07-29
CPC分类号： C07C1/043 , B01J29/08 , B01J29/185 , B01J29/70 , C07C2523/06 , C07C2529/08 , C07C2529/18 , C07C2529/40 , Y10S423/22 , Y10S423/34
摘要： A catalyst for the production of hydrocarbon consists essentially of crystalline aluminum silicate, at least one compound of the metal zinc and/or cadmium and additionally silica. The catalyst is produced by heating a crystalline aluminum silicate, in a given case partially or completely converted to the hydrogen form, with a zinc and/or cadmium compound and molding with a silica containing binder.
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4.发明授权Method for the reduction of nitrogen oxides from waste gases using a zeolite 失效使用ZEOLITE从废气中还原氮氧化物的方法
公开(公告)号：US5116586A
公开(公告)日：1992-05-26
申请号：US448198
申请日：1989-12-14
申请人： Michael Baacke , Reinhold Beand , Bernd Engler , Akos Kiss , Peter Kleine-Mollhoff , Peter Kleinschmit , Edgar Koberstein , Mustafa Siray
发明人： Michael Baacke , Reinhold Beand , Bernd Engler , Akos Kiss , Peter Kleine-Mollhoff , Peter Kleinschmit , Edgar Koberstein , Mustafa Siray
CPC分类号： B01J29/26 , B01D53/9418 , B01J29/24 , B01D2251/2062 , B01D2255/2065 , B01D2255/20738 , B01D2255/20761 , B01D2255/20769 , B01D2255/50
摘要： A zeolite catalyst and a method for reduction of nitrogen oxides present in waste gas streams is described. The method includes mixing the waste gas containing nitrogen oxides with ammonia. At an elevated temperature, this mixture is passed over a zeolite catalyst. Preferably, the zeolite catalyst is in a monolithic or honeycomb form. The zeolite catalyst includes one or more of the following subgroup metals: copper, iron, molybdeum and cerium. The zeolite catalysts made in accordance with this invention show better conversion of nitrogen oxides and longer life than known catalysts.
摘要翻译： 描述了沸石催化剂和还原废气流中存在的氮氧化物的方法。 该方法包括将含有氮氧化物的废气与氨混合。 在升高的温度下，将该混合物通过沸石催化剂。 优选地，沸石催化剂为整体或蜂窝形式。 沸石催化剂包括一种或多种以下亚族金属：铜，铁，钼和铈。 根据本发明制备的沸石催化剂表现出比已知催化剂更好的氮氧化物转化和更长的寿命。
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5.发明授权Titanium dioxide compacts, method of their production and a catalyst coated on a carrier of titanium dioxide 失效二氧化钛溶液，其生产方法和涂覆在二氧化钛载体上的催化剂
公开(公告)号：US5120701A
公开(公告)日：1992-06-09
申请号：US676176
申请日：1991-03-28
申请人： Reinhold Brand , Bernd Engler , Martin Foerster , Werner Hartmann , Peter Kleinschmit , Edgar Koberstein , Johannes Ohmer , Rudolf Schwarz
发明人： Reinhold Brand , Bernd Engler , Martin Foerster , Werner Hartmann , Peter Kleinschmit , Edgar Koberstein , Johannes Ohmer , Rudolf Schwarz
CPC分类号： B01J21/063 , B01J35/1014 , B01J35/1038 , B01J35/1052 , B01J35/1061 , B01J37/0009 , C04B35/46
摘要： Titanium dioxide compacts are produced by intensively mixing pyrogenically produced titanium dioxide in the presence of deionized water with a wetting agent and/or with a base and/or optionally with a binder and/or optionally with an auxiliary deformation agent and/or optionally with a pore former, extruding the mass thus obtained at pressures between 5 and 100 bars to form shaped articles, drying the shaped articles at temperatures between 50.degree. and 120.degree. C. and subsequently calcining the shaped articles in the ambient air at temperatures of 400.degree. to 700.degree. C. for 1 to 5 hours.
摘要翻译： 二氧化钛压块是通过在去离子水的存在下与润湿剂和/或与基底和/或任选地与粘合剂和/或任选地与辅助变形剂和/或任选地与 在50至100巴之间的压力下挤出由此获得的物料以形成成型制品，在50至120℃的温度下干燥成形制品，随后在400℃至400℃的温度下在环境空气中煅烧成型制品 700℃下1〜5小时。
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公开(公告)号：US5300472A
公开(公告)日：1994-04-05
申请号：US999618
申请日：1992-12-31
CPC分类号： B01J21/066 , B01D53/9418 , B01J21/063 , B01J23/00 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/108 , B01D2251/2062 , B01D2255/20707 , B01D2255/20723 , B01D2255/20776 , B01D2255/9207 , Y02C20/10
摘要： A catalyst for the selective reduction of nitrous oxide with ammonia contains, in addition to titanium oxide as component (A), at least one oxide of W, Si, B, Al, P, Zr, Ba, Y, La, Ce and at least one oxide of Y, Nb, Mo, Fe, Cu as component (B), whereby the atomic ratio between the elements of components (A) and (B) amounts to 1:0.001 up to 1. The catalyst can be obtained by kneading reactive titanium oxide with a high specific surface of predominantly anatase with the substances of component (B) or their preliminary stages, adding processing agents, winding up with a homogeneous kneaded mass, extruding the latter, drying the extrudate and calcining in air at 300.degree.-800.degree. C.
摘要翻译： 除了氧化钛作为组分（A）之外，用氨选择还原一氧化二氮的催化剂还包含至少一种W，Si，B，Al，P，Zr，Ba，Y，La，Ce和 作为组分（B）的Y，Nb，Mo，Fe，Cu的至少一种氧化物，由此组分（A）和（B）的元素之间的原子比为1：0.001至1。催化剂可以通过 用具有组分（B）或其初级阶段的物质将主要为锐钛矿的高比表面处理的反应性二氧化钛混合，加入加工剂，用均匀的捏合物料卷绕，挤出后者，干燥挤出物并在空气中煅烧300 -800摄氏度
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7.发明授权
公开(公告)号：US5131260A
公开(公告)日：1992-07-21
申请号：US676707
申请日：1991-03-29
申请人： Reinhold Brand , Bernd Engler , Wolfgang Honen , Edgar Koberstein
发明人： Reinhold Brand , Bernd Engler , Wolfgang Honen , Edgar Koberstein
CPC分类号： G01N1/405 , G01N1/2258 , G01N33/0054 , G01N2001/2217 , G01N2001/2282 , G01N2001/4033
摘要： A device for the continuous measurement of the ammonia concentration in gases in the ppm range includes a columnar absorption vessel (1) with a hemispherical bottom (4). The bottom of the column includes an overflow (3) and an outlet (5). The gas introduction pipe (7,8) empties above the bottom (4) and below a sieve bottom (6) arranged in the column (1). A packing material (10) rests on the sieve bottom (6), which packing (10) essentially fills the absorption column (1). A cooling part (11) extends from the absorption column (1). The cooling part (11) includes a cooling zone (15) and a gas collection space (16) above it with a closable connection piece (13). A pipe (14), which may include a serrated crown on each end, runs from the gas collecting space (16) downward in a cooled manner to the packing 10. The liquid absorption agent is introduced through a lateral connection piece (18) into the gas collection space (16). For the measurement of ammonia concentration, a certain volume flow of the gas to be measured is washed in a countercurrent flow with the absorption agent, and the NH.sub.3 content is determined in a part of the ammonia containing absorption agent. The volume flow rate of the absorption agent and of the gas from which NH.sub.3 has been removed is measured (the latter being dried), and the ammonia concentration is thereby calculated.
摘要翻译： 在ppm范围内连续测量气体中的氨浓度的装置包括具有半球形底部（4）的柱状吸收容器（1）。 塔的底部包括溢流（3）和出口（5）。 气体导入管（7,8）在布置在塔（1）中的底部（4）和下方的筛底（6）之上排空。 包装材料（10）搁置在筛底（6）上，该填料（10）基本上填充吸收塔（1）。 冷却部件（11）从吸收塔（1）延伸。 冷却部件（11）在其上方包括一个冷却区（15）和一个气体收集空间（16），并具有可关闭的连接件（13）。 可以在每个端部包括锯齿状冠的管道（14）从气体收集空间（16）以冷却的方式向下延伸到填料10.液体吸收剂通过横向连接件（18）引入 气体收集空间（16）。 为了测量氨浓度，将要测量的气体的一定体积流量与吸收剂以逆流流动洗涤，并且在含氨吸收剂的一部分中测定NH 3含量。 测量吸收剂和从其中除去NH 3的气体的体积流量（后者被干燥），由此计算氨浓度。
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8.发明授权
公开(公告)号：US4963332A
公开(公告)日：1990-10-16
申请号：US384754
申请日：1989-07-25
CPC分类号： F01N3/208 , B01D53/8625 , B01D53/8696 , B01D53/9409 , B01D53/9495 , F01N2560/026 , F01N2560/14 , F01N2570/18 , F01N2610/02 , F01N2610/146 , F01N2900/0422 , Y02T10/24
摘要： A method for the removal of nitrogen oxides contained in exhaust gases of an optionally fluctuating composition with a temperature of 0.degree.-600.degree. C. by means of catalytic reduction at a preselected stoichiometric ratio between the concentration of reducing agent and the concentration of nitrogen oxide in which the reducing agent is dosed in a pulsed manner.
摘要翻译： 通过以预选的化学计量比在还原剂的浓度与氮氧化物的浓度之间通过催化还原来除去包含在任选波动的组合物的废气中的氮氧化物的温度为0℃-600℃的方法 其中还原剂以脉冲方式配制。
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9.发明授权Process for the ring cleavage of 2-isopropyl-5,5-dimethylthiazolidines substituted in the 4-position 失效4-取代的2-异丙基-5,5-二甲基噻唑啉的环裂解方法
公开(公告)号：US4731477A
公开(公告)日：1988-03-15
申请号：US18304
申请日：1987-02-24
IPC分类号： C07C319/02 , C07C67/00 , C07C313/00 , C07C323/58 , C07D277/06 , C07C149/243
CPC分类号： C07D277/06
摘要： A process for the ring cleavage of 2-isopropyl-5,5-dimethylthiazolidines in aqueous acid medium at elevated temperature. Whenever the five ring in the 4-position is substituted by a carboxyl group, penicillamine is the resultant product.
摘要翻译： 在高温酸性介质中，2-异丙基-5,5-二甲基噻唑啉的环裂解方法。 只要四位五环被羧基取代，青霉胺就是所得的产物。
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公开(公告)号：US4477417A
公开(公告)日：1984-10-16
申请号：US542313
申请日：1983-10-14
IPC分类号： F01N3/02 , B01D53/86 , B01D53/94 , B01J23/68 , B01J35/04 , B01J35/06 , F01N3/035 , F02B1/04 , F02B3/06 , B01D53/36
摘要： A process and catalyst is disclosed for the reduction of the ignition temperature of diesel soot filtered out of the exhaust fumes of diesel engines by passing the exhaust stream through a filter element. The filter element is a temperature resistant inert support onto which is deposited a catalytically effective amount of silver vanadate or a mixture of the temperature resistant carrier material and a catalytically effective amount of silver vanadate.
摘要翻译： 公开了一种方法和催化剂，用于通过使废气流通过过滤元件来降低从柴油发动机废气中过滤的柴油烟尘的点燃温度。 过滤元件是耐温惰性载体，其上沉积催化有效量的钒酸银或耐温载体材料和催化有效量的钒酸银的混合物。
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