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    Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions
    2.
    发明申请
    Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions 失效
    用于最小化可交联组合物焦烧的硝酸化合物

    公开(公告)号：US20090069469A1

    公开(公告)日：2009-03-12

    申请号：US12267909

    申请日：2008-11-10

    申请人： Mohamed Esseghir ,  Bharat I. Chaudhary ,  Jeffrey M. Cogen ,  John Klier ,  Jinder Jow ,  Robert F. Eaton ,  Suzanne M. Guerra

    发明人： Mohamed Esseghir ,  Bharat I. Chaudhary ,  Jeffrey M. Cogen ,  John Klier ,  Jinder Jow ,  Robert F. Eaton ,  Suzanne M. Guerra

    IPC分类号： C08K5/3435 ,  C07D211/94

    CPC分类号： C08F2/38 ,  C08F4/00 ,  C08K5/0025 ,  C08K5/3435

    摘要： Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

    摘要翻译： 在可交联聚合物（例如EPDM）的自由基交联期间，通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物，优选醚，酯或氨基甲酸酯衍生物的交联之前引入聚合物中，焦烧被抑制 ，例如4-羟基 - 四氢环丁基哌啶-1-基。 在类似的聚合物组合物和类似的条件下，本发明的焦烧抑制剂（如果不是更好）也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样，在焦烧抑制和最终交联度方面也表现出较低的挥发性， 聚合物组合物内迁移少。

    Nitroxide compounds for minimizing scorch in crosslinkable compositions
    3.
    发明授权
    Nitroxide compounds for minimizing scorch in crosslinkable compositions 失效
    用于最小化可交联组合物中焦化的硝酸氧化物

    公开(公告)号：US07465769B2

    公开(公告)日：2008-12-16

    申请号：US11539815

    申请日：2006-10-09

    申请人： Mohamed Esseghir ,  Bharat I. Chaudhary ,  Jeffrey M. Cogen ,  John Klier ,  Jinder Jow ,  Robert F. Eaton ,  Suzanne M. Guerra

    发明人： Mohamed Esseghir ,  Bharat I. Chaudhary ,  Jeffrey M. Cogen ,  John Klier ,  Jinder Jow ,  Robert F. Eaton ,  Suzanne M. Guerra

    IPC分类号： C08F8/30

    CPC分类号： C08F2/38 ,  C08F4/00 ,  C08K5/0025 ,  C08K5/3435

    摘要： Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

    摘要翻译： 在可交联聚合物（例如EPDM）的自由基交联期间，通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物，优选醚，酯或氨基甲酸酯衍生物的交联之前引入聚合物中，焦烧被抑制 ，例如4-羟基 - 四氢环丁基哌啶-1-基。 在类似的聚合物组合物和类似的条件下，本发明的焦烧抑制剂（如果不是更好）也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样，在焦烧抑制和最终交联度方面也表现出较低的挥发性， 聚合物组合物内迁移少。

    Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions
    7.
    发明申请
    Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions 失效
    用于最小化可交联组合物焦烧的硝酸化合物

    公开(公告)号：US20080085973A1

    公开(公告)日：2008-04-10

    申请号：US11539815

    申请日：2006-10-09

    申请人： Mohamed Esseghir ,  Bharat I. Chaudhary ,  Jeffrey M. Cogen ,  John Klier ,  Jinder Jow ,  Robert F. Eaton ,  Suzanne M. Guerra

    发明人： Mohamed Esseghir ,  Bharat I. Chaudhary ,  Jeffrey M. Cogen ,  John Klier ,  Jinder Jow ,  Robert F. Eaton ,  Suzanne M. Guerra

    IPC分类号： C07D211/00 ,  C08F2/38

    CPC分类号： C08F2/38 ,  C08F4/00 ,  C08K5/0025 ,  C08K5/3435

    摘要： Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

    摘要翻译： 在可交联聚合物（例如EPDM）的自由基交联期间，通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物，优选醚，酯或氨基甲酸酯衍生物的交联之前引入聚合物中，焦烧被抑制 ，例如4-羟基 - 四氢环丁基哌啶-1-基。 在类似的聚合物组合物和类似的条件下，本发明的焦烧抑制剂（如果不是更好）也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样，在焦烧抑制和最终交联度方面也表现出较低的挥发性， 聚合物组合物内迁移少。

    Silicone-thermoplastic polymer reactive blends and copolymer products
    10.
    发明授权
    Silicone-thermoplastic polymer reactive blends and copolymer products 有权
    硅酮 - 热塑性聚合物反应性共混物和共聚物产品

    公开(公告)号：US08426519B2

    公开(公告)日：2013-04-23

    申请号：US13057033

    申请日：2009-07-24

    申请人： Jeffrey M. Cogen ,  Mohamed Esseghir ,  Andrew Hilmer

    发明人： Jeffrey M. Cogen ,  Mohamed Esseghir ,  Andrew Hilmer

    IPC分类号： C08F8/00

    CPC分类号： C08G77/06 ,  C08G77/442 ,  C08L23/00 ,  C08L23/0815 ,  C08L23/16 ,  C08L23/26 ,  C08L83/04 ,  C08L101/00 ,  C08L83/00

    摘要： Silicone-thermoplastic polymer reactive blends and copolymer products are prepared using economical post-reactor reactive mixing, e.g., extrusion. The procedure is based on the ring-opening polymerization of cyclic siloxanes within a thermoplastic polymer matrix. In a preferred mode, the thermoplastic polymer is a polyolefin, optionally containing silane groups that are available for reaction with the silicone polymer that is formed in situ. The resulting materials provide hybrid performance that can extend the range of applications beyond those which are served by thermoplastic polymers or silicones alone, or their physical blends.

    摘要翻译： 硅氧烷 - 热塑性聚合物反应性共混物和共聚物产物使用经济的反应器后反应混合，例如挤出制备。 该方法基于热塑性聚合物基质内环状硅氧烷的开环聚合。 在优选的模式中，热塑性聚合物是聚烯烃，任选地含有可与原位形成的硅氧烷聚合物反应的硅烷基团。 所得到的材料提供混合性能，其可以将应用的范围扩展到由单独的热塑性聚合物或硅氧烷或其物理共混物所服务的范围之外。