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    Process for Making Crosslinked Injection Molded Articles
    7.
    发明申请
    Process for Making Crosslinked Injection Molded Articles 审中-公开
    制造交联注塑制品的工艺

    公开(公告)号：US20120175809A1

    公开(公告)日：2012-07-12

    申请号：US13496523

    申请日：2010-09-14

    申请人： Mohamed Esseghir ,  Saurav S. Sengupta

    发明人： Mohamed Esseghir ,  Saurav S. Sengupta

    IPC分类号： B29C45/00 ,  B29C45/72

    CPC分类号： C08J3/244 ,  C08J2351/06

    摘要： An injection molding process for making a plastic article, the process comprising the steps of: A. Forming a moisture-curable composition comprising a 1. Silane-functionalized polyethylene, 2. Moisture source, e.g., a moisture-containing filler, wherein the moisture source excludes alcohols, and 3. Condensation catalyst; B. Injecting the composition into a mold; C. Subjecting the composition to conditions sufficient to 1. Release moisture from the moisture source, and 2. Partially cure the composition; D. Removing the partially cured composition from the mold; and E. Continuing the cure of the composition outside of the mold. The process is particularly well suited for the manufacture of thick parts, such as wire and cable elastomeric connectors.

    摘要翻译： 一种用于制造塑料制品的注射成型方法，该方法包括以下步骤：A.形成包含1.硅烷官能化聚乙烯的湿气固化组合物，2.水分源，例如含水分的填料，其中水分 来源不包括醇类，和3.缩合催化剂; B.将组合物注入模具; C.使组合物达到足以从水分源释放水分的条件，和2.部分固化组合物; D.从模具中取出部分固化的组合物; 和E.继续固化组合物在模具外面。 该方法特别适用于制造厚部件，例如电线和电缆弹性体连接器。

    Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions
    8.
    发明申请
    Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions 失效
    用于最小化可交联组合物焦烧的硝酸化合物

    公开(公告)号：US20080085973A1

    公开(公告)日：2008-04-10

    申请号：US11539815

    申请日：2006-10-09

    申请人： Mohamed Esseghir ,  Bharat I. Chaudhary ,  Jeffrey M. Cogen ,  John Klier ,  Jinder Jow ,  Robert F. Eaton ,  Suzanne M. Guerra

    发明人： Mohamed Esseghir ,  Bharat I. Chaudhary ,  Jeffrey M. Cogen ,  John Klier ,  Jinder Jow ,  Robert F. Eaton ,  Suzanne M. Guerra

    IPC分类号： C07D211/00 ,  C08F2/38

    CPC分类号： C08F2/38 ,  C08F4/00 ,  C08K5/0025 ,  C08K5/3435

    摘要： Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

    摘要翻译： 在可交联聚合物（例如EPDM）的自由基交联期间，通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物，优选醚，酯或氨基甲酸酯衍生物的交联之前引入聚合物中，焦烧被抑制 ，例如4-羟基 - 四氢环丁基哌啶-1-基。 在类似的聚合物组合物和类似的条件下，本发明的焦烧抑制剂（如果不是更好）也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样，在焦烧抑制和最终交联度方面也表现出较低的挥发性， 聚合物组合物内迁移少。

    Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions
    10.
    发明申请
    Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions 失效
    用于最小化可交联组合物焦烧的硝酸化合物

    公开(公告)号：US20090069469A1

    公开(公告)日：2009-03-12

    申请号：US12267909

    申请日：2008-11-10

    申请人： Mohamed Esseghir ,  Bharat I. Chaudhary ,  Jeffrey M. Cogen ,  John Klier ,  Jinder Jow ,  Robert F. Eaton ,  Suzanne M. Guerra

    发明人： Mohamed Esseghir ,  Bharat I. Chaudhary ,  Jeffrey M. Cogen ,  John Klier ,  Jinder Jow ,  Robert F. Eaton ,  Suzanne M. Guerra

    IPC分类号： C08K5/3435 ,  C07D211/94

    CPC分类号： C08F2/38 ,  C08F4/00 ,  C08K5/0025 ,  C08K5/3435

    摘要： Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

    摘要翻译： 在可交联聚合物（例如EPDM）的自由基交联期间，通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物，优选醚，酯或氨基甲酸酯衍生物的交联之前引入聚合物中，焦烧被抑制 ，例如4-羟基 - 四氢环丁基哌啶-1-基。 在类似的聚合物组合物和类似的条件下，本发明的焦烧抑制剂（如果不是更好）也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样，在焦烧抑制和最终交联度方面也表现出较低的挥发性， 聚合物组合物内迁移少。