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    Catalyst for hydroprocessing of Fischer-Tropsch products
    4.
    发明申请
    Catalyst for hydroprocessing of Fischer-Tropsch products 审中-公开
    费 - 托产品加氢处理催化剂

    公开(公告)号：US20050274646A1

    公开(公告)日：2005-12-15

    申请号：US10866884

    申请日：2004-06-14

    申请人： Keith Lawson ,  Kandaswamy Jothimurugesan ,  Rafael Espinoza

    发明人： Keith Lawson ,  Kandaswamy Jothimurugesan ,  Rafael Espinoza

    IPC分类号： B01J23/42 ,  B01J35/10 ,  B01J37/02 ,  B05D1/18 ,  B05D3/02 ,  C10G47/04 ,  C10G47/12

    CPC分类号： B01J35/10 ,  B01J23/42 ,  B01J35/1061 ,  B01J37/0211 ,  C10G47/12

    摘要： The invention generally relates to methods for modifying a porous amorphous material comprising micropores to reduce its micropore volume and to form a support for a hydroprocessing catalyst, to methods of making said catalyst, as well as to methods for hydrocracking employing said hydroprocessing catalyst characterized by a lower selectivity towards undesirable gaseous hydrocarbon products. In one embodiment, the method for modifying the amorphous material comprises depositing an inorganic oxide or inorganic oxide precursor to the amorphous material; and treating the deposited amorphous material so as to reduce its micropore volume by at least about 5 percent, while its mean pore diameter is substantially unchanged or changed by not more than about 10 percent. Further embodiments include the amorphous material comprising silica-alumina, and the deposited inorganic oxide or inorganic oxide precursor comprising silicon.

    摘要翻译： 本发明一般涉及用于改性包含微孔以减少其微孔体积并形成用于加氢处理催化剂的载体的多孔无定形材料的方法，制备所述催化剂的方法以及使用所述加氢处理催化剂的加氢裂化方法，其特征在于 对不需要的气态烃产物的选择性降低。 在一个实施方案中，用于改性无定形材料的方法包括将无机氧化物或无机氧化物前体沉积到无定形材料中; 以及处理所沉积的非晶材料以便将其微孔体积减少至少约5％，而其平均孔径基本上不变或改变不超过约10％。 另外的实施方案包括包含二氧化硅 - 氧化铝的无定形材料和包含硅的沉积的无机氧化物或无机氧化物前体。

    Combination of amorphous materials for hydrocracking catalysts
    8.
    发明申请
    Combination of amorphous materials for hydrocracking catalysts 有权
    用于加氢裂化催化剂的无定形材料的组合

    公开(公告)号：US20060011512A1

    公开(公告)日：2006-01-19

    申请号：US11180089

    申请日：2005-07-13

    申请人： Rafael Espinoza ,  Keith Lawson ,  Kandaswamy Jothimurugesan

    发明人： Rafael Espinoza ,  Keith Lawson ,  Kandaswamy Jothimurugesan

    IPC分类号： C10G47/02

    CPC分类号： B01J37/036 ,  B01J21/12 ,  B01J23/24 ,  B01J23/40 ,  B01J23/42 ,  B01J23/652 ,  B01J23/85 ,  B01J23/89 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/04 ,  C10G2/32 ,  C10G47/02 ,  C10G47/04 ,  C10G47/12 ,  C10G47/14

    摘要： An amorphous support, methods for making the same and methods of using, particularly in hydrocracking. A method of making may comprise mixing a first amorphous material and a second amorphous material of different acidities to form a mixture, and treating by either separately treating the first and second amorphous materials before mixing or treating the mixture, so as to form an amorphous catalyst support. Treating preferably includes calcining. The acidity of the amorphous support may be modified by the different acidities of the precursor amorphous materials, their proportions in the mixture, and/or the order of the mixing and treating steps. A method of use may comprise reacting a hydrocarbon fraction with hydrogen over a hydrocracking catalyst comprising the amorphous catalyst support to form a hydrocracked product. Further embodiments include the first and second amorphous materials comprising silica-alumina, and/or differing in Brönsted acidity, Lewis acidity, or acidity index.

    摘要翻译： 无定形支撑物，制备方法和使用方法，特别是在加氢裂化中。 制备方法可以包括混合不同酸度的第一无定形材料和第二无定形材料以形成混合物，并且在混合或处理混合物之前单独处理第一和第二非晶材料进行处理，以形成无定形催化剂 支持。 处理优选包括煅烧。 无定形载体的酸度可以通过前体无定形材料的不同酸度，它们在混合物中的比例和/或混合和处理步骤的顺序来改变。 使用的方法可以包括使烃馏分与氢气在包含无定形催化剂载体的加氢裂化催化剂上反应以形成加氢裂化产物。 另外的实施方案包括包含二氧化硅 - 氧化铝的第一和第二无定形材料和/或布朗斯台德酸度，路易斯酸度或酸度指数不同。

    Methods of reducing and loading a metal-based catalyst into a reactor
    9.
    发明申请
    Methods of reducing and loading a metal-based catalyst into a reactor 审中-公开
    将金属基催化剂还原和负载到反应器中的方法

    公开(公告)号：US20050182145A1

    公开(公告)日：2005-08-18

    申请号：US10780049

    申请日：2004-02-17

    申请人： Sergio Mohedas ,  Rafael Espinoza ,  Ajoy Raje ,  Kevin Coy

    发明人： Sergio Mohedas ,  Rafael Espinoza ,  Ajoy Raje ,  Kevin Coy

    IPC分类号： B01J20/34 ,  B01J21/08 ,  B01J23/40 ,  B01J23/75 ,  B01J23/76 ,  B01J31/00 ,  B01J37/18 ,  C07C27/00 ,  C07C27/06 ,  C07C29/10 ,  C10G2/00

    CPC分类号： C10G2/33 ,  B01J23/75 ,  B01J23/76 ,  B01J37/18 ,  C07C29/10

    摘要： The present methods feature an overall decrease in transportation costs and catalyst preparation/protection measures. A catalyst comprising a catalytic metal in an oxide form is safely transported in an oxidizing environment to a synthesis site, without any special precautions being taken before and during transport. The catalyst is then reduced with a reducing gas at the synthesis plant. The reduced catalyst is mixed with a stripped hydrocarbon liquid to form a catalyst slurry, wherein the stripped hydrocarbon liquid is substantially free of dissolved oxygen after being contacted with a stripping gas. The mixing can take place in a pre-operational hydrocarbon synthesis reactor, or at least a portion of the slurry can be transferred to at least one synthesis reactor either during operation or at the reactor start-up. A lessening of costs is realized as a coating step to minimize oxidative degradation of the catalyst is not required.

    摘要翻译： 本方法运输成本和催化剂制备/保护措施总体下降。 包含氧化物形式的催化金属的催化剂在氧化环境中被安全地运输到合成部位，而在运输之前和期间都不采取任何特别的预防措施。 然后在合成工厂用催化剂还原气体。 将还原的催化剂与汽提的烃液体混合以形成催化剂浆料，其中汽提的烃液体在与汽提气体接触后基本上不含溶解的氧气。 混合可以在预操作的烃合成反应器中进行，或者在操作期间或在反应器启动时，至少一部分浆料可以转移到至少一个合成反应器。 实现成本的降低是不需要最小化催化剂的氧化降解的涂布步骤而实现的。

    Method for improved Fischer-Tropsch catalyst stability and higher stable syngas conversion
    10.
    发明授权
    Method for improved Fischer-Tropsch catalyst stability and higher stable syngas conversion 失效
    改善费 - 托催化剂稳定性和更稳定合成气转化的方法

    公开(公告)号：US07045554B2

    公开(公告)日：2006-05-16

    申请号：US10654087

    申请日：2003-09-03

    申请人： Ajoy P. Raje ,  Rafael Espinoza

    发明人： Ajoy P. Raje ,  Rafael Espinoza

    IPC分类号： C07C27/00

    CPC分类号： C10G2/332 ,  B01J23/75 ,  B01J23/76 ,  B01J35/006 ,  B01J35/023 ,  C10G2/333

    摘要： The present invention is generally related towards methods for preparing and using a more stable synthesis catalysts. In particular, the present invention is directed towards treating synthesis catalysts with low levels of oxygen to deactivate the smaller more unstable metal crystallites present in the catalyst matrix. The process can be carried out either prior to and/or simultaneously with the synthesis reaction.

    摘要翻译： 本发明通常涉及制备和使用更稳定的合成催化剂的方法。 特别地，本发明涉及处理具有低水平氧的合成催化剂，以使催化剂基质中存在的更不稳定的更小的金属微晶失活。 该方法可以在合成反应之前和/或同时进行。