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1.发明授权
公开(公告)号：US5292701A
公开(公告)日：1994-03-08
申请号：US698524
申请日：1991-05-10
申请人： Rimantas Glemza , Yves O. Parent
发明人： Rimantas Glemza , Yves O. Parent
CPC分类号： B01J37/036 , B01J27/16 , C01B25/36 , C08F4/02 , B01J35/10 , B01J35/1019 , B01J35/1047 , B01J35/1061
摘要： Aluminum phosphate compositions are provided which are characterized simultaneously by high porosity and phosphorous-to-aluminum ratios of approximately 1.0. The high porosity of these compositions is a function of high pore volume coupled with low surface area, resulting in high average pore diameter. These materials have excellent properties as catalysts and catalyst supports. Methods of making the compositions are also provided.
摘要翻译： 提供了磷酸铝组合物，其同时由高孔隙率和约0.005的磷与铝的比率表征。 这些组合物的高孔隙率是具有高孔体积和低表面积的功能，导致高的平均孔径。 这些材料作为催化剂和催化剂载体具有优异的性能。 还提供了制备组合物的方法。
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公开(公告)号：USRE34911E
公开(公告)日：1995-04-18
申请号：US85656
申请日：1993-07-01
申请人： Rimantas Glemza
发明人： Rimantas Glemza
CPC分类号： B01J27/16 , B01J37/036 , C01B25/36 , C08F4/02 , B01J35/10 , B01J35/1019 , B01J35/1047 , B01J35/1061
摘要： Aluminum phosphate compositions arc provided which are characterized simultaneously by high porosity and phosphorous-to-aluminum ratios of approximately 1.0. The high porosity of these compositions is a function of high pore volume coupled with low surface area, resulting in high average pore diameter. These materials have excellent properties as catalysts and catalyst supports.
摘要翻译： 提供了磷酸铝组合物，其同时表征为高孔隙率和约0.005的磷与铝的比率。 这些组合物的高孔隙率是具有高孔体积和低表面积的功能，导致高的平均孔径。 这些材料作为催化剂和催化剂载体具有优异的性能。
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公开(公告)号：US5714424A
公开(公告)日：1998-02-03
申请号：US370045
申请日：1995-01-09
申请人： John L. Warthen , Rimantas Glemza
发明人： John L. Warthen , Rimantas Glemza
IPC分类号： C08F4/02 , C08F4/22 , C08F10/00 , C08F210/16 , B01J31/00
CPC分类号： C08F210/16 , C08F10/00
摘要： The present invention encompasses a monolithic multi-component composite polyolefin catalyst particle comprising at least two distinct supported catalyst components wherein each catalyst component is capable of producing a resin having a melt index different from at least one other catalyst component under constant reaction conditions. Methods of producing and using the multi-component catalyst are disclosed.
摘要翻译： 本发明包括一种整体式多组分复合聚烯烃催化剂颗粒，其包含至少两种不同的负载催化剂组分，其中每个催化剂组分能够在恒定的反应条件下产生具有与至少一种其它催化剂组分不同的熔体指数的树脂。 公开了生产和使用多组分催化剂的方法。
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公开(公告)号：US4260396A
公开(公告)日：1981-04-07
申请号：US869402
申请日：1978-01-16
申请人： Rimantas Glemza
发明人： Rimantas Glemza
IPC分类号： C09K3/14 , H01L21/304 , H01L21/306
CPC分类号： H01L21/30625 , C09K3/1463
摘要： A composition for polishing silicon and germanium comprises a synthetic amorphous silica polishing agent and a suspending agent selected from the group consisting of water-soluble carboxypolymethylene gums and xanthum gums. The composition may be used for polishing in the form of an aqueous alkaline slurry.
摘要翻译： 用于研磨硅和锗的组合物包括合成的无定形二氧化硅抛光剂和选自水溶性羧基聚亚甲基树胶和黄原胶的悬浮剂。 该组合物可用于以碱性水溶液的形式进行抛光。
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5.发明授权Coordination catalyst systems employing chromium support-agglomerate and method of their preparation 有权使用铬载体 - 附聚物的配位催化剂体系及其制备方法公开(公告)号：US06946420B2
公开(公告)日：2005-09-20
申请号：US10120314
申请日：2002-04-10
IPC分类号： C08F4/02 , C08F4/70 , C08F10/02 , C08F110/02 , B01J31/18
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F2410/04 , C08F4/69 , C08F4/025 , C08F2500/04 , C08F2500/12 , C08F2500/18 , C08F4/7042
摘要： The present invention is directed to a coordinating catalyst system comprising at least one pre-catalyst selected from late transition metal bidentate or tridentate ligand containing compounds, at least one support-agglomerate having chromium immobilized thereto (e.g., spray dried silica/clay agglomerate), and optionally at least one organometallic compound in controlled amounts, and methods for preparing the same. The resulting catalyst system exhibits enhanced activity for polymerizing olefins and yields polymer products having very good morphology.
摘要翻译： 本发明涉及一种配位催化剂体系，其包含至少一种选自后过渡金属二齿或三齿配体的化合物的预催化剂，至少一种固定有铬的载体 - 附聚物（例如喷雾干燥二氧化硅/粘土附聚物） 和任选的至少一种受控量的有机金属化合物及其制备方法。 所得到的催化剂体系表现出提高聚合烯烃的活性并产生具有非常好的形态的聚合物产物。
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公开(公告)号：US4303641A
公开(公告)日：1981-12-01
申请号：US909149
申请日：1978-05-24
IPC分类号： C01B33/157 , A61K8/00 , A61K8/25 , A61Q11/00 , B65D5/46 , B65D5/475 , B65D5/62 , B65D5/64 , A61K7/16
CPC分类号： A61K8/042 , A61K8/25 , A61Q11/00 , A61K2800/412
摘要： Dentifrice compositions containing a hydrous silica gel having a water content of from about 20 to about 60 weight percent are disclosed. The abrasiveness of the gel is increased by contacting the gel with an alkaline medium to provide a gel pH of about 6 to about 10 and/or preparing the gel by drying and grinding a silica hydrogel that has been washed with an aqueous acidic solution having a temperature of from about 80.degree. to about 100.degree. F.
摘要翻译： 公开了含有水含量为约20至约60重量％的含水硅胶的牙粉组合物。 通过使凝胶与碱性介质接触以提供约6至约10的凝胶pH和/或通过干燥和研磨已经用具有下列物质的酸性水溶液洗涤的二氧化硅水凝胶来制备凝胶来增加凝胶的磨损性 温度为约80°至约100°F
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7.发明授权Chromium support-agglomerate-transition metal polymerization catalysts and processes utilizing same 有权铬载体 - 附聚物 - 过渡金属聚合催化剂及其利用方法公开(公告)号：US06958375B2
公开(公告)日：2005-10-25
申请号：US10120310
申请日：2002-04-10
CPC分类号： C08F110/02 , C08F4/606 , C08F2410/04 , C08F4/70 , C08F4/69 , C08F4/025 , C08F2500/01 , C08F2500/12 , C08F2500/18
摘要： The present invention is directed to a novel one-step method for forming a supported catalyst complex of high activity by substantially simultaneously contacting a bidentate or tridentate ligand forming compound, a transition metal compound and a chromium immobilized Lewis acid support-agglomerate. The catalyst can be formed prior to polymerization of olefins or within the polymerization reaction zone.
摘要翻译： 本发明涉及通过基本上同时接触二齿或三齿配体形成化合物，过渡金属化合物和固定有铬的路易斯酸载体 - 附聚物来形成具有高活性的负载型催化剂络合物的新型一步法。 催化剂可以在烯烃聚合之前或在聚合反应区内形成。
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公开(公告)号：US06670302B2
公开(公告)日：2003-12-30
申请号：US10285035
申请日：2002-10-31
申请人： Rimantas Glemza , Dean A. Denton
发明人： Rimantas Glemza , Dean A. Denton
IPC分类号： B01J2108
CPC分类号： C08F10/02 , B01J21/08 , B01J23/26 , B01J35/1023 , B01J35/1047 , B01J35/108 , B01J37/036 , C08F110/02 , C08F4/24 , C08F4/025 , C08F2500/12
摘要： High melt index polyolefins have been obtained with chromium silica catalysts under conventional polymerization conditions without the use of titanium or other additives. The useful chromium silica catalysts have a pore volume in the range of 1.9-2.9 cc/g and a narrow pore size distribution. The silica is a silica gel preferably obtained from a low solids, rapid gelation process.
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9.发明授权公开(公告)号：US06734131B2
公开(公告)日：2004-05-11
申请号：US10120289
申请日：2002-04-10
IPC分类号： B01J2116
CPC分类号： C08F10/00 , C08F110/02 , C08F4/025 , C08F4/69 , C08F2500/05 , C08F2500/18
摘要： A chromium containing catalyst wherein the chromium atom is in one of its higher valence states and is immobilized to a support-agglomerate composed of at least one inorganic oxide component and at least one ion-containing layered component.
摘要翻译： 一种含铬催化剂，其中铬原子处于其较高价态之一，并固定在由至少一种无机氧化物组分和至少一种含离子的层状组分组成的载体 - 附聚物上。
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公开(公告)号：US5030431A
公开(公告)日：1991-07-09
申请号：US362545
申请日：1989-06-07
申请人： Rimantas Glemza
发明人： Rimantas Glemza
CPC分类号： B01J27/16 , B01J23/26 , B01J29/83 , B01J29/84 , B01J35/1019 , B01J35/1047 , B01J35/1061 , B01J37/036 , C01B25/36 , C08F210/02 , C08F4/02 , B01J35/10 , C08F210/16
摘要： Aluminum phosphate compositions are provided which are characterized simultaneously by high porosity and phosphorous-to-aluminum ratios of approximately 1.0. The high porosity of these compositions is a function of high pore volume coupled with low surface area, resulting in high average pore diameter. These materials have excellent properties as catalysts and catalyst supports.
摘要翻译： 提供了磷酸铝组合物，其同时由高孔隙率和约0.005的磷与铝的比率表征。 这些组合物的高孔隙率是具有高孔体积和低表面积的功能，导致高的平均孔径。 这些材料作为催化剂和催化剂载体具有优异的性能。
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