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1.发明授权Catalyst for the selective oxidation of sulfur compounds to elemental sulfur, process for preparing such catalyst and process for the selective oxidation of sulfur compounds to elemental sulfur 失效用于硫化合物选择性氧化成元素硫的催化剂，制备这种催化剂的方法和硫化合物选择性氧化成元素硫的方法
公开(公告)号：US5814293A
公开(公告)日：1998-09-29
申请号：US615307
申请日：1996-06-18
CPC分类号： B01J23/862 , B01J23/04 , B01J23/78 , C01B17/0456 , C01B17/0465
摘要： The invention relates to a catalyst on support for the selective oxidation of sulfur-containing compounds to elemental sulfur, comprising at least one catalytically active material applied to a support material, this catalyst being obtainable by applying the catalytically active material to a support material which comprises at least one alkali metal promotor.
摘要翻译： PCT No.PCT / NL94 / 00226 Sec。 371日期1996年6月18日 102（e）1996年6月18日PCT 1994年9月16日PCT PCT。 出版物WO95 / 07856 日期1995年3月23日本发明涉及一种用于将含硫化合物选择性氧化成元素硫的催化剂，其包含施加到载体材料上的至少一种催化活性材料，该催化剂可通过将催化活性材料施用于 包含至少一种碱金属促进剂的载体材料。
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公开(公告)号：US20120039781A1
公开(公告)日：2012-02-16
申请号：US13203291
申请日：2010-02-25
IPC分类号： B01D53/44
CPC分类号： B01D53/885 , B01D2255/1021 , B01D2255/1023 , B01D2257/302 , B01D2257/306 , B01D2257/708 , B01D2257/90
摘要： The present invention is directed to a process and a reactor for removing organic compounds from gas flows, in which process the said gas flow is passed through a first compartment of a multi-compartment reactor, which reactor comprises at least one first compartment and at least one second compartment, which first and second compartments are in heat exchanging relationship with each other through a joint, gas-tight wall, and in which first compartment the gas flow is heated by heat exchange with the said second compartment, passing the heated gas flow to the second compartment, further heating the gas flow entering the second compartment either by adding additional combustible gas or electric heating, and passing the heated gas through the second compartment over a catalytic oxidation catalyst to combust the organic compounds, whereby both the first and the second compartment are filled with porous sintered metal material, which is in heat exchanging relationship to the said joint wall, whereby the metal material in the second compartment is provided with the said oxidation catalyst.
摘要翻译： 本发明涉及一种用于从气流中除去有机化合物的方法和反应器，其中所述气流通过多室反应器的第一隔室，该反应器包括至少一个第一室和至少 一个第二隔室，其中第一和第二隔室通过接头，气密壁彼此热交换，并且其中第一隔室通过与所述第二隔室的热交换来加热气流，使加热的气流 通过添加额外的可燃气体或电加热，进一步加热进入第二隔室的气流，并将加热的气体通过第二隔室通过催化氧化催化剂以燃烧有机化合物，由此第一和第二隔室 第二隔室装有与所述关节瓦片热交换关系的多孔烧结金属材料 1，由此第二隔室中的金属材料设置有所述氧化催化剂。
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公开(公告)号：US20120020874A1
公开(公告)日：2012-01-26
申请号：US13203285
申请日：2010-02-25
IPC分类号： C01B3/32
CPC分类号： H01M8/0612 , B01J8/04 , B01J8/0492 , B01J8/0496 , B01J23/40 , B01J37/0219 , B01J37/0225 , B01J2208/00309 , C01B3/12 , C01B3/22 , C01B3/583 , C01B2203/0277 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0827 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1223 , C01B2203/82
摘要： The invention is directed to a process for producing hydrogen from methanol, comprising providing at least one flow of methanol and (1) catalytically converting part of the methanol or a fuel gas with air oxygen to carbon dioxide and water, while generating heat and (2) catalytically converting the methanol or the remaining part of the methanol at elevated temperature to hydrogen and carbon monoxide, followed by conversion of the carbon monoxide with water to hydrogen and carbon dioxide, wherein the heat generated in step (1) is sufficient to produce the elevated temperature required in step (2), wherein both steps (1) and (2) are carried out in a bed of sintered metal particles, the bed of sintered metal in step (2) having a surface that is catalytically active for the conversion of methanol to hydrogen, and wherein the beds of sintered metal particles are in heat exchanging relationship.
摘要翻译： 本发明涉及从甲醇生产氢气的方法，包括提供至少一个甲醇流和（1）在产生热量的同时，将部分甲醇或燃料气体与空气氧气一起催化转化为二氧化碳和水，和（2 ）将升高的甲醇或其余部分的甲醇催化转化成氢气和一氧化碳，然后将一氧化碳与水一起转化为氢气和二氧化碳，其中在步骤（1）中产生的热足以产生 步骤（2）中所需的高温，其中步骤（1）和（2）在烧结金属颗粒床中进行，步骤（2）中的烧结金属床具有对于转化具有催化活性的表面 的甲醇转化成氢，并且其中烧结金属颗粒的床处于热交换关系。
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公开(公告)号：US06187710B1
公开(公告)日：2001-02-13
申请号：US08793684
申请日：1997-11-10
IPC分类号： B01J2116
CPC分类号： B01J29/049 , B01J21/16 , B01J37/0215 , C01B33/40 , C01B33/405 , C07C2/66 , C07C2/861 , C07C4/06 , C07C2521/16 , C07C15/16
摘要： Synthetic clay minerals are made up of elementary three-layer platelets consisting of a central layer of octahedrally oxygen-surrounded metal ions (octahedron layer), which layer is surrounded by two tetrahedrally surrounded, silicon atom-containing layers (tetrahedron layers), a number of such elementary platelets being optionally stacked. The dimensions of the clay platelets vary from 0.01 &mgr;m to 1 &mgr;m, the number of the stacked elementary three-layer platelets varies from on average one platelet to twenty platelets, while in the octahedron layer at most 30 at. % of the metal ions has been replaced by ions of a lower valency and in the tetrahedron layers at most 15 at. % of the silicon ions has been replaced by ions of a lower valency, such a replacement having taken place in at least one of these layers and these layers having a deficiency of positive charge because of the replacement. They are prepared by bringing the pH of an aqueous liquid containing the components of the clay to a value of 3-9 and the temperature of the liquid to a value of from 60 to 350° C. and maintaining it at said value for the time required for the reaction, the pH being maintained at a value within said range.
摘要翻译： 合成粘土矿物由基本的三层血小板组成，由三层氧包围的金属离子（八面体层）组成，该层由两个四面体包围的含硅原子的层（四面体层）包围， 的这种基本血小板可选地堆叠。 粘土血小板的尺寸从0.01mum到1um不等，层叠的基本三层血小板的数量从平均一个血小板变化到二十个血小板，而在八面体层中最多为30个。 ％的金属离子已被低价离子替代，并且在四面体层中最多为15个。 硅离子的百分比已经被较低价的离子代替，这种替代物已经发生在这些层中的至少一个层中，并且这些层由于更换而具有正电荷不足。 它们是通过将含有粘土成分的含水液体的pH值设为3-9，液体的温度为60-350℃，并将其保持在所述值的时间 反应所需的pH值保持在所述范围内。
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公开(公告)号：US07291320B2
公开(公告)日：2007-11-06
申请号：US10954043
申请日：2004-09-29
IPC分类号： C01B17/04
CPC分类号： C01B17/0469
摘要： A process for the selective oxidation of hydrogen sulphide in a hydrogen sulphide containing feed gas to elemental sulphur, wherein the hydrogen sulphide containing feed gas (3), an inert liquid medium (5), and a molecular-oxygen containing gas (4) are supplied to a reaction zone (1) comprising at least one catalytic zone (2) comprising an oxidation catalyst to form elemental sulphur and a gaseous stream depleted in hydrogen sulphide (8), in which process the oxidation catalyst of each catalytic zone (2) is contacted with hydrogen sulphide and/or molecular-oxygen in the presence of inert liquid medium at a temperature in the range of from 120 to 160° C., under such conditions that the elemental sulphur formed is essentially in liquid form and is removed from the reaction zone with the inert liquid medium.
摘要翻译： 一种在含硫化氢的进料气体中将硫化氢选择性氧化成元素硫的方法，其中含硫化氢的进料气体（3），惰性液体介质（5）和含分子氧的气体（4）是 供应到包含至少一个包含氧化催化剂以形成元素硫的催化剂区域（2）的反应区（1）和贫硫化氢气体（8）的反应区（8），其中每个催化区（2）的氧化催化剂， 在惰性液体介质存在下，在120至160℃的温度范围内与硫化氢和/或分子氧接触，使得形成的元素硫基本上为液体形式，并从 反应区用惰性液体介质。
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公开(公告)号：US09101880B2
公开(公告)日：2015-08-11
申请号：US13203291
申请日：2010-02-25
CPC分类号： B01D53/885 , B01D2255/1021 , B01D2255/1023 , B01D2257/302 , B01D2257/306 , B01D2257/708 , B01D2257/90
摘要： The present invention is directed to a process and a reactor for removing organic compounds from gas flows, in which process the said gas flow is passed through a first compartment of a multi-compartment reactor, which reactor comprises at least one first compartment and at least one second compartment, which first and second compartments are in heat exchanging relationship with each other through a joint, gas-tight wall, and in which first compartment the gas flow is heated by heat exchange with the said second compartment, passing the heated gas flow to the second compartment, further heating the gas flow entering the second compartment either by adding additional combustible gas or electric heating, and passing the heated gas through the second compartment over a catalytic oxidation catalyst to combust the organic compounds, whereby both the first and the second compartment are filled with porous sintered metal material, which is in heat exchanging relationship to the said joint wall, whereby the metal material in the second compartment is provided with the said oxidation catalyst.
摘要翻译： 本发明涉及一种用于从气流中除去有机化合物的方法和反应器，其中所述气流通过多室反应器的第一隔室，该反应器包括至少一个第一室和至少 一个第二隔室，其中第一和第二隔室通过接头，气密壁彼此热交换，并且其中第一隔室通过与所述第二隔室的热交换来加热气流，使加热的气流 通过添加另外的可燃气体或电加热，进一步加热进入第二隔室的气流，并将加热的气体通过第二隔室通过催化氧化催化剂以燃烧有机化合物，由此第一和第二隔室 第二隔室装有与所述关节瓦片热交换关系的多孔烧结金属材料 1，由此第二隔室中的金属材料设置有所述氧化催化剂。
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7.发明授权公开(公告)号：US06919296B2
公开(公告)日：2005-07-19
申请号：US09764001
申请日：2001-01-17
CPC分类号： B01J23/76 , C01B17/0465 , Y10S502/514 , Y10S502/517
摘要： The invention provides a catalyst, a method for making the catalyst and a method for using the catalyst to promote the selective oxidation of hydrogen sulfide into elemental sulfur. The catalyst may be prepared by contacting a catalyst support, such as silica, with a mixed oxide having atomically mixed iron ions and zinc ions, to produce a support material impregnated with a mixed oxide having atomically mixed iron ions and zinc ions in an oxidic lattice. This impregnated catalyst support is then dried and calcined, preferably with chloride ions present, to produce a catalyst of an iron and zinc oxide mixture supported on silica. It has been found that when chloride is added to the impregnated catalyst support prior to calcination and drying, the sintering of the iron and zinc can be controlled more easily and the formation of iron and zinc oxide is promoted. It has also been found that the catalyst of the invention exhibits improved selectivity characteristics when compared to a catalyst prepared without the chloride.
摘要翻译： 本发明提供催化剂，制备催化剂的方法和使用催化剂促进硫化氢选择性氧化成元素硫的方法。 催化剂可以通过使诸如二氧化硅的催化剂载体与具有原子混合的铁离子和锌离子的混合氧化物接触来制备，以产生浸渍有氧化晶格中具有原子混合的铁离子和锌离子的混合氧化物的载体材料 。 然后将该浸渍的催化剂载体干燥并煅烧，优选用氯离子存在，以产生负载在二氧化硅上的铁和氧化锌混合物的催化剂。 已经发现，当在煅烧和干燥之前将氯化物加入到浸渍的催化剂载体中时，可以更容易地控制铁和锌的烧结并促进铁和氧化锌的形成。 还已经发现，与不用氯化物制备的催化剂相比，本发明的催化剂表现出改进的选择性特性。
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公开(公告)号：US6165428A
公开(公告)日：2000-12-26
申请号：US349319
申请日：1999-07-08
IPC分类号： B01D53/04 , B01D53/46 , B01J20/06 , B01J20/08 , B01J20/10 , B01J20/18 , B01J20/28 , C01B3/56 , C10K1/20 , C10K1/32 , B01D47/00 , B01D53/02 , B01D59/26
CPC分类号： B01D53/02 , B01D53/04 , B01D53/46 , B01D2253/108 , B01D2253/1085 , B01D2253/30 , B01D2253/308 , B01D2253/311 , B01J20/08 , B01J20/103 , B01J20/183 , B01J20/28014 , B01J20/2803 , B01J20/28069 , B01J20/28078 , C01B3/56 , C01B2203/043 , C01B2203/0465 , C01B2203/0475 , C01B2203/048 , C01B2203/0485 , C10K1/32 , Y10S95/902
摘要： A process is provided for the removal of metal carbonyl from gaseous streams in the presence of hydrogen sulphide and/or water using a hydrophobic porous adsorbent with an accessible pore volume for pore sizes between 0.55 and 4 nm of at least 0.005 ml/g.
摘要翻译： 提供了一种用于在硫化氢和/或水存在下从气流中除去金属羰基的方法，该疏水性多孔吸附剂具有至少0.005ml / g的孔隙在0.55和4nm之间的可及孔体积。
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公开(公告)号：US5986110A
公开(公告)日：1999-11-16
申请号：US824506
申请日：1997-03-26
IPC分类号： B01J27/198 , C07B33/00 , C07C51/215 , C07C51/25 , C07C51/31 , C07D307/60
CPC分类号： C07B33/00 , C07C51/215 , C07C51/25 , C07C51/252 , C07C51/313 , B01J27/198
摘要： The invention relates to a heterogeneous vanadium-phosphorus oxide catalyst system for the selective oxidation of hydrocarbons, which may or may not be saturated, comprising a support based on one or more metal oxides, and vanadium-phosphorus oxide in an amount of from 0.01 to 45 wt. %, based on the weight of the catalyst and calculated as (VO).sub.2 P.sub.2 O.sub.7, to a process for the selective oxidation of an organic compound in the presence of a vanadium-phosphorus oxide catalyst, which process comprises an oxidation and a reduction phase, wherein a hydrocarbon is contacted with said catalyst in the reduction phase and in oxidized or non-oxidized form is adsorbed to the catalyst, whereafter the thus loaded catalyst is brought into the oxidation phase, the desired product is formed in the presence of gaseous oxygen and subsequently separated.
摘要翻译： 本发明涉及用于选择性氧化烃的非均相钒 - 磷氧化物催化剂体系，其可以饱和或不饱和，其包含基于一种或多种金属氧化物的载体，以及含量为0.01〜 45重量％ ％，基于催化剂的重量计算为（VO）2 P 2 O 7，在钒 - 磷氧化物催化剂存在下选择性氧化有机化合物的方法，该方法包括氧化还原相，其中 烃在还原阶段与所述催化剂接触，氧化或非氧化形式被吸附到催化剂上，然后使如此负载的催化剂进入氧化阶段，在气态氧存在下形成所需产物 分开
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公开(公告)号：US08617511B2
公开(公告)日：2013-12-31
申请号：US13203285
申请日：2010-02-25
CPC分类号： H01M8/0612 , B01J8/04 , B01J8/0492 , B01J8/0496 , B01J23/40 , B01J37/0219 , B01J37/0225 , B01J2208/00309 , C01B3/12 , C01B3/22 , C01B3/583 , C01B2203/0277 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0827 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1223 , C01B2203/82
摘要： The invention is directed to a process for producing hydrogen from methanol, comprising providing at least one flow of methanol and (1) catalytically converting part of the methanol or a fuel gas with air oxygen to carbon dioxide and water, while generating heat and (2) catalytically converting the methanol or the remaining part of the methanol at elevated temperature to hydrogen and carbon monoxide, followed by conversion of the carbon monoxide with water to hydrogen and carbon dioxide, wherein the heat generated in step (1) is sufficient to produce the elevated temperature required in step (2), wherein both steps (1) and (2) are carried out in a bed of sintered metal particles, the bed of sintered metal in step (2) having a surface that is catalytically active for the conversion of methanol to hydrogen, and wherein the beds of sintered metal particles are in heat exchanging relationship.
摘要翻译： 本发明涉及从甲醇生产氢气的方法，包括提供至少一个甲醇流和（1）在产生热量的同时，将部分甲醇或燃料气体与空气氧气一起催化转化为二氧化碳和水，和（2 ）将升高的甲醇或其余部分的甲醇催化转化成氢气和一氧化碳，然后将一氧化碳与水一起转化为氢气和二氧化碳，其中在步骤（1）中产生的热足以产生 步骤（2）中所需的高温，其中步骤（1）和（2）在烧结金属颗粒床中进行，步骤（2）中的烧结金属床具有对于转化具有催化活性的表面 的甲醇转化成氢，并且其中烧结金属颗粒的床处于热交换关系。
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