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26 条记录 (耗时 0.142 秒)

    Process for the production of oligomeric polyisocyanates and their use in the production of polyurethane plastics
    1.
    发明授权
    Process for the production of oligomeric polyisocyanates and their use in the production of polyurethane plastics 失效
    制备低聚多异氰酸酯的方法及其在聚氨酯塑料生产中的应用

    公开(公告)号：US4614785A

    公开(公告)日：1986-09-30

    申请号：US765472

    申请日：1985-08-14

    申请人： Roland Richter ,  Hanns P. Muller ,  Werner Kubitza ,  Theodor Engbert ,  Gerhard Mennicken

    发明人： Roland Richter ,  Hanns P. Muller ,  Werner Kubitza ,  Theodor Engbert ,  Gerhard Mennicken

    IPC分类号： C08G18/00 ,  B01J31/00 ,  C07B61/00 ,  C07D251/34 ,  C08G18/02 ,  C08G18/79 ,  C08G18/80

    CPC分类号： C07D251/34 ,  C08G18/79

    摘要： The present invention relates to a process for the production of oligomeric polyisocyanates by the dimerization or trimerization of a portion of the isocyanate groups in organic polyisocyanates in the presence of tertiary phosphines or in the presence of a peralkylated phosphorus acid triamides as catalyst, followed by termination of the dimerization and/or trimerization reaction at the required degree of oligomerization by the addition of a catalyst poison, characterized in that a sulfonyl isocyanate is used as the catalyst poison.The present invention also relates to the use of the oligomeric polyisocyanates obtained by this process, optionally in admixture with unreacted starting polyisocyanate or optionally blocked by blocking agents for isocyanate groups, as the polyisocyanate component in the production of polyurethane plastics.

    摘要翻译： 本发明涉及通过在有机多异氰酸酯存在下在有机多异氰酸酯存在下或在作为催化剂的全烷基化的磷酸三酰胺存在下，将部分异氰酸酯基团二聚或三聚制备低聚多异氰酸酯的方法，然后终止 的二聚和/或三聚反应在所需的低聚度下通过加入催化剂毒物，其特征在于使用磺酰基异氰酸酯作为催化剂毒物。 本发明还涉及通过该方法获得的低聚多异氰酸酯作为聚氨酯塑料生产中的多异氰酸酯组分，任选与未反应的起始多异氰酸酯混合或任选地通过异氰酸酯基团的封闭剂封闭。

    Isocyanurate group-containing polyisocyanates
    3.
    发明授权
    Isocyanurate group-containing polyisocyanates 失效
    含异氰脲酸酯基的多异氰酸酯

    公开(公告)号：US4851531A

    公开(公告)日：1989-07-25

    申请号：US74380

    申请日：1987-07-16

    申请人： Reinhard Halpaap ,  Gerhard Klein ,  Roland Richter ,  Hanns P. Muller ,  Josef Pedain ,  Hans-Joachim Kreuder

    发明人： Reinhard Halpaap ,  Gerhard Klein ,  Roland Richter ,  Hanns P. Muller ,  Josef Pedain ,  Hans-Joachim Kreuder

    IPC分类号： C08G18/00 ,  C07D251/34 ,  C08G18/02 ,  C08G18/79 ,  C09D5/46 ,  C09D175/00 ,  C09D175/12

    CPC分类号： C08G18/792 ,  C07D251/34 ,  C08G2150/20

    摘要： The present invention is directed to isocyanato isocyanurates prepared from diisocyanates which contain a sterically unhindered isocyanate group bound to a primary aliphatic carbon atom and a sterically hindered isocyanate group which is bound to a tertiary carbon atom forming part of a cycloaliphatic ring system, said diisocyanate having an NCO content of about 20 to 50% by weight. The present invention is further directed to a process for preparing these isocyanato isocyanurates by catalytic trimerization and the use of the isocyanato isocyanurates in a process for the production of polyisocyanate polyaddition products, preferably two-component polyurethane stoving lacquers.

    摘要翻译： 本发明涉及由二异氰酸酯制备的异氰酸根合异氰脲酸酯，该二异氰酸酯包含与主要脂族碳原子结合的空间上不受阻碍的异氰酸酯基团和与形成脂环族环系的一部分的叔碳原子结合的空间位阻异氰酸酯基团，所述二异氰酸酯具有 约20至50重量％的NCO含量。 本发明还涉及一种通过催化三聚制备这些异氰酸酯异氰脲酸酯的方法，以及在制备多异氰酸酯加聚产物的方法中使用异氰酸酯基异氰脲酸酯的方法，优选为双组分聚氨酯烘烤漆。

    Process for the preparation of mixed trimers from organic isocyanates, the mixed trimers obtained according to the process and the use thereof for the production of polyurethanes
    5.
    发明授权
    Process for the preparation of mixed trimers from organic isocyanates, the mixed trimers obtained according to the process and the use thereof for the production of polyurethanes 失效
    从有机异氰酸酯制备混合三聚物的方法，根据该方法获得的混合三聚物及其在生产聚氨酯中的用途

    公开(公告)号：US4518761A

    公开(公告)日：1985-05-21

    申请号：US439086

    申请日：1982-11-04

    申请人： Roland Richter ,  Hanns P. Muller ,  Kuno Wagner ,  Bernd Riberi ,  Jurg Frohlich

    发明人： Roland Richter ,  Hanns P. Muller ,  Kuno Wagner ,  Bernd Riberi ,  Jurg Frohlich

    IPC分类号： C07D251/34 ,  C08G18/00 ,  C08G18/79 ,  C08G18/70

    CPC分类号： C07D251/34 ,  C08G18/791 ,  Y10T428/22

    摘要： The present invention is directed to a new process for the preparation of mixed trimers by at least partly trimerizing the isocyanate groups of at least two organic isocyanates of a reactivity which differs in the sense of the trimerization reaction, in the presence of trimerization catalysts and optionally interrupting the trimerization reaction at the respectively desired degree of trimerization, in which process the less reactive isocyanate component is introduced, polymerization is then commenced in the presence of the catalyst with the trimerization of at least 0.1% of the isocyanate groups and the more reactive isocyanate component is finally metered into the reaction mixture thus obtained; the mixed trimers obtained according to this process; and the use of the mixed trimers having free isocyanate groups obtained by this process, optionally in a form blocked by blocking agents for organic polyisocyanates, as a starting material for the production of polyurethane plastics materials.

    摘要翻译： 本发明涉及一种新的制备混合三聚体的方法，该方法是在三聚催化剂存在下，至少部分地将三聚反应意义上的至少两种有机异氰酸酯的反应性的异氰酸酯基团三聚，其反应性不同， 在分别期望的三聚程度下中断三聚反应，其中引入反应活性较低的异氰酸酯组分较少，然后在催化剂存在下开始聚合，三聚化至少为0.1％的异氰酸酯基团，反应活性较高的异氰酸酯 将组分最终计量加入由此获得的反应混合物中; 根据该方法得到的混合三聚物; 以及使用通过该方法获得的具有游离异氰酸酯基团的混合三聚体，任选地以用于有机聚异氰酸酯的封闭剂封闭的形式作为用于制备聚氨酯塑料材料的起始材料。

    Preparation of hydroxyl group-containing alkoxylation products of organic carboxylic acids
    9.
    发明授权
    Preparation of hydroxyl group-containing alkoxylation products of organic carboxylic acids 失效
    有机羧酸的含羟基烷氧基化产物的制备

    公开(公告)号：US4645817A

    公开(公告)日：1987-02-24

    申请号：US722567

    申请日：1985-04-11

    申请人： Joachim Probst ,  Michael Sonntag ,  Roland Richter ,  Hanns P. Muller

    发明人： Joachim Probst ,  Michael Sonntag ,  Roland Richter ,  Hanns P. Muller

    IPC分类号： C08G18/00 ,  C07B31/00 ,  C07B41/12 ,  C07C67/00 ,  C08F8/00 ,  C08G18/42 ,  C08G18/48 ,  C08G18/62 ,  C08G65/10 ,  C08G65/26 ,  C08G18/80 ,  C08F20/62 ,  C08G18/16 ,  C08G63/42

    CPC分类号： C08G65/2645 ,  C08F8/00 ,  C08G18/6258 ,  C08G65/105 ,  C08G65/2615 ,  C08G65/2669

    摘要： The present invention relates to a process for the preparation of alkoxylation products of organic carboxylic acids containing alcoholic hydroxyl groups by the reaction of any organic compounds containing at least one carboxyl group with alkylene oxides in an alkoxylation reaction in the presence of catalysts, characterized in that the catalysts used are phase transfer catalysts selected from the group consisting of(a) tetraalkylammonium or tetraalkylphosphonium halides in which the sum of carbon atoms of the alkyl groups is at least 8,(b) basic alkali metal compounds converted into complexes with crown ethers and(c) complexes of (i) basic alkali metal compounds and (ii) acyclic organic compounds containing at least 5 alkylene oxide units of the formula --R--O-- (R=C.sub.1 -C.sub.4 -alkylene) in the form of one or more polyether chains having at least 3 alkylene oxide units, said compounds having a molecular weight of at least 238 and containing a total of at least 40% by weight of alkylene oxide units of the type indicated in polyether chains having at least 3 alkylene oxide units.The present invention also relates to the use of these alkoxylation products for the production of polyurethanes by reaction with organic polyisocyanates.

    摘要翻译： 本发明涉及一种在催化剂存在下通过烷氧基化反应中含有至少一个羧基的任何有机化合物与烯化氧的反应来制备含醇羟基的有机羧酸的烷氧基化产物的方法，其特征在于： 所使用的催化剂是选自（a）四烷基铵或四烷基鏻卤化物的相转移催化剂，其中烷基的碳原子总数至少为8，（b）碱基碱金属化合物与冠醚转化为络合物， （c）碱性碱金属化合物和（ii）含有至少5个式-RO-（R = C 1 -C 4 - 亚烷基）的氧化烯单元的一种或多种聚醚链形式的无环有机化合物的络合物 具有至少3个烯化氧单元，所述化合物的分子量至少为238，并且含有至少40重量％的环氧烷烃 具有至少3个氧化烯单元的聚醚链中所示类型的单元。 本发明还涉及这些烷氧基化产物通过与有机多异氰酸酯反应生产聚氨酯的用途。