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    Catalysts for hydrotreatment of heavy hydrocarbon oils containing asphaltenes
    1.
    发明授权
    Catalysts for hydrotreatment of heavy hydrocarbon oils containing asphaltenes 失效
    用于加氢处理含有沥青质的重质烃油的催化剂

    公开(公告)号：US4422960A

    公开(公告)日：1983-12-27

    申请号：US210059

    申请日：1980-12-14

    申请人： Yoshimi Shiroto ,  Takeo Ono ,  Sachio Asaoka ,  Munekazu Nakamura

    发明人： Yoshimi Shiroto ,  Takeo Ono ,  Sachio Asaoka ,  Munekazu Nakamura

    IPC分类号： B01J21/00 ,  B01J23/74 ,  B01J23/85 ,  B01J23/882 ,  B01J23/887 ,  B01J35/00 ,  B01J35/10 ,  C10G45/04 ,  C10G47/10 ,  C10G55/06 ,  C10G65/04 ,  C10G65/12 ,  B01J21/04 ,  B01J23/22 ,  B01J23/24 ,  B01J27/04

    CPC分类号： B01J23/882 ,  B01J23/85 ,  B01J23/8872 ,  B01J35/10 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/108 ,  C10G2300/107

    摘要： A catalyst for hydrotreating a heavy hydrocarbon oil containing asphaltenes comprises a porous carrier composed of one or more inorganic oxides of at least one element selected from among those of Groups II, III and IV of the Periodic Table, and at least one catalytic metal component composited with the carrier. The metal of the catalytic metal component is selected from among those of Groups VB, VIB, VIII and IB of the Periodic Table. The catalyst contains about 1 to 30% by weight of such catalytic metal component and has the following pore characteristics with regard to its pores having a diameter of 75 .ANG. or more: an average pore diameter APD of about 180 to 500 .ANG., a total pore volume PV, expressed in cc/g, being equal to or greater than a value X ##EQU1## the volume of pores with a diameter of about 180 to 500 .ANG. being at least about 0.2 cc/g, the volume of pores with a diameter of at least 1,500 .ANG. being not greater than about 0.03 cc/g, and a total surface area being at least about 60 m.sup.2 /g. The catalyst has an average catalyst diameter ACD, expressed in millimeters, of not greater than a value of the formula, ACD=(APD/100).sup.0.5. Disclosed also are a method of preparing such a catalyst, and a process for hydrotreating a heavy hydrocarbon oil containing asphaltenes in the presence of such a catalyst.

    摘要翻译： 用于加氢处理含有沥青质的重烃油的催化剂包括由一种或多种选自元素周期表II，III和IV族中的至少一种元素的一种或多种无机氧化物组成的多孔载体，以及至少一种催化金属组分 与承运人。 催化金属组分的金属选自元素周期表的VB，VIB，VIII和IB族。 该催化剂含有约1至30重量％的这种催化金属组分，并且对于其直径为75埃或更高的孔具有以下孔特性：平均孔径APD为约180至500安培姆，总孔 体积PV以cc / g表示，等于或大于直径为约180至500的孔的体积至少约0.2cc / g，具有直径的孔的体积 至少1500安培角不大于约0.03cc / g，总表面积为至少约60m 2 / g。 催化剂的平均催化剂直径ACD（以毫米表示）不大于式的值ACD =（APD / 100）0.5。 还公开了制备这种催化剂的方法，以及在这种催化剂存在下，对含有沥青质的重质烃油进行加氢处理的方法。

    Hydrotreatment of heavy hydrocarbon oils containing asphaltenes, and catalysts therefor
    2.
    发明授权
    Hydrotreatment of heavy hydrocarbon oils containing asphaltenes, and catalysts therefor 失效
    含沥青质的重质烃油的加氢处理及其催化剂

    公开(公告)号：US4444655A

    公开(公告)日：1984-04-24

    申请号：US428796

    申请日：1982-09-30

    申请人： Yoshimi Shiroto ,  Takeo Ono ,  Sachio Asaoka ,  Munekazu Nakamura

    发明人： Yoshimi Shiroto ,  Takeo Ono ,  Sachio Asaoka ,  Munekazu Nakamura

    IPC分类号： B01J21/00 ,  B01J23/74 ,  B01J23/85 ,  B01J23/882 ,  B01J23/887 ,  B01J35/00 ,  B01J35/10 ,  C10G45/04 ,  C10G47/10 ,  C10G55/06 ,  C10G65/04 ,  C10G65/12

    CPC分类号： B01J23/882 ,  B01J23/85 ,  B01J23/8872 ,  B01J35/10 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/108 ,  C10G2300/107

    摘要： A catalyst for hydrotreating a heavy hydrocarbon oil containing asphaltenes comprises a porous carrier composed of one or more inorganic oxides of at least one element selected from among those of Groups II, III and IV of the Periodic Table, and at least one catalytic metal component composited with the carrier. The metal of the catalytic metal component is selected from among those of Groups VB, VIB, VIII and IB of the Periodic Table. The catalyst contains about 1 to 30% by weight of such catalytic metal component and has the following pore characteristics with regard to its pores having a diameter of 75 .ANG. or more: an average pore diameter APD of about 180 to 500 .ANG., a total pore volume PV, expressed in cc/g, being equal to or greater than a value X ##EQU1## the volume of pores with a diameter of about 180 to 500 .ANG. being at least about 0.2 cc/g, the volume of pores with a diameter of at least 1,500 .ANG. being not greater than about 0.03 cc/g, and a total surface area being at least about 60 m.sup.2 /g. The catalyst has an average catalyst diameter ACD, expressed in millimeters, of not greater than a value of the formula, ACD=(APD/100).sup.0.5. Disclosed also are a method of preparing such a catalyst, and a process for hydrotreating a heavy hydrocarbon oil containing asphaltenes in the presence of such a catalyst.

    摘要翻译： 用于加氢处理含有沥青质的重烃油的催化剂包括由一种或多种选自元素周期表II，III和IV族中的至少一种元素的一种或多种无机氧化物组成的多孔载体，以及至少一种催化金属组分 与承运人。 催化金属组分的金属选自元素周期表的VB，VIB，VIII和IB族。 该催化剂含有约1至30重量％的这种催化金属组分，并且对于其直径为75埃或更高的孔具有以下孔特性：平均孔径APD为约180至500安培姆，总孔 体积PV以cc / g表示，等于或大于直径为约180至500的孔的体积至少约0.2cc / g，具有直径的孔的体积 至少1500安培角不大于约0.03cc / g，总表面积为至少约60m 2 / g。 催化剂的平均催化剂直径ACD（以毫米表示）不大于式的值ACD =（APD / 100）0.5。 还公开了制备这种催化剂的方法，以及在这种催化剂存在下，对含有沥青质的重质烃油进行加氢处理的方法。

    Catalyst for hydrotreating heavy hydrocarbon oils and method of preparing same
    7.
    发明授权
    Catalyst for hydrotreating heavy hydrocarbon oils and method of preparing same 失效
    用于加氢处理重质烃油的催化剂及其制备方法

    公开(公告)号：US4367165A

    公开(公告)日：1983-01-04

    申请号：US210049

    申请日：1980-11-24

    申请人： Sachio Asaoka ,  Takeo Ono ,  Yoshimi Shiroto

    发明人： Sachio Asaoka ,  Takeo Ono ,  Yoshimi Shiroto

    IPC分类号： C10G49/02 ,  B01J21/14 ,  B01J21/16 ,  B01J23/00 ,  B01J23/22 ,  B01J27/12 ,  B01J27/18 ,  B01J27/198 ,  B01J35/10 ,  C10G11/02 ,  C10G45/04 ,  C10G47/12 ,  C10G49/04 ,  B01J21/00

    CPC分类号： C10G47/12 ,  B01J21/14 ,  B01J21/16 ,  B01J35/0026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  C10G11/02 ,  C10G2300/107

    摘要： A catalyst for hydrotreating a heavy hydrocarbon oil comprises a carrier which is a calcined composite of a mixture of a clay mineral consisting mainly of magnesium silicate having a double-chain structure and a pseudoboehmite which shows a powder X-ray diffraction spectrum obtained by applying a CuK.sub..alpha. ray such that the half value width of the peak on the (020) plane is between about 0.8.degree. and 4.0.degree. and the intensity of said peak is between 1.2 and 8.0 times as high as that at 2.theta.=10.degree.. At least one catalytic metal component is composited with the carrier, the metal of the catalytic metal component being selected from the group consisting of metals belonging to Groups VB, VIB, VIII and IB of the Periodic Table. Disclosed also are a method of preparing such a catalyst, and a process for the hydrotreatment of heavy hydrocarbon oils containing asphaltenes and heavy metals.

    摘要翻译： 用于加氢处理重质烃油的催化剂包括载体，其是主要由具有双链结构的硅酸镁组成的粘土矿物和假勃姆石的混合物的煅烧复合物，其显示通过施加粉末X射线衍射光谱获得的粉末X射线衍射光谱 （020）平面上的峰的半值宽度在约0.8°至4.0°之间，并且所述峰的强度在2θ= 10°时的强度在1.2至8.0倍之间。 至少一种催化金属组分与载体复合，催化金属组分的金属选自属于元素周期表的VB族，VIB族，VIII族和IB族的金属。 还公开了制备这种催化剂的方法，以及用于加氢处理含有沥青质和重金属的重质烃油的方法。

    Separator
    10.
    发明授权
    Separator 失效
    分隔器

    公开(公告)号：US5200075A

    公开(公告)日：1993-04-06

    申请号：US846198

    申请日：1992-03-05

    申请人： Seiya Otani ,  Hiroaki Taniguchi ,  Kei Yokoyama ,  Yoshimi Shiroto ,  Mitsunori Shimura ,  Osamu Akimoto ,  Masayoshi Notoya

    发明人： Seiya Otani ,  Hiroaki Taniguchi ,  Kei Yokoyama ,  Yoshimi Shiroto ,  Mitsunori Shimura ,  Osamu Akimoto ,  Masayoshi Notoya

    IPC分类号： B01D15/18

    CPC分类号： B01D15/1842 ,  B01D2215/023 ,  Y10T428/24273 ,  Y10T428/24322 ,  Y10T428/24331 ,  Y10T428/24479 ,  Y10T428/24562 ,  Y10T428/24612

    摘要： An adsorbent is charged into a horizontal type packed column having a multiplicity of packed vessels each of which is composed of a partition plate and a cylindrical body and which are connected through the partition plates, from an opening formed on the upper wall of each cylindrical body. Then, each opening is closed tightly with a detachable plug cover. The partition plate is provided with a first fluid passage through which a fluid is passed in the direction of the axis of the cylindrical body and a second fluid passage which is in communication with the first fluid passage, which extends toward the peripheral wall of the cylindrical body and which opens at the cylindrical body. This apparatus is suitable for use as a multiple-stage adsorption separator directed to a simulated moving-bed system.

    摘要翻译： 将吸附剂装入具有多个填充容器的水平型填充柱，每个填充容器由分隔板和圆柱体组成，并且通过隔板连接，从形成在每个圆柱体的上壁上的开口 。 然后，每个开口用可拆卸的插头盖紧紧地闭合。 分隔板设置有第一流体通道，流体沿着圆柱体的轴线方向通过，第二流体通道与第一流体通道连通，第二流体通道朝向圆柱体的周壁延伸 并且在圆柱体上打开。 该装置适用于指向模拟移动床系统的多级吸附分离器。