公开(公告)号：US08779600B2

公开(公告)日：2014-07-15

申请号：US13344009

申请日：2012-01-05

申请人： Son Van Nguyen ,  Griselda Bonilla ,  Alfred Grill ,  Thomas J. Haigh, Jr. ,  Satyanarayana V. Nitta

发明人： Son Van Nguyen ,  Griselda Bonilla ,  Alfred Grill ,  Thomas J. Haigh, Jr. ,  Satyanarayana V. Nitta

IPC分类号： H01L29/40

CPC分类号： H01L23/5384 ,  H01L21/02167 ,  H01L21/02274 ,  H01L21/76801 ,  H01L21/76825 ,  H01L21/76832 ,  H01L21/76834 ,  H01L23/5329 ,  H01L23/53295 ,  H01L2924/0002 ,  Y10T428/249969 ,  H01L2924/00

摘要： A dielectric stack and method of depositing the stack to a substrate using a single step deposition process. The dielectric stack includes a dense layer and a porous layer of the same elemental compound with different compositional atomic percentage, density, and porosity. The stack enhances mechanical modulus strength and enhances oxidation and copper diffusion barrier properties. The dielectric stack has inorganic or hybrid inorganic-organic random three-dimensional covalent bonding throughout the network, which contain different regions of different chemical compositions such as a cap component adjacent to a low-k component of the same type of material but with higher porosity.

摘要翻译： 一种电介质堆叠和使用单步沉积工艺将叠层沉积到衬底的方法。 电介质堆叠包括具有不同组成原子百分比，密度和孔隙率的相同元素化合物的致密层和多孔层。 该堆叠增强机械模量强度并增强氧化和铜扩散阻挡性能。 电介质叠层在整个网络中具有无机或杂化的无机 - 有机随机三维共价键，其含有不同化学组成的不同区域，例如与相同类型材料的低k组分相邻但具有较高孔隙率的盖组分 。

公开(公告)号：US20130175697A1

公开(公告)日：2013-07-11

申请号：US13344009

申请日：2012-01-05

申请人： Son Van Nguyen ,  Griselda Bonilla ,  Alfred Grill ,  Thomas J. Haigh, JR. ,  Satyanarayana V. Nitta

发明人： Son Van Nguyen ,  Griselda Bonilla ,  Alfred Grill ,  Thomas J. Haigh, JR. ,  Satyanarayana V. Nitta

IPC分类号： H01L23/538 ,  H01L21/31 ,  B32B9/04

CPC分类号： H01L23/5384 ,  H01L21/02167 ,  H01L21/02274 ,  H01L21/76801 ,  H01L21/76825 ,  H01L21/76832 ,  H01L21/76834 ,  H01L23/5329 ,  H01L23/53295 ,  H01L2924/0002 ,  Y10T428/249969 ,  H01L2924/00

摘要： A dielectric stack and method of depositing the stack to a substrate using a single step deposition process. The dielectric stack includes a dense layer and a porous layer of the same elemental compound with different compositional atomic percentage, density, and porosity. The stack enhances mechanical modulus strength and enhances oxidation and copper diffusion barrier properties. The dielectric stack has inorganic or hybrid inorganic-organic random three-dimensional covalent bonding throughout the network, which contain different regions of different chemical compositions such as a cap component adjacent to a low-k component of the same type of material but with higher porosity.

摘要翻译： 一种电介质堆叠和使用单步沉积工艺将叠层沉积到衬底的方法。 电介质堆叠包括具有不同组成原子百分比，密度和孔隙率的相同元素化合物的致密层和多孔层。 该堆叠增强机械模量强度并增强氧化和铜扩散阻挡性能。 电介质叠层在整个网络中具有无机或杂化的无机 - 有机随机三维共价键，其含有不同化学组成的不同区域，例如与相同类型材料的低k组分相邻但具有较高孔隙率的盖组分 。

公开(公告)号：US20090224374A1

公开(公告)日：2009-09-10

申请号：US12042873

申请日：2008-03-05

申请人： Ritwik Bhatia ,  Griselda Bonilla ,  Alfred Grill ,  Joshua L. Herman ,  Son Van Nguyen ,  E. Todd Ryan ,  Hosadurga Shobha

发明人： Ritwik Bhatia ,  Griselda Bonilla ,  Alfred Grill ,  Joshua L. Herman ,  Son Van Nguyen ,  E. Todd Ryan ,  Hosadurga Shobha

IPC分类号： H01L23/538 ,  H01L23/58 ,  H01L21/31 ,  H01L21/768

CPC分类号： H01L21/76834 ,  H01L21/02348 ,  H01L21/76832

摘要： A dielectric cap, interconnect structure containing the same and related methods are disclosed. The inventive dielectric cap includes a multilayered dielectric material stack wherein at least one layer of the stack has good oxidation resistance, Cu diffusion and/or substantially higher mechanical stability during a post-deposition curing treatment, and including Si—N bonds at the interface of a conductive material such as, for example, Cu. The dielectric cap exhibits a high compressive stress and high modulus and is still remain compressive stress under post-deposition curing treatments for, for example: copper low k back-end-of-line (BEOL) nanoelectronic devices, leading to less film and device cracking and improved reliability.

摘要翻译： 公开了包含相同方法和相关方法的电介质盖，互连结构。 本发明的电介质盖包括多层介电材料堆叠，其中叠层的至少一层在后沉积固化处理期间具有良好的抗氧化性，Cu扩散和/或显着更高的机械稳定性，并且包括Si-N键在 导电材料，例如Cu。 电介质盖表现出高压缩应力和高模量，并且在后沉积固化处理时仍然保持压应力，例如：铜低k后端（BEOL）纳米电子器件，导致较少的膜和器件 开裂和可靠性提高。

公开(公告)号：US20110162874A1

公开(公告)日：2011-07-07

申请号：US12683590

申请日：2010-01-07

申请人： Son Van Nguyen ,  Alfred Grill ,  Thomas J. Haigh, JR. ,  Hosadurga Shobha ,  Tuan A. Vo

发明人： Son Van Nguyen ,  Alfred Grill ,  Thomas J. Haigh, JR. ,  Hosadurga Shobha ,  Tuan A. Vo

IPC分类号： H05K1/09 ,  B05D5/12 ,  B05D3/06 ,  B05D3/04

CPC分类号： H01L21/76849 ,  H01L21/76846 ,  H01L21/76864 ,  H01L21/76867

摘要： An interconnect structure is provided that has improved electromigration resistance as well as methods of forming such an interconnect structure. The interconnect structure includes an interconnect dielectric material having a dielectric constant of about 4.0 or less. The interconnect dielectric material has at least one opening therein that is filled with a Cu-containing material. The Cu-containing material within the at least one opening has an exposed upper surface that is co-planar with an upper surface of the interconnect dielectric material. The interconnect structure further includes a composite M-MOx cap located at least on the upper surface of the Cu-containing material within the at least one opening. The composite M-MOx cap includes an upper region that is composed of the metal having a higher affinity for oxygen than copper and copper oxide and a lower region that is composed of a non-stoichiometric oxide of said metal. The interconnect structure further includes a dielectric cap located on at least an upper surface of the composite M-MOx cap.

摘要翻译： 提供了具有改进的电迁移阻力的互连结构以及形成这种互连结构的方法。 互连结构包括具有约4.0或更小的介电常数的互连电介质材料。 互连电介质材料在其中具有填充有含Cu材料的至少一个开口。 至少一个开口内的含Cu材料具有与互连电介质材料的上表面共面的暴露的上表面。 互连结构还包括至少位于至少一个开口内的含Cu材料的上表面上的复合M-MOx帽。 复合M-MOx帽包括由与氧和氧化铜相比具有比氧更高的亲和性的金属构成的上部区域和由所述金属的非化学计量氧化物构成的下部区域。 互连结构还包括位于复合M-MOx帽的至少上表面上的介电帽。

公开(公告)号：US09502288B2

公开(公告)日：2016-11-22

申请号：US13420728

申请日：2012-03-15

申请人： Son Van Nguyen ,  Alfred Grill ,  Thomas J. Haigh, Jr. ,  Hosadurga Shobha ,  Tuan A. Vo

发明人： Son Van Nguyen ,  Alfred Grill ,  Thomas J. Haigh, Jr. ,  Hosadurga Shobha ,  Tuan A. Vo

IPC分类号： H05K3/02 ,  H05K3/10 ,  H01L21/768

CPC分类号： H01L21/76849 ,  H01L21/76846 ,  H01L21/76864 ,  H01L21/76867

摘要： An interconnect structure is provided that has improved electromigration resistance as well as methods of forming such an interconnect structure. The interconnect structure includes a composite M-MOx cap located at least on the upper surface of the Cu-containing material within the at least one opening. The composite M-MOx cap includes an upper region that is composed of the metal having a higher affinity for oxygen than copper and copper oxide and a lower region that is composed of a non-stoichiometric oxide of said metal.

摘要翻译： 提供了具有改进的电迁移阻力的互连结构以及形成这种互连结构的方法。 互连结构包括至少位于至少一个开口内的含Cu材料的上表面上的复合M-MOx帽。 复合M-MOx帽包括由与氧和氧化铜相比具有比氧更高的亲和性的金属构成的上部区域和由所述金属的非化学计量氧化物构成的下部区域。

公开(公告)号：US08476743B2

公开(公告)日：2013-07-02

申请号：US13228857

申请日：2011-09-09

申请人： Son Van Nguyen ,  Alfred Grill ,  Thomas J. Haigh, Jr. ,  Sanjay Mehta

发明人： Son Van Nguyen ,  Alfred Grill ,  Thomas J. Haigh, Jr. ,  Sanjay Mehta

IPC分类号： H01L23/58 ,  H01L21/31 ,  C23C8/54 ,  B05D5/12

CPC分类号： H01L21/02112 ,  H01B3/12 ,  H01L21/02274 ,  H01L21/02318 ,  H01L21/02348 ,  H01L21/02351 ,  H01L21/76825 ,  H01L21/76826 ,  H01L21/76828 ,  H01L21/76829 ,  H01L21/76832 ,  H01L21/76834 ,  H01L23/53252 ,  H01L23/53276 ,  H01L29/1054 ,  H01L29/1606 ,  H01L29/456 ,  H01L29/4908 ,  H01L29/4983 ,  H01L29/78648 ,  H01L2924/0002 ,  H01L2924/00

摘要： A carbon-rich carbon boron nitride dielectric film having a dielectric constant of equal to, or less than 3.6 is provided that can be used as a component in various electronic devices. The carbon-rich carbon boron nitride dielectric film has a formula of CxByNz wherein x is 35 atomic percent or greater, y is from 6 atomic percent to 32 atomic percent and z is from 8 atomic percent to 33 atomic percent.

摘要翻译： 提供具有等于或小于3.6的介电常数的富碳碳氮化硼介电膜，其可用作各种电子器件中的组分。 富碳碳氮化硼电介质膜具有C x B y N z的化学式，其中x为35原子％以上，y为6原子％〜32原子％，z为8原子％〜33原子％。

公开(公告)号：US20120175023A1

公开(公告)日：2012-07-12

申请号：US13420728

申请日：2012-03-15

申请人： Son Van Nguyen ,  Alfred Grill ,  Thomas J. Haigh, JR. ,  Hosadurga Shobha ,  Tuan A. Vo

发明人： Son Van Nguyen ,  Alfred Grill ,  Thomas J. Haigh, JR. ,  Hosadurga Shobha ,  Tuan A. Vo

IPC分类号： C23C8/00 ,  C23C28/04

CPC分类号： H01L21/76849 ,  H01L21/76846 ,  H01L21/76864 ,  H01L21/76867

摘要： An interconnect structure is provided that has improved electromigration resistance as well as methods of forming such an interconnect structure. The interconnect structure includes a composite M-MOx cap located at least on the upper surface of the Cu-containing material within the at least one opening. The composite M-MOx cap includes an upper region that is composed of the metal having a higher affinity for oxygen than copper and copper oxide and a lower region that is composed of a non-stoichiometric oxide of said metal.

摘要翻译： 提供了具有改进的电迁移阻力的互连结构以及形成这种互连结构的方法。 互连结构包括至少位于至少一个开口内的含Cu材料的上表面上的复合M-MOx帽。 复合M-MOx帽包括由与氧和氧化铜相比具有比氧更高的亲和性的金属构成的上部区域和由所述金属的非化学计量氧化物构成的下部区域。

公开(公告)号：US20130062753A1

公开(公告)日：2013-03-14

申请号：US13228857

申请日：2011-09-09

申请人： Son Van Nguyen ,  Alfred Grill ,  Thomas J. Haigh, JR. ,  Sanjay Mehta

发明人： Son Van Nguyen ,  Alfred Grill ,  Thomas J. Haigh, JR. ,  Sanjay Mehta

IPC分类号： H01L23/48 ,  C09K3/00 ,  H01L21/31

CPC分类号： H01L21/02112 ,  H01B3/12 ,  H01L21/02274 ,  H01L21/02318 ,  H01L21/02348 ,  H01L21/02351 ,  H01L21/76825 ,  H01L21/76826 ,  H01L21/76828 ,  H01L21/76829 ,  H01L21/76832 ,  H01L21/76834 ,  H01L23/53252 ,  H01L23/53276 ,  H01L29/1054 ,  H01L29/1606 ,  H01L29/456 ,  H01L29/4908 ,  H01L29/4983 ,  H01L29/78648 ,  H01L2924/0002 ,  H01L2924/00

摘要： A carbon-rich carbon boron nitride dielectric film having a dielectric constant of equal to, or less than 3.6 is provided that can be used as a component in various electronic devices. The carbon-rich carbon boron nitride dielectric film has a formula of CxByNz wherein x is 35 atomic percent or greater, y is from 6 atomic percent to 32 atomic percent and z is from 8 atomic percent to 33 atomic percent.

摘要翻译： 提供具有等于或小于3.6的介电常数的富碳碳氮化硼介电膜，其可用作各种电子器件中的组分。 富碳碳氮化硼电介质膜具有C x B y N z的化学式，其中x为35原子％以上，y为6原子％〜32原子％，z为8原子％〜33原子％。

公开(公告)号：US08299365B2

公开(公告)日：2012-10-30

申请号：US12683590

申请日：2010-01-07

申请人： Son Van Nguyen ,  Alfred Grill ,  Thomas J. Haigh, Jr. ,  Hosadurga Shobha ,  Tuan A. Vo

发明人： Son Van Nguyen ,  Alfred Grill ,  Thomas J. Haigh, Jr. ,  Hosadurga Shobha ,  Tuan A. Vo

IPC分类号： H05K1/09

CPC分类号： H01L21/76849 ,  H01L21/76846 ,  H01L21/76864 ,  H01L21/76867

摘要： An interconnect structure is provided that has improved electromigration resistance as well as methods of forming such an interconnect structure. The interconnect structure includes an interconnect dielectric material having a dielectric constant of about 4.0 or less. The interconnect dielectric material has at least one opening therein that is filled with a Cu-containing material. The Cu-containing material within the at least one opening has an exposed upper surface that is co-planar with an upper surface of the interconnect dielectric material. The interconnect structure further includes a composite M-MOx cap located at least on the upper surface of the Cu-containing material within the at least one opening. The composite M-MOx cap includes an upper region that is composed of the metal having a higher affinity for oxygen than copper and copper oxide and a lower region that is composed of a non-stoichiometric oxide of said metal. The interconnect structure further includes a dielectric cap located on at least an upper surface of the composite M-MOx cap.

摘要翻译： 提供了具有改进的电迁移阻力的互连结构以及形成这种互连结构的方法。 互连结构包括具有约4.0或更小的介电常数的互连电介质材料。 互连电介质材料在其中具有填充有含Cu材料的至少一个开口。 至少一个开口内的含Cu材料具有与互连电介质材料的上表面共面的暴露的上表面。 互连结构还包括至少位于至少一个开口内的含Cu材料的上表面上的复合M-MOx帽。 复合M-MOx帽包括由与氧和氧化铜相比具有比氧更高的亲和性的金属构成的上部区域和由所述金属的非化学计量氧化物构成的下部区域。 互连结构还包括位于复合M-MOx帽的至少上表面上的介电帽。

公开(公告)号：US07737052B2

公开(公告)日：2010-06-15

申请号：US12042873

申请日：2008-03-05

申请人： Ritwik Bhatia ,  Griselda Bonilla ,  Alfred Grill ,  Joshua L. Herman ,  Son Van Nguyen ,  E. Todd Ryan ,  Hosadurga Shobha

发明人： Ritwik Bhatia ,  Griselda Bonilla ,  Alfred Grill ,  Joshua L. Herman ,  Son Van Nguyen ,  E. Todd Ryan ,  Hosadurga Shobha

IPC分类号： H01L21/31 ,  H01L21/469 ,  H01L23/58 ,  H01L23/48

CPC分类号： H01L21/76834 ,  H01L21/02348 ,  H01L21/76832

摘要： A dielectric cap, interconnect structure containing the same and related methods are disclosed. The inventive dielectric cap includes a multilayered dielectric material stack wherein at least one layer of the stack has good oxidation resistance, Cu diffusion and/or substantially higher mechanical stability during a post-deposition curing treatment, and including Si—N bonds at the interface of a conductive material such as, for example, Cu. The dielectric cap exhibits a high compressive stress and high modulus and is still remain compressive stress under post-deposition curing treatments for, for example: copper low k back-end-of-line (BEOL) nanoelectronic devices, leading to less film and device cracking and improved reliability.

摘要翻译： 公开了包含相同方法和相关方法的电介质盖，互连结构。 本发明的电介质盖包括多层介电材料堆叠，其中叠层的至少一层在后沉积固化处理期间具有良好的抗氧化性，Cu扩散和/或显着更高的机械稳定性，并且包括Si-N键在 导电材料，例如Cu。 电介质盖表现出高压缩应力和高模量，并且在后沉积固化处理时仍然保持压应力，例如：铜低k后端（BEOL）纳米电子器件，导致较少的膜和器件 开裂和可靠性提高。