摘要:
A retroreflective article comprising a substrate and a cured ceramer coating provided on at least a portion of a surface of the substrate. The coated portion of the surface is retroreflective and can be dew-resistant. The ceramer is derived from a free-radically-curable binder, colloidal inorganic oxide and fluoro/silane component comprising a hydrolyzable silane moiety and a fluorinated moiety.
摘要:
A retroreflective article comprising a substrate and a cured ceramer coating provided on at least a portion of a surface of the substrate. The coated portion of the surface is retroreflective. The coating comprises a cured ceramer composite derived from ingredients comprising a free radically curable binder precursor and a plurality of surface treated, colloidal inorganic oxide components. The colloidal inorganic oxide components are surface treated with a surface treatment agent comprising a fluoro/silane component comprising a hydrolyzable silane moiety and a fluorinated moiety, and a crosslinkable silane component comprising a hydrolyzable silane moiety and a free radically crosslinkable moiety. The weight ratio of the crosslinkable silane component to the fluoro/silane component is from about 4:1 to 20:1, and the weight ratio of the free radically curable binder precursor to the colloidal inorganic oxide components is from about 1:10 to 8:10. A method of making a retroreflective article by coating a substrate with a ceramer composite coating is also described. A method of making a dew-resistant retroreflective article by coating a substrate with a ceramer composite coating and then surface treating the coating is also described.
摘要:
A structured paper release liner (10) for use with an article (44) backed with a pressure sensitive adhesive, an adhesive-backed article assembly (42) and methods of making each are disclosed. The liner (10) comprises a piece of paper (14) having a release side free of a structural support layer, a back side, and a structured release surface (48) having a pattern formed into the paper (14) on the release side. A release material is on the structured release surface of the paper. The pattern formed in the paper (14) is designed so as to form fluid egress channels in a bonding surface of the pressure sensitive adhesive (46). The fluid egress channels define a structured bonding surface (48) having exit pathways for fluid to bleed out from behind the article when the structured bonding surface (48) is adhered to or otherwise disposed on a substrate.
摘要:
A novel topical medicinal composition is described which comprises a copolymer which has both pendant fluorochemical groups and pendant polysiloxane grafts.
摘要:
A curable composition comprises (a) at least one polydiorganosiloxane, fluorinated polydiorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydroxysilyl moieties; (b) at least one polydiorganosiloxane, fluorinated polydiorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydrosilyl moieties; and (c) at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof; wherein at least one of the components (a) and (b) has an average reactive silane functionality of at least three.
摘要:
A structured paper release liner (10) for use with an article (44) backed with a pressure sensitive adhesive, an adhesive-backed article assembly (42) and methods of making each are disclosed. The liner (10) comprises a piece of paper (14) having a release side free of a structural support layer, a back side, and a structured release surface (48) having a pattern formed into the paper (14) on the release side. A release material is on the structured release surface of the paper. The pattern formed in the paper (14) is designed so as to form fluid egress channels in a bonding surface of the pressure sensitive adhesive (46). The fluid egress channels define a structured bonding surface (48) having exit pathways for fluid to bleed out from behind the article when the structured bonding surface (48) is adhered to or otherwise disposed on a substrate.
摘要:
Retroreflective articles having multilayer films are useful for commercial graphics and retroreflective products, such as roll-up signs for highway transportation safety. The articles comprise multilayer films having at least one layer of polyurethane and at least one layer of a copolymer of alkylene and at least one non-acidic, polar co-monomer. Articles having the new multilayer films provide the same or improved performance, are less expensive, and offer improved methods for manufacturing, when compared to prior articles.