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公开(公告)号：US5478367A
公开(公告)日：1995-12-26
申请号：US937908
申请日：1992-12-09
CPC分类号： C10L1/143 , C10L1/14 , C10L1/22 , C10L10/02 , C10L10/12 , C10L1/221 , C10L1/2222 , C10L1/2225 , C10L1/223 , C10L1/2235 , C10L1/224 , C10L1/2286 , C10L1/231 , C10L1/232 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L1/2425 , C10L1/2475 , C10L1/2493 , C10L1/2683 , C10L1/2691 , C10L1/303
摘要： The addition to diesel or jet fuel of macrocyclic polyamines, especially those derived from PIBSA, or hydrocarbyl polyamines reduces particle emission, especially in association with organic nitrate cetane improvers.
摘要翻译： PCT No.PCT / EP91 / 01937 Sec。 371日期：1992年12月9日 102（e）1991年12月9日PCT 1991年10月11日PCT。1991年10月11日提交的大环多胺，特别是衍生自PIBSA或烃基多胺的柴油或喷气燃料的添加减少了颗粒排放，特别是与有机硝酸盐十六烷值改进剂 。
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2.发明授权
公开(公告)号：US5314633A
公开(公告)日：1994-05-24
申请号：US963971
申请日：1992-10-20
申请人： Jack Ryer , Antonio Gutierrez , James S. Puckace , Raymond F. Watts , Craig W. Gleason , Daniel R. Mills , Edmund H. Braun, II , Stanley J. Brois
发明人： Jack Ryer , Antonio Gutierrez , James S. Puckace , Raymond F. Watts , Craig W. Gleason , Daniel R. Mills , Edmund H. Braun, II , Stanley J. Brois
IPC分类号： C07F9/141 , C10L1/14 , C10L1/24 , C10L1/26 , C10M135/24 , C10M137/02 , C10M141/10 , C10M159/12 , C10M137/00 , C10M153/00
CPC分类号： C10L10/08 , C07F9/1411 , C10L1/2406 , C10L1/2641 , C10L1/2691 , C10M135/24 , C10M137/02 , C10M141/10 , C10M159/123 , C10L1/143 , C10L1/2493 , C10M2207/04 , C10M2207/046 , C10M2215/042 , C10M2215/24 , C10M2219/084 , C10M2223/02 , C10M2223/04 , C10M2223/042 , C10M2223/047 , C10M2223/049 , C10M2223/065 , C10M2223/10 , C10M2223/12 , C10M2223/121 , C10M2227/061 , C10N2240/00 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/06 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2270/02
摘要： A phosphorous- and sulfur-containing additive and its use to impart anti-wear and/or antioxidant properties to oleaginous compositions such as fuels and lubricating oils, particularly power transmission compositions, such as automatic transmission fluids, is disclosed. The additive comprises a mixture of products formed by simultaneously reacting (1) a beta-hydroxy thioether, such as thiobisethanol, and (2) a phosphorous-containing reactant, such as tributyl phosphite. The reaction is carried out under reduced pressure conditions (e.g., -40 KPa to -100 KPa) to limit the amount of thioether species in said additive to less than about 45 mole %.
摘要翻译： 公开了含磷和硫的添加剂及其用于赋予含油组合物如燃料和润滑油，特别是动力传动组合物如自动变速器油的抗磨损和/或抗氧化性能的用途。 添加剂包括通过使（1）β-羟基硫醚如硫代双乙醇同时反应形成的产物和（2）含磷反应物如亚磷酸三丁酯形成的混合物。 反应在减压条件（例如，-40KPa至-100KPa）下进行，以将所述添加剂中的硫醚物质的量限制在小于约45摩尔％。
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3.发明授权Thio-bis(alkyl lactone acid esters) and thio-bis (Hydrocarbyl diacid esters) are usefull additives for lubricating compositions 失效硫代双（烷基内酯酸酯）和硫代双（烃基二酸酯）是用于润滑组合物的有用添加剂
公开(公告)号：US5118835A
公开(公告)日：1992-06-02
申请号：US554789
申请日：1990-07-18
IPC分类号： C07D307/32 , C07D307/33 , C07D307/60 , C07D309/30 , C08F8/06 , C08F8/14 , C08F8/34 , C10L1/198 , C10L1/233 , C10L1/24 , C10M129/76 , C10M133/44 , C10M133/48 , C10M133/58 , C10M135/26 , C10M135/32 , F02B3/06 , C07C69/74 , C07C381/00
CPC分类号： C07D307/33 , C07D307/32 , C07D307/60 , C07D309/30 , C08F8/14 , C08F8/34 , C10L1/198 , C10L1/233 , C10L1/2475 , C10L1/2493 , C10M1/08 , C10M129/76 , C10M133/44 , C10M133/48 , C10M133/58 , C10M135/26 , C10M135/32 , C10M2205/00 , C10M2205/022 , C10M2205/026 , C10M2205/14 , C10M2207/024 , C10M2207/028 , C10M2207/282 , C10M2207/287 , C10M2207/289 , C10M2207/30 , C10M2207/34 , C10M2209/084 , C10M2209/086 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10M2209/106 , C10M2209/11 , C10M2209/112 , C10M2209/12 , C10M2215/065 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/30 , C10M2219/046 , C10M2219/06 , C10M2219/085 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/09 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10M2221/04 , C10M2223/041 , C10M2223/045 , C10M2223/047 , C10M2227/061 , C10M2229/02 , C10M2229/05 , C10N2210/02 , C10N2210/03 , C10N2240/04 , C10N2240/042 , C10N2240/044 , C10N2240/046 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2240/12 , C10N2240/121 , C10N2240/14 , C10N2270/02 , F02B3/06
摘要： Thio-bis-(hydrocarbyl substituted diacid materials), such as thio-bis-(polyalkyl lactone acid) and/or their precursors, the adducts of sulfur chloride and unsaturated diacid materials, e.g., 4,8-bis-polyalkyl-4,8-dichloro-6-thiaundecane-1,2,10,11-tetracarboxylic acid bis-anhydride and their dehydrochlorinated analogs, when esterified with an alcohol, preferably a polyol, such as pentaerythritol, polypentaerythritol or a polyalkylene glycol with or without acid catalysts and/or metal template reagents yield thio-bis-(alkyl lactone acid esters) and thio-bis-(hydrocarbyl diacid esters) which can be characterized in part, as macrocyclic and/or macrocyclic-like structures, are useful as stable additives in lubricating compositions, e.g. as varnish inhibiting dispersants for lubricating oils and fuels.
摘要翻译： 硫代双 - （烃基取代的二酸物质），例如硫代双 - （多烷基内酯酸）和/或其前体，硫化氯和不饱和二酸物质的加合物，例如4,8-双 - 聚烷基-4， 8-二氯-6-硫杂十一烷-1,2,10,11-四羧酸二酐和它们的脱氯化氢类似物，当用醇酯化时，优选多元醇如季戊四醇，聚季戊四醇或具有或不含酸催化剂的聚亚烷基二醇 和/或金属模板试剂产生硫代双 - （烷基内酯酸酯）和硫代双 - （烃基二酸酯），其可部分表征为大环和/或大环类结构，可用作稳定的添加剂 润滑组合物，例如 作为用于润滑油和燃料的清漆抑制分散剂。
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4.发明授权Macrocyclic polyamine and polycyclic polyamine multifunctional lubricating oil additives 失效大环多胺和多环多胺多官能润滑油添加剂
公开(公告)号：US4880923A
公开(公告)日：1989-11-14
申请号：US902779
申请日：1986-09-02
IPC分类号： C07D307/32 , C07D307/33 , C07D307/60 , C07D309/30 , C07D487/04 , C08F8/32 , C10L1/232 , C10L1/233 , C10L1/24 , C10M133/38 , C10M133/44 , C10M133/48 , C10M133/58 , C10M135/32 , F02B3/06
CPC分类号： C07D307/33 , C07D307/32 , C07D307/60 , C07D309/30 , C07D487/04 , C08F8/34 , C08F8/44 , C10L1/232 , C10L1/233 , C10L1/2493 , C10M1/08 , C10M133/38 , C10M133/44 , C10M133/48 , C10M133/58 , C10M135/32 , C10M2205/00 , C10M2205/022 , C10M2205/026 , C10M2205/06 , C10M2205/14 , C10M2205/22 , C10M2207/024 , C10M2207/026 , C10M2207/027 , C10M2207/028 , C10M2207/144 , C10M2207/146 , C10M2207/16 , C10M2207/262 , C10M2207/289 , C10M2209/084 , C10M2209/086 , C10M2209/112 , C10M2215/04 , C10M2215/065 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06 , C10M2219/022 , C10M2219/024 , C10M2219/044 , C10M2219/046 , C10M2219/085 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/09 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10M2223/041 , C10M2223/045 , C10M2223/047 , C10M2223/12 , C10M2225/04 , C10M2225/041 , C10M2227/09 , C10M2229/02 , C10M2229/05 , C10N2210/01 , C10N2210/02 , C10N2210/03 , C10N2210/05 , C10N2210/06 , C10N2210/07 , C10N2210/08 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2270/02 , F02B3/06
摘要： There are disclosed macrocyclic and polycyclic polyamine lubricating oil additives formed by cyclodehydration of reaction products of hydrocarbon substituted succinic anhydrides or carboxylic acids with poly 3-amino propyl compounds or by acylation of macrocyclic polyamines and polycyclic polyamines with hydrocarbon substituted succinic anhydride or carboxylic acids. These compounds are useful as dispersants and dispersants-V.I. improvers in both gasoline and diesel engine lubricating oil compositions and are also useful fuel additives.
摘要翻译： 公开了通过烃取代的琥珀酸酐或羧酸与聚3-氨基丙基化合物的反应产物的环化脱水或通过用烃取代的琥珀酸酐或羧酸酰化大环多胺和多环多胺而形成的大环和多环多胺润滑油添加剂。 这些化合物可用作分散剂和分散剂。 汽油和柴油发动机润滑油组合物中的改进剂也是有用的燃料添加剂。
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5.发明授权Amine-treated thio-bis-(alkyl lactone acid) and thio-bis-(hydrocarbyl diacid) materials, additives for lubricating compositions 失效胺处理的硫代双 - （烷基内酯酸）和硫代双 - （烃基二酸）材料，用于润滑组合物的添加剂
公开(公告)号：US4851524A
公开(公告)日：1989-07-25
申请号：US802594
申请日：1985-11-27
IPC分类号： C07D307/32 , C07D307/33 , C07D307/60 , C07D309/30 , C10L1/233 , C10L1/24 , C10M133/44 , C10M133/48 , C10M133/58 , C10M135/32 , F02B3/06 , C07D257/02 , C07D259/00
CPC分类号： C07D307/33 , C07D307/32 , C07D307/60 , C07D309/30 , C08F8/14 , C08F8/34 , C10L1/233 , C10L1/2493 , C10M1/08 , C10M133/44 , C10M133/48 , C10M133/58 , C10M135/32 , C10M2205/00 , C10M2205/022 , C10M2205/026 , C10M2205/14 , C10M2207/024 , C10M2209/084 , C10M2209/086 , C10M2209/112 , C10M2215/065 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/30 , C10M2219/085 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/09 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10M2223/041 , C10M2223/045 , C10M2223/047 , C10M2229/02 , C10M2229/05 , C10N2210/03 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2270/02 , F02B3/06
摘要： Thio-bis-(hydrocarbyl substituted diacid materials), such as thio-bis-(polyalkyl lactone acid) and/or their precursors, the adducts of sulfur chloride and unsaturated diacid materials, e.g., 4,8-bis-polyalkyl-4, 8-dichloro-6-thiaundecane-1,2,10,11-tetracarboxylic acid bis-anhydride and especially their dehydrochlorinated analogs, when treated with an amine preferably polyalkylene polyamines such as tetraethylene pentamine, directly or in the presence of a metal template reagent, yield aminated thio-bis-(alkyl lactone acid) and thio-bis-(hydrocarbyl diacid) materials or their metal complexes which can be characterized in part, as macrocyclic and/or macrocyclic-like amide and/or imide structures, are useful as stable additives in lubricating compositions, e.g., as varnish inhibiting dispersants and/or inhibitors for lubricating oils and fuels.
摘要翻译： 硫代双 - （烃基取代的二酸物质），例如硫代双 - （多烷基内酯酸）和/或其前体，硫化氯和不饱和二酸物质的加合物，例如4,8-双 - 聚烷基-4， 8-二氯-6-硫杂十一烷-1,2,10,11-四羧酸二酐，特别是其脱氯化氢类似物，当用胺优选聚亚烷基多胺如四亚乙基五胺处理时，直接或在金属模板试剂 产生胺化的硫代双 - （烷基内酯酸）和硫代双 - （烃基二酸）材料或它们的金属配合物，其部分可以表征为大环和/或大环类似酰胺和/或酰亚胺结构，是有用的 作为润滑组合物中的稳定的添加剂，例如作为润滑剂抑制分散剂和/或润滑油和燃料的抑制剂。
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6.发明授权Metal salt esters of hydrocarbyl substituted succinic acid or anhydride and thio alkanols 失效烃基取代的琥珀酸或酸酐和硫代链烷醇的金属盐酯
公开(公告)号：US4664826A
公开(公告)日：1987-05-12
申请号：US763294
申请日：1985-08-07
申请人： Antonio Gutierrez , Stanley J. Brois , Jack Ryer , Harold E. Deen
发明人： Antonio Gutierrez , Stanley J. Brois , Jack Ryer , Harold E. Deen
IPC分类号： C10M129/72 , C10M133/16 , C10M135/22 , C10M135/24
CPC分类号： C10M135/24 , C07C323/00 , C10M2219/084 , C10M2227/061 , C10N2210/01 , C10N2210/02 , C10N2210/08 , C10N2240/08
摘要： The present invention provides certain metal (e.g., Ca or Mg) ester salt derivatives capable of exhibiting friction modification, oxidation inhibition, and corrosion inhibition properties in power transmitting fluids such as automatic transmission fluids. These salts are derived from mono or diesters prepared by the reaction of an alkanol (e.g., thio-bis-ethanol) and a hydrocarbon substituted succinic acid or anhydride, such as octadecenyl succinic anhydride.
摘要翻译： 本发明提供了能够在诸如自动变速器流体的动力传递流体中表现出摩擦改性，氧化抑制和腐蚀抑制性质的某些金属（例如Ca或Mg）酯盐衍生物。 这些盐衍生自通过链烷醇（例如硫代双 - 乙醇）和烃取代的琥珀酸或酸酐如十八碳烯基琥珀酸酐反应制备的单或二酯。
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7.发明授权Oxazolines of 2-(alkylthio)succinic acids as an additive for drilling muds 失效2-（烷硫基）琥珀酸的恶唑啉作为钻井泥浆的添加剂
公开(公告)号：US4455429A
公开(公告)日：1984-06-19
申请号：US534272
申请日：1983-09-21
IPC分类号： C09K8/22 , C07D263/08 , C09K7/00
CPC分类号： C09K8/22
摘要： A bis-oxazoline of the formula: ##STR1## wherein R represents an alkyl group of 6 to 50 carbons and X is selected from the group containing of an alkyl or hydroxyalkyl group and at least one of the X substituents being a hydroxy alkyl group of the structure --(CH.sub.2).sub.n OH where n is 1 to 3, which is useful in improving the lubricity of aqueous drilling muds.
摘要翻译： 下式的双恶唑啉：其中R表示碳原子数为6〜50的烷基，X选自烷基或羟烷基，X取代基中的至少一个为羟基烷基， 结构 - （CH 2）n OH，其中n为1至3，其可用于改善含水钻井泥浆的润滑性。
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8.发明授权Thio-bis-(hydrocarbon-bisoxazolines) as oleaginous additives for lubricants and fuels 失效硫代双（烃 - 双恶唑啉）作为润滑剂和燃料的含油添加剂
公开(公告)号：US4292184A
公开(公告)日：1981-09-29
申请号：US134511
申请日：1980-03-27
IPC分类号： C07D263/14 , C07D307/60 , C10L1/24 , C10M135/32 , C10M1/38
CPC分类号： C07D263/14 , C07D307/60 , C10L1/2493 , C10M135/32 , C10M2219/09 , C10N2210/06 , C10N2240/06 , C10N2240/08 , C10N2270/02
摘要： Thio-bis-(hydrocarbon-bisoxazolines) which are the reaction products of thio-bis-(hydrocarbon substituted dicarboxylic acid material), for example, thio-bis-(polyisobutenyl succinic anhydride), with 2,2-disubstituted-2-amino-1-alkanols, such as tris-(hydroxymethyl) amino-methane (THAM), and their derivatives are useful additives in oleaginous compositions, such as sludge dispersants for lubricating oil, or anti-corrosion agents for fuels.
摘要翻译： 作为硫代双 - （烃取代的二羧酸材料）的反应产物的硫 - 双 - （烃 - 双恶唑啉），例如硫代双 - （聚异丁烯基琥珀酸酐）与2,2-二取代-2-氨基 -1-烷醇，例如三 - （羟甲基）氨基甲烷（THAM）及其衍生物是含油组合物中的有用添加剂，例如用于润滑油的污泥分散剂或用于燃料的防腐剂。
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公开(公告)号：US4221720A
公开(公告)日：1980-09-09
申请号：US967289
申请日：1978-12-07
IPC分类号： C07D413/06 , C07D307/32 , C07D307/33 , C07D307/60 , C07D309/30 , C07D413/14 , C10L1/233 , C10L1/24 , C10M133/44 , C10M133/48 , C10M133/58 , C10M135/22 , C10M135/32 , C10N30/04 , C10N30/12 , C10N40/04 , F02B3/06 , C07D307/10 , C07D309/20
CPC分类号： C07D307/33 , C07D307/32 , C07D307/60 , C07D309/30 , C10L1/233 , C10L1/2493 , C10M133/44 , C10M133/48 , C10M133/58 , C10M135/32 , C10M2205/00 , C10M2205/022 , C10M2205/026 , C10M2205/14 , C10M2207/024 , C10M2209/084 , C10M2209/086 , C10M2209/112 , C10M2215/065 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/30 , C10M2219/085 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/09 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10M2223/041 , C10M2223/045 , C10M2223/047 , C10M2229/02 , C10M2229/05 , C10N2210/03 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2270/02 , F02B3/06
摘要： Lactone oxazoline reaction products of hydrocarbon substituted lactone carboxylic acids, for example, polybutyl lactone carboxylic acid, with 2,2-disubstituted-2-amino-1-alkanols, such as tris-(hydroxymethyl)aminomethane (THAM), and their derivatives are useful aditives in oleaginous compositions, such as sludge dispersants for lubricating oil, or anti-rust agents for gasoline.
摘要翻译： 烃取代的内酯羧酸（例如聚丁内酯羧酸）与2,2-二取代-2-氨基-1-链烷醇如三 - （羟甲基）氨基甲烷（THAM）及其衍生物的内酯恶唑啉反应产物是 含油组合物，如用于润滑油的污泥分散剂，或汽油用防锈剂等有用的助剂。
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公开(公告)号：US4174322A
公开(公告)日：1979-11-13
申请号：US817217
申请日：1977-07-20
IPC分类号： C07D307/32 , C07D307/33 , C07D307/60 , C07D309/30 , C10L1/233 , C10L1/24 , C10M133/48 , C10M133/58 , C10M135/32 , F02B3/06 , C07D263/08
CPC分类号： C07D307/33 , C07D307/32 , C07D307/60 , C07D309/30 , C10L1/233 , C10L1/2493 , C10M133/48 , C10M133/58 , C10M135/32 , C10M2205/00 , C10M2205/022 , C10M2205/026 , C10M2205/14 , C10M2207/024 , C10M2209/084 , C10M2209/086 , C10M2209/112 , C10M2215/065 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/30 , C10M2219/085 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/09 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10M2223/041 , C10M2223/045 , C10M2223/047 , C10M2229/02 , C10M2229/05 , C10N2210/03 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106 , C10N2270/02 , F02B3/06
摘要： Lactone oxazoline reaction products of hydrocarbon substituted lactone carboxylic acids, for example, polybutyl lactone carboxylic acid, with 2,2-disubstituted-2-amino-1-alkanols, such as tris-(hydroxymethyl)aminomethane (THAM), and their derivatives are useful additives in oleaginous compositions, such as sludge dispersants for lubricating oil, or anti-rust agents for gasoline.
摘要翻译： 烃取代的内酯羧酸（例如聚丁内酯羧酸）与2,2-二取代-2-氨基-1-链烷醇如三 - （羟甲基）氨基甲烷（THAM）及其衍生物的内酯恶唑啉反应产物是 含油组合物中有用的添加剂，如润滑油污泥分散剂，或汽油防锈剂。
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