Composite particle
    1.
    发明授权
    Composite particle 失效
    复合颗粒

    公开(公告)号:US5112689A

    公开(公告)日:1992-05-12

    申请号:US447511

    申请日:1989-12-07

    IPC分类号: C08J3/12 C09D5/03 G03G9/087

    摘要: The invention relates to a composite particle comprising 2 to 98% by weight of a base resin having softending point of -10.degree. to 120.degree. C. and a number average molecular weight of 600 or more and 98 to 2% by weight of an anisotropic crystalline polymer having a phase transition point of 60.degree. to 230.degree. C. and a number average molecular weight of 600 to 10,000 and capable for forming an anisotropic molten phase, the polymer having the specific structure in which a repeating unit of the formula:A--X--B (I)(wherein 100 to 50 mol % of A stands for defined mesogenic group, 0 to 50 mole % of A is p-phenylene, m-phenylene or trans-1,4-cyclohexylene, B is a defined spacer group, and X is ester bond, carbonate bond, amide bond, urethane bond or urea bond, and a repeating unit of the formula:R (II)in which R stands for bivalent to hexavalent hydrocarbon residue, are connected, in any successive orders and in a weight ratio of (I)/(II)=99.9/0.1 to 60/40, with each other through ester bond, carbonate bond, amide bond, urethane bond or urea bond, and end portions are occupied by a functional group as hydroxyl, carboxyl and the like. The composition particle is useful as powder coating, dry toner and the like.

    Thermosetting polyester resin and powder coating resinous composition
containing the same
    4.
    发明授权
    Thermosetting polyester resin and powder coating resinous composition containing the same 失效
    热固性聚酯树脂和粉末涂料含有相同的树脂组合物

    公开(公告)号:US5306806A

    公开(公告)日:1994-04-26

    申请号:US560226

    申请日:1990-07-20

    摘要: The invention concerns a thermosetting polyester resin capable of forming an anisotropic molten phase comprising a repeating unit of the formula: A-X-B alone, or a combination of the repeating unit of the formula: A-X-B and the repeating unit of the formula: R, adjoining two repeating units being connected each other through an ester bond, in which A represents a mesogenic group defined in the specification, B is a spacer group defined in the specification, X is an ester bond, and R represents a bivalent to hexavalent aliphatic, aromatic or alicyclic hydrocarbon residue, the end bondings of the connected repeating units being occupied by OH, COOH or their reactive derivatives and the sum of the resinous acid value and the OH value being 10 to 200.The invention also provides a powder coating resinous composition containing the abovesaid resin.

    摘要翻译: 本发明涉及一种能够形成各向异性熔融相的热固性聚酯树脂,其包含下式的重复单元:单独的AXB,或下式的重复单元:AXB和式R的重复单元的组合:邻接两个重复的 单元通过酯键彼此连接,其中A表示说明书中定义的介晶基团,B是说明书中定义的间隔基团,X是酯键,R代表二价至六价的脂族,芳族或脂环族 烃残基,所连接的重复单元的末端键合被OH,COOH或它们的活性衍生物占据,并且树脂酸值和OH值的总和为10〜200。本发明还提供了含有上述物质的粉末涂料树脂组合物 树脂。

    Modified polyester resin composition containing isonanoic acid and a
cyclic ester
    6.
    发明授权
    Modified polyester resin composition containing isonanoic acid and a cyclic ester 失效
    含有异壬酸和环状酯的改性聚酯树脂组合物

    公开(公告)号:US4891419A

    公开(公告)日:1990-01-02

    申请号:US119834

    申请日:1987-11-12

    CPC分类号: C08G63/60 C09D167/00

    摘要: A modified polyester resin composition for coating use comprising a polyester resin modified with 5 to 30% by weight of the total solid of a branched fatty acid having 8 and more carbon atoms and with 5 to 30% by weight of the total solid of a cyclic ester represented by the formula: ##STR1## wherein R represents an alkylene group having 4 to 10 carbon atoms, the resin having a hydroxyl value of 70 to 300. The present resin composition is specifically useful as resinous vehicle in a top coat composition for plastic and other substrates.

    摘要翻译: 一种涂料用改性聚酯树脂组合物,其包含用5至30重量%的具有8个或更多个碳原子的支链脂肪酸的总固体和5至30重量%总固体的环状 由下式表示的酯:其中R表示具有4-10个碳原子的亚烷基,该树脂的羟值为70〜300。本发明的树脂组合物特别可用作塑料用面漆组合物中的树脂载体 和其他底物。

    Resinous composition for coating use, which is excellent in weather
resistance and in low temperature curing properties, its preparation
and coating composition containing the same
    7.
    发明授权
    Resinous composition for coating use, which is excellent in weather resistance and in low temperature curing properties, its preparation and coating composition containing the same 失效
    其耐候性和低温固化性优异的涂料用树脂组合物及其制备方法和含有它们的涂料组合物

    公开(公告)号:US4810758A

    公开(公告)日:1989-03-07

    申请号:US25281

    申请日:1987-03-12

    CPC分类号: C09D201/08 C09D167/00

    摘要: A resinous composition for coating use which is excellent in weather resistance and in low temperature curing properties, comprising a resin having resinous acid value based on carboxyl groups derived from its constituting tetrachlorophthalic acid of 2 to 8, a resinous acid value based on sulfonic acid groups derived from its constituting sulfophthalic acid of 0.5 to 5, and a functional group capable of reacting with a crosslinking agent to be compounded with the resin. The present resin is useful, in the combination form with a crosslinking agent, as a resinous vehicle of a coating composition which is excellent in curing properties, weather resistance, pigment dispersibility and storage stability and is specifically useful as an intermediate or top coat paint for automobile bodies or the like.

    摘要翻译: 一种耐候性和低温固化性优异的涂料用树脂组合物,其含有树脂酸值基于其构成的四氯邻苯二甲酸的羧基为2-8的树脂酸值,基于磺酸基的树脂酸值 衍生自其构成的0.5〜5的间苯二甲酸,以及能够与与树脂配混的交联剂反应的官能团。 本树脂与交联剂的组合形式可用作固化性,耐候性,颜料分散性和储存稳定性优异的涂料组合物的树脂载体,并且特别适用于作为中间或面漆涂料 汽车车身等。

    Organic polymer microparticle and process for producing the same
    8.
    发明授权
    Organic polymer microparticle and process for producing the same 失效
    有机聚合物微粒及其制造方法

    公开(公告)号:US5373052A

    公开(公告)日:1994-12-13

    申请号:US992749

    申请日:1992-12-18

    摘要: Disclosed is an organic polymer microparticle which is obtainable from copolymerization of (a) an ethylenically unsaturated amine polymer obtained by reacting an amine polymer having at least two primary amino groups with 0.01 to 0.99 molar equivalents based on the amount of the primary amino group, of an unsaturation introducing monomer having at least one functional group which is reactive with the primary amino group and an ethylenic double bond with (b) 10 to 99000 parts by weight based on the total amount (100 parts by weight) of the amine polymer and the unsaturation introducing monomer, of a matrix forming ethylenically unsaturated monomer, in an aqueous medium. A process for producing the organic polymer microparticle is also disclosed.

    摘要翻译: 公开了一种有机聚合物微粒,其可通过(a)通过使具有至少两个伯氨基的胺聚合物与基于伯氨基的量为0.01至0.99摩尔当量的胺聚合物反应而获得的烯属不饱和胺聚合物 具有至少一个与伯氨基反应的官能团和烯键式双键的不饱和引入单体,(b)基于胺聚合物的总量(100重量份)为10〜99000重量份,和 不饱和引入单体,在含水介质中形成烯属不饱和单体的基质。 还公开了制备有机聚合物微粒的方法。

    Powder coating composition
    9.
    发明授权
    Powder coating composition 失效
    粉末涂料组合物

    公开(公告)号:US5418309A

    公开(公告)日:1995-05-23

    申请号:US174168

    申请日:1993-12-29

    摘要: The present invention provides a powder coating composition which is suitable for precoated steel plates. The powder coating composition has excellent storage stability (e.g. blocking resistance) and provides a cured film having good weather resistance and a good balance of hardness and processability. The powder coating composition comprises;(I) 95 to 70% by weight of a polyester resin having a glass transition temperature of 40.degree. to 70.degree. C., prepared from (i) and acid component containing at least 80 mole % of an aromatic dicarboxylic acid with (ii) a polyol component which comprises(a) at least 50 mole % of neopentyl glycol, and(b) 1 to 10% by weight of a diol selected from the group consisting of a linear chain C.sub.8 -C.sub.16 alkylene diol, 2-methyl-1,8-octane diol and a mixture thereof, and(II) 5 to 30% by weight of a curing agent.

    摘要翻译: 本发明提供一种适用于预涂钢板的粉末涂料组合物。 粉末涂料组合物具有优异的储存稳定性(例如耐粘连性),并提供具有良好耐候性和良好的硬度和加工性能的固化膜。 粉末涂料组合物包含: (I)95〜70重量%的玻璃化转变温度为40〜70℃的聚酯树脂,(i)和含有至少80摩尔%芳族二羧酸的酸成分与(ii) 一种多元醇组分,其包含(a)至少50摩尔%的新戊二醇,和(b)1至10重量%的选自直链C8-C16亚烷基二醇,2-甲基-1 ,8-辛二醇及其混合物,和(II)5-30重量%的固化剂。