摘要:
An aqueous polymer composition comprising 10 to 40 wt % of a polymer in water, the polymer consisting essentially of 20-90 wt % .alpha.,.beta.-ethylenically unsaturated carboxylic acid monomer, 10-80 wt % one or more softening monomers, the aqueous composition being adjusted to pH 4-6 with alkali metal hydroxide or alkaline earth metal hydroxide and further containing 0.1 to 3 wt % zirconium crosslinking salt. Such aqueous compositions can be applied to nonwoven and woven substrates to make superabsorbent products.
摘要:
A method for preparing an acrylic polymer powder which is redispersible in water by atomizing an aqueous polymer dispersion containing a dispersing aid, the improvement which comprises employing an acrylic polymer containing 1-15 wt % olefinically unsaturated carboxylic acid comonomer and an effective amount of a dispersing aid consisting essentially of polyvinyl alcohol.
摘要:
This invention relates to flame-retarded cross-linked elastomer compositions obtained from an elastomeric polyurethane prepolymer; an organic fire-retardant additive containing chlorine and/or bromine; a compound of antimony; and a hexaalkoxymethyl melamine. These new compositions are self-extinguishing as well as non-dripping.
摘要:
Flexible automobile exterior body parts are molded from a polyurethane elastomer prepared from a reaction mixture comprising:A. a poly(oxypropylene)-poly(oxyethylene) glycol of molecular weight of from about 1500 to about 4000 containing 15 to 50% by weight oxyethylene groups;B. a "graft" polyol of molecular weight from about 2500 to about 4500, prepared by the in situ polymerization of one or more ethylenically unsaturated monomers in a poly(oxypropylene) and/or poly(oxypropylene)-poly(oxyethylene) glycol containing less than 15% by weight oxyethylene groups;C. methylenebis(4-phenylisocyanate);D. 1,4-butanediol.The invention also relates to this polyurethane elastomer.
摘要:
Flexible automobile exterior body parts are molded from a polyurethane elastomer prepared from a reaction mixture comprising:A. a "graft" polyol prepared by the in situ polymerization of one or more ethylenically unsaturated monomers in a poly(oxypropylene)-poly(oxyethylene) glycol of molecular weight from about 1750 to about 4000 and containing from 15 to 50% oxyethylene groups by weight,B. methylenebis(4-phenylisocyanate),C. 1,4-butanediol.
摘要:
The present invention is directed to improved flexibilized, plasticized polyvinyl chloride films bonded with a substrate by means of an aqueous based pressure sensitive acrylic adhesive emulsion polymers. Conventional emulsion based pressure sensitive adhesives were comprised of a copolymer comprised of polymerized units of acrylic esters and ethylenically unsaturated monomers, the copolymer having a Tg of from −15 to −70° C. The improvement in the aqueous based, emulsion polymerized pressure sensitive adhesives resides in the incorporation of polymerized units of a vinyl C8-13 ester of a neo-acid into the adhesive. The vinyl ester is formed from a mixture of propylene oligomers and such vinyl ester is represented by the chemical formula: C8-13H7-27CO2CH═CH2. Preferably, the adhesive includes units of methyl methacrylate, butyl acrylate of 2-ethylhexyl acrylate and a carboxylic acid selected from acrylic acid or methacrylic acid.
摘要:
A copolymer emulsion for bonding nonwoven products comprising an aqueous medium having colloidally dispersed therein a copolymer consisting essentially of vinyl acetate, 5-35 wt % ethylene and 2 to 10 wt % of an amide functional crosslinking comonomer which is N-methylolacrylamide or a compound of the formula R--NH--(CH.sub.2).sub.n --CH(OR').sub.2 where R is (meth)acryloyl, R' is a C.sub.1 -C.sub.4 alkyl group and n is 3 or 4, the copolymer emulsion prepared in the presence of 0.1 to 1 wt % polyvinyl pyrrolidone, based on vinyl acetate in the copolymer. Such emulsion binder copolymers demonstrate improved solvent resistance.
摘要:
This inventon relates to flame-retarded cross-linked elastomer compositions obtained from an elastomeric polyurethane prepolymer; an organic fire-retardant additive containing chlorine and/or bromine; a compound of antimony; and a hexaalkoxymethyl melamine. These new compositions are self-extinguishing as well as non-dripping.
摘要:
Chain extended polyurethanes are prepared, using certain 3-(hydroxyhydrocarbylsecondaryamino)thiophene 1,1-dioxides, some of which are new chemicals. E.g., 3-(2-hydroxypropylamino)tetrahydrothiophene 1,1-dioxide is especially useful as a chain extender for high resiliency, flexible polyurethane foams.