Dihalo-allyloxy-phenol derivatives having pesticidal activity

    公开(公告)号:US20060014806A1

    公开(公告)日:2006-01-19

    申请号:US10537444

    申请日:2003-12-10

    IPC分类号: C07D213/42

    摘要: Compounds of formula (I), wherein A1 and A2 are each independently of the other a bond or a C1-C6alkylene bridge; A3 is a C1-C6alkylene bridge; X1 and X2 are each independently of the other fluorine, chlorine or bromine; Y is O, NR7, S, SO or SO2; R1, R2 and R3 are each independently of the others, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkylcarbonyl or C2-C6alkenyl; Q is O, NR5, S, SO or SO2; W is, for example, O, NR5 or SO; T is for example, a bond, O or NR5; D is CH or N; R4 is, for example, H, halogen, OH, SH, CN or nitro; R5 and R7 are, for example, H, C1-C6alkyl or C1-C3haloalkyl; k is 1, 2, 3 or 4; m is 1 or 2; R10 is a radical which contains 0, N or S; R11 is, for example, H, C1-C12alkyl or a radical which contains from one to three hetero atoms selected from O, N and S; or R11 together with R12 is a bond; R12 is, for example, H, C1-C6alkyl, halo-C1-C6alkyl or C1-C6alkoxy-C1-C6-alkyl; and, where applicable, their possible E/Z isomeric mixtures isomers, EQ isomeric mixtures and/or tautomers, in each case in free from or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds or an agrochemically acceptable salt thereof; a process for the preparation of those compositions and their use, plant propagation material treated with those compositions, and a method of controlling pests.

    PESTICIDALLY ACTIVE KETONE AND OXIME DERIVATIVES
    7.
    发明申请
    PESTICIDALLY ACTIVE KETONE AND OXIME DERIVATIVES 审中-公开
    杀虫活性酮和氧化衍生物

    公开(公告)号:US20090298898A1

    公开(公告)日:2009-12-03

    申请号:US12533302

    申请日:2009-07-31

    摘要: Compounds of formula wherein A0, A1 and A2 are each independently of the others a bond or a C1-C6alkylene bridge; A3 is a C1-C6alkylene bridge which is unsubstituted or substituted by from one to six identical or different substituents selected from halogen and C3-C8cycloalkyl; Y is, for example, O, S, SO or SO2; M is O or NOR6, X1 and X2 are each independently of the other fluorine, chlorine or bromine; R1, R2 and R3 are, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkylcarbonyl, C2-C6alkenyl, C2-C6haloalkenyl or C2-C6alkynyl; Q is, for example, O, S, SO or SO2; W is, for example, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; T is, for example, a bond, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; D is CH or N; R4 is, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl or C1-C6haloalkyl; R5 is, for example, C1-C12alkyl, C3-C8cycloalkyl or —N(R7)2; R7 is H, C1-C6alkyl, C1-C3haloalkyl, C1-C6alkylcarbonyl, C1-C3haloalkylcarbonyl, C1-C6alkoxycarbonyl, C3-C8cycloalkyl, C3-C8 cycloalkylcarbonyl or formyl; k is 0, 1, 2, 3 or 4; m is 1 or 2; and q is 0, 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds and agrochemically acceptable salts thereof, and a process for the preparation of those compositions and their use, to plant propagation material treated with those compositions, and a method of controlling pests.

    摘要翻译: 下式化合物其中A0,A1和A2各自独立地为键或C1-C6亚烷基桥; A3是C1-C6亚烷基桥,其未被取代或被1-6个相同或不同的选自卤素和C 3 -C 8环烷基的取代基取代; Y是例如O,S,SO或SO 2; M为O或NOR6,X1和X2各自独立地为氟,氯或溴; R1,R2和R3是例如H,卤素,OH,SH,CN,硝基,C1-C6烷基,C1-C6卤代烷基,C1-C6烷基羰基,C2-C6链烯基,C2-C6卤代烯基或C2-C6炔基; Q是例如O,S,SO或SO 2; W是例如O,S,SO,SO 2,-C(-O)-O-或-O-C(-O) - ; T是例如键O,S,SO,SO 2,-C(-O)-O-或-O-C(-O) - ; D是CH或N; R4是例如H,卤素,OH,SH,CN,硝基,C1-C6烷基或C1-C6卤代烷基; R5是例如C1-C12烷基,C3-C8环烷基或-N(R7)2; R 7是H,C 1 -C 6烷基,C 1 -C 3卤代烷基,C 1 -C 6烷基羰基,C 1 -C 3卤代烷基羰基,C 1 -C 6烷氧基羰基,C 3 -C 8环烷基,C 3 -C 8环烷基羰基或甲酰基; k为0,1,2,3或4; m为1或2; q为0,1或2; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体,在每种情况下为游离形式或盐形式,制备这些化合物及其用途的方法,其中 已经从这些化合物和农业化学上可接受的盐中选择活性成分,以及这些组合物的制备方法及其用途,用这些组合物处理的繁殖材料以及控制害虫的方法。

    Pesticidally active ketone and oxime derivatives
    9.
    发明授权
    Pesticidally active ketone and oxime derivatives 失效
    杀虫活性酮和肟衍生物

    公开(公告)号:US07569727B2

    公开(公告)日:2009-08-04

    申请号:US12098594

    申请日:2008-04-07

    摘要: Compounds of formula wherein A0, A1 and A2 are each independently of the others a bond or a C1-C6alkylene bridge; A3 is a C1-C6alkylene bridge which is unsubstituted or substituted by from one to six identical or different substituents selected from halogen and C3-C8cycloalkyl; Y is, for example, O, S, SO or SO2; M is O or NOR6, X1 and X2 are each independently of the other fluorine, chlorine or bromine; R1, R2 and R3 are, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkylcarbonyl, C2-C6alkenyl, C2-C6haloalkenyl or C2-C6alkynyl; Q is, for example, O, S, SO or SO2; W is, for example, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; T is, for example, a bond, O, S, SO, SO2, —C(═O)—O— or —O—C(═O)—; D is CH or N; R4 is, for example, H, halogen, OH, SH, CN, nitro, C1-C6alkyl or C1-C6haloalkyl; R5 is, for example, C1-C12alkyl, C3-C8cycloalkyl or —N(R7)2; R7 is H, C1-C6alkyl, C1-C3haloalkyl, C1-C6alkylcarbonyl, C1-C3haloalkylcarbonyl, C1-C6alkoxycarbonyl, C3-C8cycloalkyl, C3-C8 cycloalkylcarbonyl or formyl; k is 0, 1, 2, 3 or 4; m is 1 or 2; and q is 0, 1 or 2; and, where applicable, their possible E/Z isomers, E/Z isomeric mixtures and/or tautomers, in each case in free form or in salt form, a process for the preparation of those compounds and their use, pesticidal compositions in which the active ingredient has been selected from those compounds and agrochemically acceptable salts thereof, and a process for the preparation of those compositions and their use, to plant propagation material treated with those compositions, and a method of controlling pests.

    摘要翻译: 下式化合物其中A0,A1和A2各自独立地为键或C1-C6亚烷基桥; A3是C1-C6亚烷基桥,其未被取代或被1-6个相同或不同的选自卤素和C 3 -C 8环烷基的取代基取代; Y是例如O,S,SO或SO 2; M为O或NOR6,X1和X2各自独立地为氟,氯或溴; R1,R2和R3是例如H,卤素,OH,SH,CN,硝基,C1-C6烷基,C1-C6卤代烷基,C1-C6烷基羰基,C2-C6链烯基,C2-C6卤代烯基或C2-C6炔基; Q是例如O,S,SO或SO 2; W是例如O,S,SO,SO 2,-C(-O)-O-或-O-C(-O) - ; T是例如键O,S,SO,SO 2,-C(-O)-O-或-O-C(-O) - ; D是CH或N; R4是例如H,卤素,OH,SH,CN,硝基,C1-C6烷基或C1-C6卤代烷基; R5是例如C1-C12烷基,C3-C8环烷基或-N(R7)2; R 7是H,C 1 -C 6烷基,C 1 -C 3卤代烷基,C 1 -C 6烷基羰基,C 1 -C 3卤代烷基羰基,C 1 -C 6烷氧基羰基,C 3 -C 8环烷基,C 3 -C 8环烷基羰基或甲酰基; k为0,1,2,3或4; m为1或2; q为0,1或2; 在适用情况下,它们可能的E / Z异构体,E / Z异构体混合物和/或互变异构体,在每种情况下为游离形式或盐形式,制备这些化合物及其用途的方法,其中 已经从这些化合物和农业化学上可接受的盐中选择活性成分,以及这些组合物的制备方法及其用途,用这些组合物处理的繁殖材料以及控制害虫的方法。