公开(公告)号：US06903050B2

公开(公告)日：2005-06-07

申请号：US10281635

申请日：2002-10-28

申请人： Oleg M. Ilinich ,  Wolfgang F. Ruettinger ,  Ronald T. Mentz ,  Robert J. Farrauto

发明人： Oleg M. Ilinich ,  Wolfgang F. Ruettinger ,  Ronald T. Mentz ,  Robert J. Farrauto

IPC分类号： B01J21/04 ,  B01J23/00 ,  B01J23/72 ,  B01J23/94 ,  B01J37/00 ,  B01J37/14 ,  B01J37/18 ,  C01B3/16 ,  H01M8/06 ,  B01J20/34

CPC分类号： H01M8/0662 ,  B01J21/04 ,  B01J23/005 ,  B01J23/72 ,  B01J23/94 ,  B01J37/0018 ,  B01J37/14 ,  B01J37/18 ,  C01B3/16 ,  C01B2203/0283 ,  C01B2203/1076 ,  H01M8/0612 ,  H01M8/0668 ,  H01M8/0675 ,  Y02P20/52 ,  Y02P20/584

摘要： Provided is a process for preparing a non-pyrophoric catalyst having about 2 to 20 wt. % of a copper component, wherein at least 50 wt. % of the copper component is in the form of a copper oxide, aluminum oxide-spinel. The catalyst can be prepared by forming a mixture of a copper precursor and an alumina precursor, coextruding the mixture, drying the coextrudate and calcining the dried coextrudate at a temperature of at least 600° C. In other aspects, the invention also relates to processes for the activation of copper-based catalysts and for the regeneration of deactivated copper-based catalysts.

摘要翻译： 提供了一种制备具有约2至20重量％的非发烟催化剂的方法。 ％的铜组分，其中至少50wt。 铜成分的百分比为氧化铜 - 氧化铝 - 尖晶石的形式。 可以通过形成铜前体和氧化铝前体的混合物，共混挤出混合物，干燥共挤出物并在至少600℃的温度下煅烧干燥的共挤出物来制备催化剂。在其它方面，本发明还涉及方法 用于铜基催化剂的活化和用于活化的铜基催化剂的再生。

公开(公告)号：US06913739B2

公开(公告)日：2005-07-05

申请号：US10035525

申请日：2001-11-09

申请人： Lawrence Shore ,  Wolfgang F. Ruettinger ,  Robert J. Farrauto

发明人： Lawrence Shore ,  Wolfgang F. Ruettinger ,  Robert J. Farrauto

IPC分类号： B01J23/56 ,  B01J23/63 ,  B01J23/76 ,  B01J23/83 ,  B01J23/86 ,  B01J23/89 ,  B01J37/02 ,  C01B3/16 ,  C01B3/58 ,  H01M8/06 ,  C01B31/20

CPC分类号： B01J37/0248 ,  B01J23/56 ,  B01J23/63 ,  B01J23/76 ,  B01J23/83 ,  B01J23/868 ,  B01J23/894 ,  B01J37/0205 ,  C01B3/16 ,  C01B3/583 ,  C01B2203/0205 ,  C01B2203/0283 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/146 ,  H01M8/0612 ,  H01M8/0662 ,  Y02P20/52

摘要： The invention provides processes for selectively oxidizing carbon monoxide from an input gas stream that contains carbon monoxide, oxygen and hydrogen. The process includes the step of contacting the input gas stream with a preferential oxidation catalyst. The preferential oxidation catalysts are copper-based catalysts containing low concentrations of platinum group metals. In some embodiments, the processes of the invention are conducted using preferential oxidation catalysts having an oxide support on which is dispersed copper or an oxide thereof, a platinum group metal and a reducible metal oxide. In other embodiments, the processes of the invention are conducted with a preferential oxidation catalysts having a cerium oxide support on which is dispersed copper or an oxide thereof and a platinum group metal.

摘要翻译： 本发明提供从含有一氧化碳，氧气和氢气的输入气流中选择性地氧化一氧化碳的方法。 该方法包括使输入气流与优先氧化催化剂接触的步骤。 优选的氧化催化剂是含有低浓度铂族金属的铜基催化剂。 在一些实施方案中，本发明的方法使用具有氧化物载体的优先氧化催化剂进行，其上分散有铜或其氧化物，铂族金属和可还原的金属氧化物。 在其它实施方案中，本发明的方法用具有氧化铈载体的优先氧化催化剂进行，其上分散有铜或其氧化物和铂族金属。

公开(公告)号：US06790432B2

公开(公告)日：2004-09-14

申请号：US10170079

申请日：2002-06-12

申请人： Wolfgang F. Ruettinger ,  Robert J. Farrauto

发明人： Wolfgang F. Ruettinger ,  Robert J. Farrauto

IPC分类号： C01B316

CPC分类号： B01J37/038 ,  B01J23/62 ,  B01J23/626 ,  B01J23/63 ,  B01J35/04 ,  B01J37/0207 ,  B01J37/0215 ,  C01B3/16 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/1023 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1241 ,  H01M8/0618 ,  H01M8/0631 ,  Y02P20/52

摘要： Provided is a method and apparatus for producing hydrogen from an input gas stream containing carbon monoxide and steam that includes contacting the input gas stream with a catalyst. The catalyst contains an inorganic oxide support; a platinum group metal dispersed on the inorganic oxide support; and a methane suppressing dispersed on the inorganic oxide support. The methane suppressing component is selected from the group consisting of oxides of tin, oxides of gallium and combinations thereof. Also provided are preferred catalyst preparations.

摘要翻译： 提供了一种从包含一氧化碳和蒸汽的输入气流产生氢气的方法和装置，其包括使输入气流与催化剂接触。 催化剂含有无机氧化物载体; 分散在无机氧化物载体上的铂族金属; 和分散在无机氧化物载体上的甲烷抑制。 甲烷抑制成分选自锡的氧化物，镓的氧化物及其组合。 还提供优选的催化剂制剂。

公开(公告)号：US08221693B2

公开(公告)日：2012-07-17

申请号：US11194816

申请日：2005-08-01

申请人： Lawrence Shore ,  Robert J. Farrauto

发明人： Lawrence Shore ,  Robert J. Farrauto

IPC分类号： B01D53/62

CPC分类号： B01J12/007 ,  B01J19/2485 ,  B01J2219/00164 ,  C01B3/583 ,  C01B2203/044 ,  C01B2203/047

摘要： A two stage-carbon monoxide preferential oxidation article and method that uses a single injection of an O2-containing gas.

摘要翻译： 一种二氧化碳优先氧化制品和使用单次注入含氧气体的方法。

公开(公告)号：US07704486B2

公开(公告)日：2010-04-27

申请号：US11059148

申请日：2005-02-16

申请人： Oleg Mikhailovich Ilinich ,  Robert J. Farrauto ,  Wolfgang Friedrich Ruettinger ,  Xiaolin Yang

发明人： Oleg Mikhailovich Ilinich ,  Robert J. Farrauto ,  Wolfgang Friedrich Ruettinger ,  Xiaolin Yang

IPC分类号： C01B3/16

CPC分类号： C01B3/16 ,  B01J23/63 ,  B01J37/0018 ,  B01J2523/00 ,  C01B2203/107 ,  C01B2203/1082 ,  Y02P20/52 ,  B01J2523/31 ,  B01J2523/3718 ,  B01J2523/828 ,  B01J2523/3725

摘要： A water gas shift catalyst comprising a platinum group metal dispersed on an inorganic oxide support modified with a carbon-containing burn-out additive and a rare earth oxide. A water gas shift catalyst containing alumina, a platinum group metal, and oxides of Pr and Nd are also disclosed.

摘要翻译： 一种水煤气变换催化剂，其包含分散在用含碳燃烧添加剂和稀土氧化物改性的无机氧化物载体上的铂族金属。 还公开了含有氧化铝，铂族金属和Pr和Nd的氧化物的水煤气变换催化剂。

公开(公告)号：US5756053A

公开(公告)日：1998-05-26

申请号：US646180

申请日：1996-05-07

申请人： Jeffrey B. Hoke ,  Matthew P. Larkin ,  Robert J. Farrauto ,  Kenneth E. Voss ,  Robert E. Whiteley ,  Leonard M. Quick

发明人： Jeffrey B. Hoke ,  Matthew P. Larkin ,  Robert J. Farrauto ,  Kenneth E. Voss ,  Robert E. Whiteley ,  Leonard M. Quick

IPC分类号： B01D53/86 ,  B01D53/94 ,  B01J23/10 ,  B01J23/40 ,  B01J23/63 ,  B01J29/72 ,  B01J35/10 ,  B01J37/02 ,  F02B3/06 ,  F24C15/20 ,  B01D53/34

CPC分类号： B01D53/944 ,  B01D53/864 ,  B01D53/8668 ,  B01D53/9481 ,  B01J23/10 ,  B01J23/63 ,  B01J35/10 ,  B01J37/0215 ,  B01J37/0244 ,  F24C15/205 ,  B01J29/7215 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1047 ,  B01J35/1061 ,  F02B3/06

摘要： A method for treating cooking fumes to oxidize oxidizeable particulate and gaseous components thereof includes contacting the fumes with a catalytic material containing ceria and alumina each having a BET surface of at least about 10 m.sup.2 /g, for example, ceria and activated alumina in a weight ratio of from about 1.5:1 and 1:1.5 and a BET surface area of from about 25 m.sup.2 /g to 200 m.sup.2 /g. Optionally, a catalytic metal component such as platinum or palladium may be included in the catalytic material. The foodstuffs cooking fumes are contacted with the catalyst composition (22 or 40) at a temperature of 200.degree. C. to 600.degree. C. to promote the oxidation of both particulate (atomized) animal and/or vegetable oils and fats and oxidizeable gas phase components of the fumes. Optionally, a separate, supplemental gas phase oxidation catalyst (42) may be used in conjunction with and downstream of the above-described catalyst (40) to provide a two-catalyst system for treating cooking fumes.

公开(公告)号：US5750458A

公开(公告)日：1998-05-12

申请号：US271687

申请日：1994-07-07

申请人： Teresa Kennelly ,  John K. Hochmuth ,  Ting C. Chou ,  Robert J. Farrauto

发明人： Teresa Kennelly ,  John K. Hochmuth ,  Ting C. Chou ,  Robert J. Farrauto

IPC分类号： B01J23/63 ,  B01J23/96 ,  B01J38/12 ,  C01G55/00 ,  F23C13/00 ,  B01J23/10 ,  C01F17/00

CPC分类号： B01J38/12 ,  B01J23/63 ,  B01J23/96

摘要： A catalyst composition containing one or more binary oxides of palladium and rare earth metal such as Ce, La, Nd, Pr and/or Sm. The catalyst composition is used for the catalytic combustion of gaseous combustion mixtures of oxygen and carbonaceous fuels such as methane, e.g., a natural gas/air combustion mixture. Specific preferred binary oxides may be, for example, M.sub.2 O.sub.3.PdO (e.g., La.sub.2 O.sub.3.PdO) or 2M.sub.2 O.sub.3.PdO, wherein in each case M is La, Nd or Sm. A process of combusting gaseous carbonaceous fuels includes contacting a catalyst as described above under combustion conditions, e.g., 925.degree. C. to 1650.degree. C. and 1 to 20 atmospheres pressure, to carry out sustained combustion of the combustion mixture, including catalytically supported thermal combustion. Regeneration of over-temperatured M.sub.2 O.sub.3.PdO catalyst is also provided for.

公开(公告)号：US5462907A

公开(公告)日：1995-10-31

申请号：US247625

申请日：1994-05-23

申请人： Robert J. Farrauto ,  Kenneth E. Voss ,  Ronald M. Heck

发明人： Robert J. Farrauto ,  Kenneth E. Voss ,  Ronald M. Heck

IPC分类号： B01D53/86 ,  B01D53/94 ,  B01J23/10 ,  B01J23/40 ,  B01J23/63 ,  B01J29/72 ,  B01J35/10 ,  B01J37/02 ,  F02B3/06 ,  F24C15/20 ,  B01J21/04 ,  B01J23/42

CPC分类号： B01D53/9481 ,  B01D53/864 ,  B01D53/8668 ,  B01D53/944 ,  B01J23/10 ,  B01J23/63 ,  B01J35/10 ,  B01J37/0215 ,  B01J37/0244 ,  B01J29/7215 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1047 ,  B01J35/1061 ,  F02B3/06

摘要： Oxidation catalyst compositions include a catalytic material containing ceria and alumina each having a surface area of at least about 10 m.sup.2 /g, for example, ceria and activated alumina in a weight ratio of from about 1.5:1 to 1:1.5. Optionally, platinum may be included in the catalytic material in amounts which are sufficient to promote gas phase oxidation of CO and HC but which are limited to preclude excessive oxidation of SO.sub.2 to SO.sub.3. Alternatively, palladium in any desired amount may be included in the catalytic material. The catalyst compositions have utility as oxidation catalysts for pollution abatement of exhausts contianing unburned fuel or oil. For example, the catalyst compositions may be used in a method to treat diesel engine exhaust by contacting the hot exhaust with the catalyst composition to promote the oxidation of the volatile organic fraction component of particulates in the exhaust.

摘要翻译： 氧化催化剂组合物包括含有表面积至少约10m 2 / g的二氧化铈和氧化铝的催化材料，例如二氧化铈和活性氧化铝，重量比为约1.5:1至1:1.5。 任选地，铂可以以足以促进CO和HC的气相氧化的量包含在催化材料中，但限制为排除SO2过度氧化成SO 3。 或者，任何所需量的钯可以包括在催化材料中。 催化剂组合物可用作氧化催化剂，用于污染消除未燃燃料或油的废气。 例如，催化剂组合物可用于通过使热排气与催化剂组合物接触来促进废气中的微粒的挥发性有机部分组分的氧化来处理柴油发动机排气的方法。

公开(公告)号：US5214912A

公开(公告)日：1993-06-01

申请号：US776907

申请日：1991-10-16

申请人： Robert J. Farrauto ,  Teresa Kennelly ,  Earl M. Waterman ,  Melvin C. Hobson, Jr.

发明人： Robert J. Farrauto ,  Teresa Kennelly ,  Earl M. Waterman ,  Melvin C. Hobson, Jr.

IPC分类号： F23C13/00 ,  F23R3/40

CPC分类号： F23C13/00 ,  F23C13/08 ,  F23R3/40

摘要： A method for operating a palladium oxide containing catalytic combustor useful, e.g., for powering a gas turbine, wherein the palladium oxide is supported on a metal oxide such as alumina, ceria, titania or tantalum oxide. The method involves maintaining control of the temperature within the combustor in such a manner as to insure the presence of palladium oxide. By maintaining the temperature below about 800.degree. C. decomposition of palladium oxide into metallic palladium is avoided and high catalytic activity is retained. Regeneration of catalyst following inactivation resulting from an over-temperature is accomplished by using a heat soak in a temperature range which varies depending on the metal oxide used to support the palladium oxide.

摘要翻译： 一种用于操作含氧化钯的催化燃烧器的方法，其可用于例如为燃气轮机供电，其中氧化钯负载在诸如氧化铝，二氧化铈，二氧化钛或氧化钽的金属氧化物上。 该方法包括以确保氧化钯存在的方式维持燃烧室内温度的控制。 通过保持温度低于约800℃，避免氧化钯分解成金属钯，并保持高催化活性。 通过在根据用于负载氧化钯的金属氧化物而变化的温度范围内的热浸泡来实现由过温引起的失活后催化剂的再生。

公开(公告)号：US4863893A

公开(公告)日：1989-09-05

申请号：US888179

申请日：1986-08-06

申请人： Robert J. Farrauto ,  Hyo C. Lee ,  W. Robert Hatfield

发明人： Robert J. Farrauto ,  Hyo C. Lee ,  W. Robert Hatfield

IPC分类号： B01J23/46 ,  B01J35/06 ,  C01B21/26

CPC分类号： C01B21/265 ,  B01J23/464 ,  B01J35/06 ,  C01B21/267

摘要： Platinum-rhodium and platinum-palladium-rhodium gauzes bearing a high surface area coating (in excess of 50 cm.sup.2 /g) of platinum ease initiation of ammonia oxidation.

摘要翻译： 具有高表面积涂层（超过50cm2 / g）铂的铂 - 铑和铂 - 铑 - 铑纱布容易引发氨氧化。