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    Process for the continuous polymerization with micromixing of reactive fluids
    1.
    发明授权
    Process for the continuous polymerization with micromixing of reactive fluids 失效
    用反应流体微混合连续聚合的方法

    公开(公告)号：US06892958B2

    公开(公告)日：2005-05-17

    申请号：US10331997

    申请日：2002-12-31

    申请人： Xavier Marcarian ,  Christophe Navarro ,  Laurent Falk ,  Fernand Pla

    发明人： Xavier Marcarian ,  Christophe Navarro ,  Laurent Falk ,  Fernand Pla

    IPC分类号： B01F5/02 ,  B01F5/20 ,  B01F13/00 ,  B01F13/10 ,  B01J19/26 ,  C08F2/00 ,  C08F2/01 ,  C08F4/08 ,  C08F4/46 ,  C08F20/12 ,  B05B12/04 ,  B63H25/46

    CPC分类号： B01F5/205 ,  B01F5/0256 ,  B01F13/0059 ,  B01F2013/1091 ,  B01F2215/0049 ,  B01J19/26 ,  B01J2219/00162 ,  B01J2219/00164 ,  B29K2033/12

    摘要： The process for the continuous preparation of homopolymers or copolymers by free-impinging-jet micromixing of fluids formed (1) of monomer(s) and (2) of an initiator system consists in micromixing the said fluids (1) and (2) and in recovering the mixture of these fluids in the form of a resultant jet Jr, originating from the point of impingement (I), the micromixture being obtained by: a) forming at least one group of at least two jets Ja of the said identical or different fluids, these jets coinciding at a point of impingement (I), the jets Ja of the same group all being of identical geometry, their axes being arranged such that their projections on a plane perpendicular to the axis (A) of the resultant jet Jr are distributed angularly in a uniform manner and these axes being inclined relative to the said axis (A) by the same non-zero angle α of not more than 90°; b) simultaneously directing at the point of impingement (I) at least one jet Jb of a fluid which is different from at least one of the fluids of the said jets Ja for forming the resultant jet Jr, the axis of the jet(s) Jb being inclined relative to the axis of the resultant jet Jr by an angle β which is less than the angle α; and c) recovering the mixture of the fluids in the jets Ja and Jb in the form of the resultant jet Jr consisting of the homopolymers or copolymers.

    摘要翻译： 通过自由冲击微混合形成（1）单体和（2）引发剂体系的流体连续制备均聚物或共聚物的方法包括将所述流体（1）和（2）和 在回收起始于冲击点（I）的合成射流Jr形式的这些流体的混合物时，该微混合物通过以下步骤获得：a）形成至少一组至少两组所述相同或 不同的流体，这些射流在冲击点（I）处重合，同一组的射流Ja都具有相同的几何形状，它们的轴被布置成使得它们的凸起在垂直于合成射流的轴线（A）的平面上 Jr以均匀的方式成角度地分布，并且这些轴相对于所述轴线（A）倾斜相同的非零角度α为不大于90°; b）在冲击点（I）的同时引导至少一个与所述喷嘴J j的流体中的至少一种流体不同的流体的喷射流Jb，以形成合成射流Jr， Jb相对于合成射流Jr的轴线倾斜小于角度α的角度β; 和c）以由均聚物或共聚物组成的合成喷嘴Jr的形式回收喷嘴J j和J b中的流体混合物。

    Composition containing a lactic acid homopolymer and a block copolymer
    4.
    发明授权
    Composition containing a lactic acid homopolymer and a block copolymer 有权
    含有乳酸均聚物和嵌段共聚物的组合物

    公开(公告)号：US08183322B2

    公开(公告)日：2012-05-22

    申请号：US12678799

    申请日：2008-08-26

    申请人： Pierre Gerard ,  Christophe Navarro

    发明人： Pierre Gerard ,  Christophe Navarro

    IPC分类号： C08L53/00 ,  C08L67/00 ,  C08L69/00

    CPC分类号： C08F293/005 ,  C08L53/00 ,  C08L2666/04 ,  C08L2666/14 ,  C08L2666/02

    摘要： The present invention relates to a composition containing at least one lactic acid homopolymer and at least one block copolymer with a polydispersity index ranging from 1.5 to 5 and comprising: at least one block A that is miscible with the homopolymer and formed from monomers containing at least one methacrylate of formula CH2═C(CH3)—COOR1, and at least one block B that is immiscible with the homopolymer and formed from monomers containing at least one alkyl acrylate of formula CH2═CH—COOR2 and/or at least one methacrylate of formula CH2═C(CH3)—COOR3. The invention also relates to the use of this composition for the manufacture of medical articles, textile fibers, thermoformed plates or packaging, in particular films or bottles.

    摘要翻译： 本发明涉及含有至少一种乳酸均聚物和至少一种多分散指数为1.5至5的嵌段共聚物的组合物，其包含：至少一种与均聚物可混溶并由至少含有至少 一种式CH 2 = C（CH 3）-COOR 1的甲基丙烯酸酯和至少一种与均聚物不混溶并由含有至少一种式CH 2 = CH-COOR 2的丙烯酸烷基酯和/或至少一种甲基丙烯酸甲酯的单体形成的嵌段B 式CH 2 = C（CH 3）-COOR 3。 本发明还涉及该组合物用于制造医疗制品，纺织纤维，热成型板或包装，特别是薄膜或瓶子的用途。

    CROSSLINKED COMPOSITION COMPRISING A CORE/SHELL COPOLYMER, METHOD OF OBTAINING SAME AND USES THEREOF
    6.
    发明申请
    CROSSLINKED COMPOSITION COMPRISING A CORE/SHELL COPOLYMER, METHOD OF OBTAINING SAME AND USES THEREOF 审中-公开
    包含核心/壳共聚物的交联组合物，其获得方法及其用途

    公开(公告)号：US20090306246A1

    公开(公告)日：2009-12-10

    申请号：US12096237

    申请日：2006-12-01

    申请人： Laurent Gervat ,  Gilles Meunier ,  Christophe Navarro ,  Elisabeth Bay ,  Laure Mauboules

    发明人： Laurent Gervat ,  Gilles Meunier ,  Christophe Navarro ,  Elisabeth Bay ,  Laure Mauboules

    IPC分类号： C08L33/12

    CPC分类号： C08L23/16 ,  A43B13/04 ,  B60C1/00 ,  B60C1/0008 ,  B60C1/0016 ,  B60C1/0025 ,  B60C2009/0021 ,  C08F255/02 ,  C08F265/04 ,  C08F279/02 ,  C08K3/06 ,  C08K3/22 ,  C08K3/36 ,  C08K5/0025 ,  C08K5/09 ,  C08K5/54 ,  C08L21/00 ,  C08L23/02 ,  C08L23/0815 ,  C08L23/22 ,  C08L51/00 ,  C08L51/04 ,  C08L51/06 ,  C08L61/06 ,  C08L2314/06 ,  C08L2666/24 ,  C08L2666/04 ,  C08L2666/02 ,  C08L2666/06

    摘要： The invention relates to is a crosslinked composition containing in parts by weight: 20 to 100 parts of at least one elastomer (I), 2 to 50 parts of at least one core/shell copolymer (II), and 0 to 100 parts of at least one thermoplastic polymer (III). The invention also relates to a method of producing one such crosslinked composition, which is characterized in that it consists in: mixing an elastomer and a core/shell copolymer optionally in the presence of: a grafted polyolefin, a plasticizer, fillers and/or additives, and a suitably-selected crosslinking system, and subsequently crosslinking said mixture at a suitable temperature. In a preferred embodiment of the invention, the mixture is crosslinked at a temperature of between 150 and 320° C. The invention method be carried out in an internal mixer, or, alternately, in a twin-screw extruder or a Buss®-type co-kneader. Depending on the case, the resulting mass is calendared or extruded, cooled and subsequently granulated. The granules thus obtained are then ready to be transformed, by means of heating, into sheets, plates, extrusions, tubes or other desired products. The invention further relates to the use of one such composition in the production of ducts, pipes, tubing, couplers or similar for conveying fluids, such as the fluid transfer conduits, pipes and other elements which are used in the automobile industry in braking, cooling, steering and air-conditioning systems. The inventive crosslinked composition can also be used in the production of belts, tires, electrical cable sheaths, and shoe soles.”

    摘要翻译： 本发明涉及一种交联组合物，其含有重量份：20-100份至少一种弹性体（I），2-50份至少一种核/壳共聚物（II）和0-100份 至少一种热塑性聚合物（III）。 本发明还涉及生产一种这样的交联组合物的方法，其特征在于它包括：将弹性体和核/壳共聚物任选地在以下存在下混合：接枝聚烯烃，增塑剂，填料和/或添加剂 和适当选择的交联体系，随后在合适的温度下交联所述混合物。 在本发明的一个优选实施方案中，该混合物在150-320℃的温度下交联。本发明方法在内部混合器中进行，或者在双螺杆挤出机或Buss（R） 型共捏合机。 根据情况，将所得物料压延或挤出，冷却并随后造粒。 然后将如此获得的颗粒通过加热转化成片，板，挤出物，管或其它所需产物。 本发明还涉及一种这样的组合物在制造用于输送流体的管道，管道，管道，耦合器或类似物中的用途，例如用于汽车工业中的流体输送导管，管道和其它元件，用于制动，冷却 ，转向和空调系统。 本发明的交联组合物也可用于生产带，轮胎，电缆护套和鞋底。“

    Method for continuously and dynamically mixing at least two fluids, and micromixer
    7.
    发明申请
    Method for continuously and dynamically mixing at least two fluids, and micromixer 失效
    用于连续和动态地混合至少两种流体的方法和微混合器

    公开(公告)号：US20050237854A1

    公开(公告)日：2005-10-27

    申请号：US10517190

    申请日：2003-05-23

    申请人： Christophe Navarro ,  Peter Walzel

    发明人： Christophe Navarro ,  Peter Walzel

    IPC分类号： B01F3/10 ,  B01F7/00 ,  B01F7/16 ,  B01F7/18 ,  B01F13/00 ,  B01J14/00 ,  C08F2/01 ,  C08F20/00 ,  C08F120/06 ,  B01F7/12

    CPC分类号： B01F7/008 ,  B01F3/10 ,  B01F7/00808 ,  B01F7/00816 ,  B01F7/183 ,  B01F13/0059 ,  B01F2215/045 ,  B01F2215/0468 ,  B01F2215/0472 ,  B01F2215/0481 ,  B01F2215/0495 ,  Y10S366/01 ,  Y10S366/02 ,  Y10S366/03 ,  Y10S366/04

    摘要： The invention relates to a method for continuously and dynamically mixing at least two fluids. Said method comprises the following steps: a) the rotor (1) of a micromixer is rotatably driven, said micromixer comprising a rotor (1) which is provided with a shaft (2) encompassing blades (3) that are arranged in groups (3a-3g), a stator (4) which is provided with at least one inlet (5) for a first fluid, at least one inlet (6) for a second fluid, and an outlet (7); b) the fluids are fed into the micromixer; and c) a micromixture of the fluids is collected at the outlet (7) of the micromixer. The inventive method is particularly suitable for rapid and/or complex kinetic chemical reactions such as anionic polymerization. The invention also relates to a micromixer for carrying out said method.

    摘要翻译： 本发明涉及一种用于连续和动态地混合至少两种流体的方法。 所述方法包括以下步骤：a）微型混合器的转子（1）被可旋转地驱动，所述微型混合器包括转子（1），转子（1）设置有围绕叶片（3）的轴（2） 设有至少一个用于第一流体的入口（5）的定子（4），用于第二流体的至少一个入口（6）和出口（7）; b）将流体进料到微混合器中; 和c）在微混合器的出口（7）收集流体的微混合物。 本发明的方法特别适用于快速和/或复杂的动力学化学反应，如阴离子聚合。 本发明还涉及一种用于执行所述方法的微混合器。