公开(公告)号：US09062261B2

公开(公告)日：2015-06-23

申请号：US12813179

申请日：2010-06-10

申请人： Xionghou Gao ,  Shuhong Sun ,  Lin Wang ,  Xinmei Pang ,  Zhifeng Wang ,  Yongfu Gao ,  Zhaoyong Liu ,  Conghua Liu ,  Jinsen Gao ,  Gang Wang ,  Yanhui Zhang ,  Tao Liu ,  Juanjuan Liu

发明人： Xionghou Gao ,  Shuhong Sun ,  Lin Wang ,  Xinmei Pang ,  Zhifeng Wang ,  Yongfu Gao ,  Zhaoyong Liu ,  Conghua Liu ,  Jinsen Gao ,  Gang Wang ,  Yanhui Zhang ,  Tao Liu ,  Juanjuan Liu

IPC分类号： C10G51/02 ,  C10G51/06 ,  C10G11/18 ,  C10G55/00 ,  C10G55/02

CPC分类号： C10G51/026 ,  C10G11/18 ,  C10G11/182 ,  C10G11/187 ,  C10G51/06 ,  C10G55/00 ,  C10G55/02 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/4006 ,  C10G2300/70

摘要： The invention relates to a catalytic cracking process for reducing sulfur content in gasoline and the device thereof, which includes a fluidized bed reactor in addition of a heavy oil catalytic cracking riser, characterized in enhancing contact time of oil-gas with the catalyst, further desulfurizing and reducing olefin content and increasing octane number in gasoline; regenerating all recycling catalysts, quality of products being stable and easily operated, reducing sulfur of gasoline to a maximum limit; adding a cooling device so as to avoid coking when the catalyst contacts with oil-gas in high temperature and decrease of yield of light oil resulted by excessively high reaction temperature of gasoline upgrading, improving products distribution, being flexible to change catalyst-oil ratio and reaction temperature of catalytic cracking reaction. The invention also provides an easily operated process for FCC desulfurization with stronger desulfurizing ability, good selectivity of products and high light oil yield, which can realize 40-80% of FCC gasoline desulfurization. Furthermore, more than 80% of FCC gasoline desulfurization can be achieved if the process is applied in combination with some particular catalysts.

摘要翻译： 本发明涉及一种用于降低汽油中硫含量的催化裂化方法及其装置，其中还包括流化床反应器以及重油催化裂化提升剂，其特征在于提高油气与催化剂的接触时间，进一步脱硫 并减少汽油中的烯烃含量和增加辛烷值; 再生所有回收催化剂，产品质量稳定且易于运行，将汽油中的硫降至最大限度; 添加冷却装置，以防止催化剂在高温下与油气接触并导致轻油产率降低，导致汽油升级反应温度过高，产物分布提高，催化剂 - 油比变化灵活， 催化裂化反应的反应温度。 本发明还提供了一种FCC脱硫脱硫能力强，产品选择性好，轻油产率高的易脱硫脱硫工艺，可实现FCC汽油脱硫40-80％。 此外，如果将该方法与某些特定催化剂结合使用，则可以实现超过80％的FCC汽油脱硫。

公开(公告)号：US07390762B2

公开(公告)日：2008-06-24

申请号：US11287415

申请日：2005-11-23

申请人： Xionghou Gao ,  Honghai Liu ,  Baojie Wang ,  Changyan Duan ,  Xinmei Pang ,  Li Zhang ,  Lianhong Zhao ,  Jiangang Ma ,  Yunheng Liu

发明人： Xionghou Gao ,  Honghai Liu ,  Baojie Wang ,  Changyan Duan ,  Xinmei Pang ,  Li Zhang ,  Lianhong Zhao ,  Jiangang Ma ,  Yunheng Liu

IPC分类号： B01J29/04 ,  B01J29/08

CPC分类号： B01J29/084 ,  B01J37/0018 ,  B01J37/0045 ,  B01J2229/64 ,  C01B39/24

摘要： A method for synthesizing high-content NaY molecular sieves with kaolin sprayed microspheres includes adding functional components and deionized water into kaolin so as to be pulped into a mixed slurry. The slurry is sprayed into microspheres. The microspheres are calcined at a temperature between 700 and 1,000° C. and mixed with a directing agent for crystallization. The resultant solid is filtrated and washed with water and then dried to obtain a final in-situ crystallized product with high content of molecular sieves.

摘要翻译： 用高岭土喷雾微球合成高含量NaY分子筛的方法包括将功能成分和去离子水添加到高岭土中，以便制成混合浆料。 将浆料喷雾到微球体中。 将微球体在700至1000℃的温度下煅烧，并与定向剂混合以进行结晶。 将所得固体过滤并用水洗涤，然后干燥，得到具有高含量分子筛的最终原位结晶产物。

公开(公告)号：US20060116277A1

公开(公告)日：2006-06-01

申请号：US11287415

申请日：2005-11-23

申请人： Xionghou Gao ,  Honghai Liu ,  Baojie Wang ,  Changyan Duan ,  Xinmei Pang ,  Li Zhang ,  Lianhong Zhao ,  Jiangang Ma ,  Yunheng Liu

发明人： Xionghou Gao ,  Honghai Liu ,  Baojie Wang ,  Changyan Duan ,  Xinmei Pang ,  Li Zhang ,  Lianhong Zhao ,  Jiangang Ma ,  Yunheng Liu

IPC分类号： B01J29/04

CPC分类号： B01J29/084 ,  B01J37/0018 ,  B01J37/0045 ,  B01J2229/64 ,  C01B39/24

摘要： A method for synthesizing high-content NaY molecular sieves with kaolin sprayed microspheres is provided, comprising that functional components and deionized water are added into the kaolin so as to be pulped mixed slurry, and the slurry is sprayed into microspheres, the sprayed microspheres are calcined at a temperature between 700 and 1,000° C. and the obtained is mixed up with directing agent for crystallization, the resultant solid is filtrated from mother liquid and washed by water. The functional components include structural agents, and the addition of the agents is about 2˜10 percent by mass of the kaolin; the structural agents are one or more of starch, graphite powder, and carboxymenthyl cellulose. Alternatively according to the present invention, one part of the sprayed microspheres with particle sizes of 20˜110 μm is calcined at high temperature to get high-temperature calcined kaolin microspheres, while the other part is calcined at a low temperature to get meta kaolin microspheres. The two parts are mixed up for crystallization reaction in hydrothermal conditions to get a crystallized product containing 40 to 60 weight percent of NaY molecular sieves, and the ratio of silicon to aluminum therein is 3.5˜5.5.

摘要翻译： 提供了一种用高岭土喷雾微球合成高含量NaY分子筛的方法，其中将功能组分和去离子水加入到高岭土中以制浆混合浆料，将浆料喷雾成微球，将喷雾的微球煅烧 在700和1000℃之间的温度下，将所得物与导向剂混合，结晶，将所得固体从母液中过滤并用水洗涤。 功能组分包括结构试剂，添加剂约为高岭土的2〜10质量％。 结构剂是淀粉，石墨粉和羧基纤维素中的一种或多种。 或者根据本发明，一部分粒径为20〜110μm的喷雾微球体在高温下煅烧得到高温煅烧高岭土微球，而另一部分在低温下煅烧得到高岭土微球 。 将两部分混合在水热条件下进行结晶反应，得到含有40〜60重量％NaY分子筛的结晶产物，硅与铝的比例为3.5〜5.5。

公开(公告)号：US09968915B2

公开(公告)日：2018-05-15

申请号：US14404774

申请日：2012-07-27

申请人： Xionghou Gao ,  Haitao Zhang ,  Di Li ,  Xueli Li ,  Hongchang Duan ,  Zhengguo Tan ,  Chaowei Liu ,  Yunfeng Zheng ,  Xiaoliang Huang ,  Jinjun Cai ,  Chenxi Zhang ,  Zhishuang Pan ,  Gengzhen Cao

发明人： Xionghou Gao ,  Haitao Zhang ,  Di Li ,  Xueli Li ,  Hongchang Duan ,  Zhengguo Tan ,  Chaowei Liu ,  Yunfeng Zheng ,  Xiaoliang Huang ,  Jinjun Cai ,  Chenxi Zhang ,  Zhishuang Pan ,  Gengzhen Cao

IPC分类号： B01J29/06 ,  B01J29/08 ,  B01J29/80 ,  B01J37/30 ,  B01J35/10 ,  C01B39/02 ,  B01J37/28 ,  C01B39/24 ,  C01B39/54 ,  B01J37/00 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08

CPC分类号： B01J29/088 ,  B01J29/084 ,  B01J29/80 ,  B01J35/10 ,  B01J35/109 ,  B01J37/009 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/28 ,  B01J37/30 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24 ,  C01B39/54

摘要： Provided is a phosphorus-containing ultrastable Y-type rare earth (RE) molecular sieve and the preparation method thereof. The method is: based on NaY molecular sieve as a raw material, obtaining “one-exchange one-roast” RE-Na Y-type molecular sieve through the steps of exchanging with RE, pre-exchanging with dispersing, and the first calcination; and then performing ammonium salt exchange, phosphorus modification, and the second calcination on the “one-exchange one-roast” RE-Na Y-type molecular sieve, wherein the sequence of the RE exchange and the pre-exchange with dispersing is unlimited, and the sequence of the ammonium salt exchange and the phosphorus modification is unlimited as well. The obtained molecular sieve contains RE oxide 1-20 wt %, phosphorus 0.1-5 wt %, and sodium oxide no more than 1.2 wt %, and has a crystallization degree of 51-69% and a lattice parameter of 2.449-2.469 nm. Heavy oil conversion rate can be increased by using the molecular sieve as an active component in a catalytic cracking catalyst.

公开(公告)号：US09844772B2

公开(公告)日：2017-12-19

申请号：US14364536

申请日：2012-04-13

申请人： Xionghou Gao ,  Haitao Zhang ,  Zhengguo Tan ,  Di Li ,  Dong Ji ,  Hongchang Duan ,  Chenxi Zhang

发明人： Xionghou Gao ,  Haitao Zhang ,  Zhengguo Tan ,  Di Li ,  Dong Ji ,  Hongchang Duan ,  Chenxi Zhang

IPC分类号： B01J29/06 ,  B01J29/80 ,  C01B39/24 ,  C01B39/02 ,  B01J35/10 ,  B01J35/08 ,  B01J37/00 ,  B01J37/30 ,  B01J29/08 ,  B01J29/40 ,  B01J35/00 ,  B01J35/02

CPC分类号： B01J29/80 ,  B01J29/088 ,  B01J29/40 ,  B01J35/002 ,  B01J35/023 ,  B01J35/08 ,  B01J35/10 ,  B01J35/1085 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/30 ,  B01J2029/062 ,  B01J2229/186 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24

摘要： The present invention relates to a heavy oil catalytic cracking catalyst and preparation method thereof. The catalyst comprises 2 to 50% by weight of an ultra-stable rare earth type Y molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of rare earth oxide. The ultra-stable rare earth type Y molecular sieve is obtained as follows: the raw material, NaY molecular sieve, is subjected to a rare earth exchange and a dispersing pre-exchange, and the molecular sieve slurry is filtered, washed and subjected to a first calcination to produce a “one-exchange one-calcination” rare earth sodium Y molecular sieve, wherein the order of the rare earth exchange and the dispersing pre-exchange is not limited; and the “one-exchange one-calcination” rare earth sodium Y molecular sieve is further subjected to ammonium salt exchange for sodium reduction and a second calcination. The catalyst provided in the present invention is characteristic in its high heavy-oil-conversion capacity, a high total liquid yield and a high light oil yield.

公开(公告)号：US20150165428A1

公开(公告)日：2015-06-18

申请号：US14404776

申请日：2012-07-27

申请人： Xionghou Gao ,  Haitao Zhang ,  Di Li ,  Zhengguo Tan ,  Hongchang Duan ,  Xueli Li ,  Chaowei Liu ,  Yunfeng Zheng ,  Xiaoliang Huang ,  Jinjun Cai ,  Zhishuang Pan ,  Xueqin Sun

发明人： Xionghou Gao ,  Haitao Zhang ,  Di Li ,  Zhengguo Tan ,  Hongchang Duan ,  Xueli Li ,  Chaowei Liu ,  Yunfeng Zheng ,  Xiaoliang Huang ,  Jinjun Cai ,  Zhishuang Pan ,  Xueqin Sun

IPC分类号： B01J29/85 ,  B01J37/08 ,  B01J37/30 ,  B01J37/04 ,  B01J21/16 ,  B01J29/70 ,  B01J29/80 ,  B01J37/06

CPC分类号： B01J29/85 ,  B01J21/16 ,  B01J29/084 ,  B01J29/088 ,  B01J29/40 ,  B01J29/605 ,  B01J29/7003 ,  B01J29/7007 ,  B01J29/7049 ,  B01J29/80 ,  B01J35/002 ,  B01J35/10 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/28 ,  B01J37/30 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24 ,  C10G11/05 ,  C10G2400/30

摘要： The present invention provides a catalytic cracking catalyst for heavy oil and preparation methods thereof. The catalyst comprises 2 to 50% by weight of a phosphorus-containing ultrastable rare earth Y-type molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of a rare earth oxide. The phosphorus-containing ultra-stable rare earth Y-type molecular sieve uses a NaY molecular sieve as a raw material. The raw material is subjected to a rare-earth exchange and a dispersing pre-exchange; the molecular sieve slurry is then filtered, washed with water and subjected to a first calcination to obtain a rare earth sodium Y molecular sieve which has been subjected to such “first-exchange first-calcination”, wherein the steps of rare earth exchange and dispersing pre-exchange are not restricted in sequence; and then the rare earth sodium Y molecular sieve which has been subjected to “one-exchange one-calcination” is subjected to “second exchange and second calcination” including ammonium exchange and a phosphorus modification, wherein the steps of the ammonium exchange and the phosphorus modification are not restricted in sequence. The steps of the ammonium exchange and the phosphorus modification can be conducted continuously or non-continuously, the second calcination is conducted after the ammonium exchange for reducing sodium, the phosphorus modification can be conducted before or after the second calcination. The catalyst provided by the invention has the characteristics of high heavy oil conversion capacity, high total liquid yield, and high yield of light oil.

摘要翻译： 本发明提供一种重油催化裂化催化剂及其制备方法。 该催化剂含有2〜50重量％的含磷超纯稀土Y型分子筛，0.5〜30重量％的一种或多种其它分子筛，0.5〜70重量％的粘土，1.0〜65重量％ 的耐高温无机氧化物，0.01〜12.5重量％的稀土类氧化物。 含磷超稳定稀土Y型分子筛采用NaY分子筛为原料。 原料进行稀土交换和分散预交换; 然后将分子筛浆液过滤，用水洗涤并进行第一次煅烧，得到已经进行了这种“第一次交换第一次煅烧”的稀土钠Y分子筛，其中稀土交换和分散的步骤 预交换不受限制; 然后进行“一次一煅烧”的稀土钠Y分子筛进行铵交换和磷改性的“二次交换和二次煅烧”，其中铵交换和磷的步骤 修改不受限制。 铵交换和磷改性的步骤可以连续地或不连续地进行，第二次煅烧在铵还原钠进行之后进行，可以在第二次煅烧之前或之后进行磷改性。 本发明提供的催化剂具有重油转化率高，总液体产率高，轻油产率高的特点。

公开(公告)号：US09789475B2

公开(公告)日：2017-10-17

申请号：US14365489

申请日：2012-04-13

申请人： Xionghou Gao ,  Haitao Zhang ,  Zhengguo Tan ,  Di Li ,  Dong Ji ,  Hongchang Duan ,  Chenxi Zhang

发明人： Xionghou Gao ,  Haitao Zhang ,  Zhengguo Tan ,  Di Li ,  Dong Ji ,  Hongchang Duan ,  Chenxi Zhang

IPC分类号： B01J29/06 ,  C01B39/24 ,  B01J29/08 ,  C10G11/05 ,  C01B39/02 ,  B01J35/02 ,  B01J37/30 ,  B01J35/10

CPC分类号： B01J29/088 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1085 ,  B01J37/30 ,  B01J2229/186 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24 ,  C10G11/05

摘要： The present invention provides an ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment. The molecular sieve comprises 1 to 20% by weight of rare earth oxide, not more than 1.2% by weight of sodium oxide, has a crystallinity of 51 to 69%, and a lattice parameter of 2.451 nm to 2.469 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 μm and a D(v,0.9) of not more than 20 μm. Cracking catalysts using the molecular sieve as an active component is characterized by a high heavy-oil-conversion capacity and a high yield of valuable target products.

公开(公告)号：US20150080209A1

公开(公告)日：2015-03-19

申请号：US14364536

申请日：2012-04-13

申请人： Xionghou Gao ,  Haitao Zhang ,  Zhengguo Tan ,  Di Li ,  Dong Ji ,  Hongchang Duan ,  Chenxi Zhang

发明人： Xionghou Gao ,  Haitao Zhang ,  Zhengguo Tan ,  Di Li ,  Dong Ji ,  Hongchang Duan ,  Chenxi Zhang

IPC分类号： B01J29/80

CPC分类号： B01J29/80 ,  B01J29/088 ,  B01J29/40 ,  B01J35/002 ,  B01J35/023 ,  B01J35/08 ,  B01J35/10 ,  B01J35/1085 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/30 ,  B01J2029/062 ,  B01J2229/186 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24

摘要： The present invention relates to a heavy oil catalytic cracking catalyst and preparation method thereof. The catalyst comprises 2 to 50% by weight of an ultra-stable rare earth type Y molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of rare earth oxide. The ultra-stable rare earth type Y molecular sieve is obtained as follows: the raw material, NaY molecular sieve, is subjected to a rare earth exchange and a dispersing pre-exchange, and the molecular sieve slurry is filtered, washed and subjected to a first calcination to produce a “one-exchange one-calcination” rare earth sodium Y molecular sieve, wherein the order of the rare earth exchange and the dispersing pre-exchange is not limited; and the “one-exchange one-calcination” rare earth sodium Y molecular sieve is further subjected to ammonium salt exchange for sodium reduction and a second calcination. The catalyst provided in the present invention is characteristic in its high heavy-oil-conversion capacity, a high total liquid yield and a high light oil yield.

摘要翻译： 本发明涉及一种重油催化裂化催化剂及其制备方法。 该催化剂包含2至50重量％的超稳定稀土型Y分子筛，0.5至30重量％的一种或多种其它分子筛，0.5至70重量％的粘土，1.0至65重量％ 的耐高温无机氧化物和0.01〜12.5重量％的稀土氧化物。 超稳定型稀土类Y分子筛的制备如下：将原料NaY分子筛进行稀土交换和分散预交换，并将分子筛浆料过滤，洗涤并进行 首先煅烧产生“一次一次煅烧”稀土钠Y分子筛，其中稀土交换和分散预交换的顺序不受限制; “一交一一”稀土钠Y分子筛进一步进行铵盐交换钠还原和二次煅烧。 本发明提供的催化剂具有高重油转化能力，总液体产率高，轻油收率高的特点。

公开(公告)号：US09968918B2

公开(公告)日：2018-05-15

申请号：US14404776

申请日：2012-07-27

申请人： Xionghou Gao ,  Haitao Zhang ,  Di Li ,  Zhengguo Tan ,  Hongchang Duan ,  Xueli Li ,  Chaowei Liu ,  Yunfeng Zheng ,  Xiaoliang Huang ,  Jinjun Cai ,  Zhishuang Pan ,  Xueqin Sun

发明人： Xionghou Gao ,  Haitao Zhang ,  Di Li ,  Zhengguo Tan ,  Hongchang Duan ,  Xueli Li ,  Chaowei Liu ,  Yunfeng Zheng ,  Xiaoliang Huang ,  Jinjun Cai ,  Zhishuang Pan ,  Xueqin Sun

IPC分类号： B01J29/06 ,  B01J29/85 ,  C01B39/24 ,  C01B39/02 ,  B01J35/10 ,  C10G11/05 ,  B01J37/28 ,  B01J29/08 ,  B01J29/40 ,  B01J21/16 ,  B01J29/70 ,  B01J29/80 ,  B01J37/06 ,  B01J37/08 ,  B01J37/30 ,  B01J35/00 ,  B01J37/00 ,  B01J29/60 ,  B01J37/04

CPC分类号： B01J29/85 ,  B01J21/16 ,  B01J29/084 ,  B01J29/088 ,  B01J29/40 ,  B01J29/605 ,  B01J29/7003 ,  B01J29/7007 ,  B01J29/7049 ,  B01J29/80 ,  B01J35/002 ,  B01J35/10 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/28 ,  B01J37/30 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24 ,  C10G11/05 ,  C10G2400/30

摘要： The present invention provides a catalytic cracking catalyst for heavy oil and preparation methods thereof. The catalyst comprises 2 to 50% by weight of a phosphorus-containing ultrastable rare earth Y-type molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of a rare earth oxide. The phosphorus-containing ultra-stable rare earth Y-type molecular sieve uses a NaY molecular sieve as a raw material. The raw material is subjected to a rare-earth exchange and a dispersing pre-exchange; the molecular sieve slurry is then filtered, washed with water and subjected to a first calcination to obtain a rare earth sodium Y molecular sieve which has been subjected to such “first-exchange first-calcination”, wherein the steps of rare earth exchange and dispersing pre-exchange are not restricted in sequence; and then the rare earth sodium Y molecular sieve which has been subjected to “one-exchange one-calcination” is subjected to “second exchange and second calcination” including ammonium exchange and a phosphorus modification, wherein the steps of the ammonium exchange and the phosphorus modification are not restricted in sequence. The steps of the ammonium exchange and the phosphorus modification can be conducted continuously or non-continuously, the second calcination is conducted after the ammonium exchange for reducing sodium, the phosphorus modification can be conducted before or after the second calcination. The catalyst provided by the invention has the characteristics of high heavy oil conversion capacity, high total liquid yield, and high yield of light oil.

公开(公告)号：US20150175432A1

公开(公告)日：2015-06-25

申请号：US14365432

申请日：2012-04-13

申请人： Xionghou Gao ,  Haitao Zhang ,  Hongchang Duan ,  Chaowei Liu ,  Di Li ,  Xueli Li ,  Zhengguo Tan ,  Yunfeng Zheng ,  Xiaoliang Huang ,  Jinjun Cai ,  Chenxi Zhang

发明人： Xionghou Gao ,  Haitao Zhang ,  Hongchang Duan ,  Chaowei Liu ,  Di Li ,  Xueli Li ,  Zhengguo Tan ,  Yunfeng Zheng ,  Xiaoliang Huang ,  Jinjun Cai ,  Chenxi Zhang

IPC分类号： C01B39/24 ,  B01J29/08 ,  B01J37/08 ,  C01B39/02

CPC分类号： C01B39/24 ,  B01J29/084 ,  B01J29/088 ,  B01J29/80 ,  B01J35/023 ,  B01J35/10 ,  B01J35/109 ,  B01J37/08 ,  B01J37/30 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C10G11/05

摘要： The present invention provides a magnesium-modified ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment, and finally to a magnesium modification. The molecular sieve comprises 0.2 to 5% by weight of magnesium oxide, 1 to 20% by weight of rare earth oxide, and not more than 1.2% by weight of sodium oxide, and has a crystallinity of 46 to 63%, and a lattice parameter of 2.454 nm to 2.471 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 μm and a D(v,0.9) of not more than 20 μm. Such a molecular sieve has both high stability and high selectivity for the target product, while cracking catalysts using the molecular sieve as an active component is characterized by a high heavy-oil-conversion capacity and a high yield of valuable target products.

摘要翻译： 本发明提供一种镁改性超稳定稀土类Y分子筛及其制备方法，该方法是以NaY分子筛为原料进行稀土交换和分散预交换， 然后进行超稳定化煅烧处理，最后进行镁改性。 分子筛含有0.2〜5重量％的氧化镁，1〜20重量％的稀土氧化物和1.2重量％的氧化钠，结晶度为46〜63％，晶格 参数为2.454 nm至2.471 nm。 与现有技术相反，在通过该方法制备的分子筛中，稀土离子位于钠盐网箱中，这通过在反向交换过程中没有稀土离子损失的事实来证明。 此外，通过这种方法制备的分子筛具有不大于3.0μm的分子粒度D（v，0.5）和不大于20μm的D（v，0.9）。 这种分子筛对于目标产物具有高稳定性和高选择性，而使用分子筛作为活性组分的裂化催化剂的特征在于高重油转化能力和高产率的有价值的目标产物。