DIRECT CONVERSION OF OLEFIN TO OLEFIN OXIDE BY MOLECULAR OXYGEN
    5.
    发明申请
    DIRECT CONVERSION OF OLEFIN TO OLEFIN OXIDE BY MOLECULAR OXYGEN 有权
    通过分子氧直接转化烯烃到氧化烯

    公开(公告)号:US20130296586A1

    公开(公告)日:2013-11-07

    申请号:US13979393

    申请日:2012-01-18

    摘要: The present invention relates to a direct conversion of olefin to olefin oxide, which are important and versatile intermediates used in the production of a large variety of valuable consumer products such as polyurethane foams, polymers, alkylene glycol, cosmetics, food emulsifiers and as fumigants and insecticides. More specifically, the present invention provides a process for producing an olefin oxide which comprises reacting an olefin with oxygen in the presence of a halogen compound additive and a catalyst comprising copper, ruthenium or both thereof.

    摘要翻译: 本发明涉及烯烃直接转化为烯烃氧化物,其是用于生产大量有价值的消费品如聚氨酯泡沫,聚合物,亚烷基二醇,化妆品,食品乳化剂和作为熏蒸剂的重要且通用的中间体,以及 杀虫剂。 更具体地说,本发明提供了一种制备烯烃氧化物的方法,其包括在卤素化合物添加剂和包含铜,钌或其二者的催化剂的存在下使烯烃与氧反应。

    Direct conversion of olefin to olefin oxide by molecular oxygen
    7.
    发明授权
    Direct conversion of olefin to olefin oxide by molecular oxygen 有权
    通过分子氧直接将烯烃转化为烯烃氧化物

    公开(公告)号:US08829211B2

    公开(公告)日:2014-09-09

    申请号:US13979393

    申请日:2012-01-18

    摘要: The present invention relates to a direct conversion of olefin to olefin oxide, which are important and versatile intermediates used in the production of a large variety of valuable consumer products such as polyurethane foams, polymers, alkylene glycol, cosmetics, food emulsifiers and as fumigants and insecticides. More specifically, the present invention provides a process for producing an olefin oxide which comprises reacting an olefin with oxygen in the presence of a halogen compound additive and a catalyst comprising copper, ruthenium or both thereof.

    摘要翻译: 本发明涉及烯烃直接转化为烯烃氧化物,其是用于生产大量有价值的消费品如聚氨酯泡沫,聚合物,亚烷基二醇,化妆品,食品乳化剂和作为熏蒸剂的重要且通用的中间体,以及 杀虫剂。 更具体地说,本发明提供了一种制备烯烃氧化物的方法,其包括在卤素化合物添加剂和包含铜,钌或其二者的催化剂的存在下使烯烃与氧反应。

    Method for regenerating catalyst for the production of methacrylic acid and process for preparing methacrylic acid
    9.
    发明授权
    Method for regenerating catalyst for the production of methacrylic acid and process for preparing methacrylic acid 失效
    用于生产甲基丙烯酸的催化剂再生方法和制备甲基丙烯酸的方法

    公开(公告)号:US07667074B2

    公开(公告)日:2010-02-23

    申请号:US11907362

    申请日:2007-10-11

    IPC分类号: C07C57/02 B01J38/66

    摘要: A catalyst for the production of methacrylic acid comprising a heteropolyacid compound containing phosphorus and molybdenum is regenerated by a method comprising the steps of drying a mixture containing a deactivated catalyst, an ammonium ion, a nitrate ion and water, molding the dried mixture, firstly calcining the molded product in an atmosphere of an oxidizing gas at a temperature of 360 to 410° C., and then secondly calcining the product in an atmosphere of a non-oxidizing gas at a temperature of 420 to 500° C. The regenerated catalyst has substantially the same catalytic activity as a fresh catalyst in a gas phase catalytic oxidation reaction of methacrolein, isobutylaldehyde, isobutane or isobutyric acid to prepare methacrylic acid.

    摘要翻译: 包含含有磷和钼的杂多酸化合物的甲基丙烯酸的催化剂通过包括以下步骤的方法再生,所述方法包括干燥含有失活催化剂,铵离子,硝酸根离子和水的混合物,模制干燥的混合物,首先煅烧 将该成型体在氧化气体气氛中在360〜410℃的温度下,然后在420〜500℃的温度下,在非氧化性气氛中二次煅烧该产物。再生催化剂具有 在甲基丙烯醛,异丁醛,异丁烷或异丁酸的气相催化氧化反应中与新鲜催化剂基本上相同的催化活性以制备甲基丙烯酸。

    Method for regenerating catalyst for the production of methacrylic acid and process for preparing methacrylic acid
    10.
    发明申请
    Method for regenerating catalyst for the production of methacrylic acid and process for preparing methacrylic acid 失效
    用于生产甲基丙烯酸的催化剂再生方法和制备甲基丙烯酸的方法

    公开(公告)号:US20080293968A1

    公开(公告)日:2008-11-27

    申请号:US11907362

    申请日:2007-10-11

    IPC分类号: C07C51/23 B01J38/18

    摘要: A catalyst for the production of methacrylic acid comprising a heteropolyacid compound containing phosphorus and molybdenum is regenerated by a method comprising the steps of drying a mixture containing a deactivated catalyst, an ammonium ion, a nitrate ion and water, molding the dried mixture, firstly calcining the molded product in an atmosphere of an oxidizing gas at a temperature of 360 to 410° C., and then secondly calcining the product in an atmosphere of a non-oxidizing gas at a temperature of 420 to 500° C. The regenerated catalyst has substantially the same catalytic activity as a fresh catalyst in a gas phase catalytic oxidation reaction of methacrolein, isobutylaldehyde, isobutane or isobutyric acid to prepare methacrylic acid.

    摘要翻译: 包含含有磷和钼的杂多酸化合物的甲基丙烯酸的催化剂通过包括以下步骤的方法再生,所述方法包括干燥含有失活催化剂,铵离子,硝酸根离子和水的混合物,模制干燥的混合物,首先煅烧 将该成型体在氧化气体气氛中在360〜410℃的温度下,然后在420〜500℃的温度下,在非氧化性气氛中二次煅烧该产物。再生催化剂具有 在甲基丙烯醛,异丁醛,异丁烷或异丁酸的气相催化氧化反应中与新鲜催化剂基本上相同的催化活性以制备甲基丙烯酸。