公开(公告)号：US11865505B2

公开(公告)日：2024-01-09

申请号：US17588398

申请日：2022-01-31

申请人： Chevron Phillips Chemical Company LP

发明人： Max P. McDaniel ,  Kathy S. Clear ,  Jeremy M. Praetorius

IPC分类号： B01J23/26 ,  B01J35/10 ,  C08F10/02 ,  B01J37/02 ,  B01J35/02 ,  B01J37/03 ,  B01J37/14 ,  B01J21/06 ,  B01J21/08 ,  C08F4/18 ,  C08F4/24 ,  C08F10/00 ,  B01J3/02 ,  B01J31/34 ,  B01J31/38 ,  B01J37/04 ,  B01J31/02

CPC分类号： B01J23/26 ,  B01J21/063 ,  B01J21/08 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/0209 ,  B01J37/035 ,  B01J37/04 ,  C08F4/18 ,  C08F4/24 ,  C08F10/00 ,  C08F10/02 ,  B01J31/0212 ,  B01J31/0274 ,  B01J31/0275 ,  B01J31/34 ,  B01J31/38 ,  B01J2231/12 ,  C08F10/00 ,  C08F4/24 ,  C08F110/02 ,  C08F2500/12

摘要： Methods for synthesizing a water-soluble titanium-silicon complex are disclosed herein. The titanium-silicon complex can be utilized to produce titanated solid oxide supports and titanated chromium supported catalysts. The titanated chromium supported catalysts subsequently can be used to polymerize olefins to produce, for example, ethylene based homopolymer and copolymers.

公开(公告)号：US20240001344A1

公开(公告)日：2024-01-04

申请号：US18208929

申请日：2023-06-13

申请人： ExxonMobil Chemical Patents Inc.

发明人： Xiaoying Bao ,  Chuansheng Bai

IPC分类号： B01J23/62 ,  B01J23/02 ,  B01J37/08 ,  B01J37/18 ,  B01J37/14

CPC分类号： B01J23/626 ,  B01J23/02 ,  B01J37/08 ,  B01J37/18 ,  B01J37/14

摘要： Processes for calcining a catalyst. The process can include subjecting a synthesized catalyst that includes Pt disposed on a support to an initial calcination that includes exposing the catalyst to a first reducing gas or a first oxidizing gas to produce an initial calcined catalyst. The process can optionally include subjecting the initial calcined. catalyst to a cycle calcination that includes exposing the initial calcined catalyst to a second reducing gas and a second oxidizing gas to produce a cycle calcined catalyst. The process can optionally include subjecting the initial or the cycle calcined catalyst to a final calcination that includes exposing the initial or the cycle calcined catalyst to a third reducing gas or a third oxidizing gas. At least one of the cycle and the final calcination can be carried out. A calcined catalyst can be obtained at the end of the cycle or the final calcination.

公开(公告)号：US20230381768A1

公开(公告)日：2023-11-30

申请号：US18307060

申请日：2023-04-26

申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA

发明人： Yusaku ONOCHI ,  Masakazu AOKI ,  Mitsuru MATSUMOTO ,  Takuto HIROSE

IPC分类号： B01J37/14 ,  B01J23/755 ,  C07C1/12

CPC分类号： B01J37/14 ,  B01J23/755 ,  C07C1/12 ,  C07C2523/755

摘要： Provided is a methanation catalyst processing method capable of suppressing degradation of a catalyst performance. A methanation catalyst processing method of the present disclosure includes oxidizing nickel through a heat treatment of a methanation catalyst by supplying an oxygen gas containing oxygen to a reactor, the reactor housing the methanation catalyst containing the nickel as a catalyst component. In the oxidizing, the oxygen gas is supplied to the reactor such that the oxygen is supplied to 1 g of the methanation catalyst at a supply rate in a range of from 0.0213 mmol-O2/sec·g-cat. to 0.0638 mmol-O2/sec·g-cat., and a time period of the heat treatment of the methanation catalyst by supplying the oxygen gas to the reactor is set to 30 minutes or more.

公开(公告)号：US20230381754A1

公开(公告)日：2023-11-30

申请号：US18202648

申请日：2023-05-26

申请人： YKK Corporation ,  NATIONAL UNIVERSITY CORPORATION UNIVERSITY OF TOYAMA

发明人： Mai Mizubayashi ,  Naoki Tomono ,  Yuka Katayama ,  Jingdi Cao ,  Noritatsu Tsubaki ,  Guohui Yang

IPC分类号： B01J23/86 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  B01J37/02 ,  B01J37/14 ,  B01J37/06 ,  B01J37/00 ,  C07C1/12

CPC分类号： B01J23/866 ,  B01J35/0066 ,  B01J35/026 ,  B01J35/1014 ,  B01J37/0209 ,  B01J37/0207 ,  B01J37/14 ,  B01J37/06 ,  B01J37/0009 ,  C07C1/12 ,  C07C2523/86

摘要： A hydrocarbon synthesis catalyst is for reacting a raw material gas including hydrogen and carbon dioxide to convert to hydrocarbons, wherein when elemental analysis of a surface of the hydrocarbon synthesis catalyst to be brought into contact with the raw material gas is performed by energy dispersive X-ray spectroscopy (SEM-EDX), 15 to 65% by mass of Fe, 10 to 40% by mass of O, 0.04 to 30% by mass of Na, 0 to 15% by mass of Ni, and 5 to 30% by mass of Cr are detected.

公开(公告)号：US20230311098A1

公开(公告)日：2023-10-05

申请号：US18023785

申请日：2021-08-31

申请人： L'Air Liquide, Société Anonyme pour I'Etude et I'Exploitation des Procédés Georges Claude

发明人： Takashi ONO ,  Takashi TERAMOTO ,  Christian DUSSARRAT ,  Nicolas BLASCO ,  Quentin DEMARLY

IPC分类号： B01J23/42 ,  B01J37/14 ,  B01J35/00 ,  B01J37/02 ,  B01J37/18 ,  C23C16/14 ,  B01J21/18 ,  C23C16/455 ,  C23C16/44

CPC分类号： B01J23/42 ,  B01J21/18 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/0066 ,  B01J37/0228 ,  B01J37/14 ,  B01J37/18 ,  C23C16/14 ,  C23C16/4417 ,  C23C16/45553 ,  C23C16/45555

摘要： The disclosure describes a method of depositing a plurality Ft metal containing nanodots on a catalyst carbon support structure by forming a vapor of Pt(PF3)4, exposing a surface of the catalyst support to the vapor of Pt(PF3)4, purging the surface of the catalyst support with a purge gas to remove the vapor of Pt(PF3)4, exposing the surface of the catalyst support to a second reactant in gaseous form, purging the surface of the catalyst support with a purge gas to remove the second reactant, and repeating these steps to form a plurality of the Pt metal containing nanodots.

公开(公告)号：US11679377B2

公开(公告)日：2023-06-20

申请号：US17161138

申请日：2021-01-28

申请人： UCHICAGO ARGONNE, LLC

发明人： Rongyue Wang ,  Krzysztof Pupek ,  Vojislav Stamenkovic

IPC分类号： B22F1/17 ,  B01J37/02 ,  B01J35/00 ,  B01J35/02 ,  B01J37/14 ,  B01J37/03 ,  B22F9/04 ,  B01J23/89 ,  B22F1/054 ,  B82Y30/00 ,  B82Y40/00

CPC分类号： B22F1/17 ,  B01J23/892 ,  B01J35/006 ,  B01J35/026 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/031 ,  B01J37/14 ,  B22F1/054 ,  B22F9/04 ,  B22F1/0553 ,  B22F2301/15 ,  B22F2301/25 ,  B82Y30/00 ,  B82Y40/00

摘要： A method for synthesis of PtNi smooth surface core/shell particles or Nano cages and porous nanocages from segregated nanoparticles.

公开(公告)号：US11628427B2

公开(公告)日：2023-04-18

申请号：US17161114

申请日：2021-01-28

申请人： UCHICAGO ARGONNE, LLC

发明人： Rongyue Wang ,  Vojislav Stamenkovic ,  Gregory K. Krumdick ,  Krzysztof Pupek

IPC分类号： B01J23/89 ,  B01J35/00 ,  B01J37/03 ,  B01J37/04 ,  B01J37/06 ,  B01J37/14 ,  B01J37/34 ,  B01J23/42 ,  B01J37/00

摘要： A process for synthesis of PtNi high surface area core/shell particles. The processing including formation of PtNi nanoparticles, exposure of the PtNi nanoparticles to oxygen to form a nickel oxide coating on the nanoparticles at the same time the segregation of Ni to surface induces a Pt-skin with PtNi core structure, removal of the nickel oxide coating to form PtNi core/Pt shell (or Pt-skin) structure.

公开(公告)号：US20220362757A1

公开(公告)日：2022-11-17

申请号：US17762730

申请日：2020-09-25

申请人： EVONIK OPERATIONS GMBH

发明人： René POSS ,  Meike ROOS ,  Monika BERWEILER ,  Maximilian GLASER

IPC分类号： B01J37/02 ,  B01J23/755 ,  B01J37/14 ,  B01J35/04 ,  B01J37/08 ,  B01J23/75 ,  B01J21/04

摘要： The present invention relates to a method for producing supported catalysts, comprising: providing a metal foam element A, which consists of metallic cobalt, an alloy of nickel and cobalt, or an arrangement of layers of nickel and cobalt, lying one over the other; applying an aluminum-containing powder MP to metal foam element A in order to obtain metal foam element AX; thermally treating metal foam element AX to achieve alloy formation between metal foam element A and aluminum-containing powder MP, in order to obtain metal foam element B; oxidatively treating metal foam element B, in order to obtain metal foam element C; and applying a catalytically active layer, comprising at least one support oxide and at least one catalytically active component, to at least part of the surface of metal foam element C, in order to obtain a supported catalyst. The present invention further relates to the supported catalysts that can be obtained using the method and to the use of said supported catalysts in chemical transformations.

公开(公告)号：US11123719B2

公开(公告)日：2021-09-21

申请号：US16697492

申请日：2019-11-27

申请人： Allen Artur Carl Reule ,  Natalia Semagina ,  Esteban Chornet

发明人： Allen Artur Carl Reule ,  Natalia Semagina ,  Esteban Chornet

IPC分类号： B01J37/18 ,  B01J29/24 ,  C07C67/37 ,  B01J29/90 ,  B01J38/10 ,  B01J29/22 ,  B01J29/40 ,  B01J29/44 ,  B01J29/46 ,  B01J29/035 ,  B01J37/30 ,  B01J29/06 ,  B01J29/10 ,  B01J29/20 ,  B01J29/12 ,  B01J29/064 ,  B01J29/072 ,  B01J29/068 ,  B01J29/14 ,  B01J29/66 ,  B01J29/67 ,  B01J29/65 ,  B01J29/72 ,  B01J29/42 ,  B01J29/68 ,  B01J29/70 ,  B01J29/76 ,  B01J29/74 ,  B01J29/18 ,  B01J37/14

摘要： A catalyst for the carbonylation of dimethyl ether to methyl acetate. The catalyst comprises a zeolite, such as a mordenite zeolite, at least one Group IB metal, such as copper, and/or at least one Group VIII metal, such as iron, and at least one Group IIB metal, such as zinc. Such a catalyst with combined metals provides enhanced catalytic activity, improved stability, and improved selectivity to methyl acetate, and does not require a halogen promoter, as compared to a metal-free or copper only zeolite.

公开(公告)号：US11072527B2

公开(公告)日：2021-07-27

申请号：US16464118

申请日：2017-11-29

申请人： MITSUI CHEMICALS, INC.

发明人： Masami Murakami ,  Hideharu Kuwamoto ,  Kenji Iwata

IPC分类号： C01B7/04 ,  B01J23/83 ,  B01J37/02 ,  B01J21/08 ,  B01J37/14 ,  B01J35/02 ,  B01J35/10

摘要： The method for producing chlorine by oxidation of hydrogen chloride with oxygen in the presence of a catalyst in a fixed-bed reactor, wherein [I] a material containing hydrogen chloride and oxygen is allowed to contact a catalyst in a temperature range of 280 to 370° C., and [II] the material containing hydrogen chloride and oxygen has an oxygen concentration of 45 to 75 vol %.