Curable composition for silicone pressure sensitive adhesives

    公开(公告)号:US12091548B2

    公开(公告)日:2024-09-17

    申请号:US18555908

    申请日:2022-03-30

    摘要: A curable composition contains: (A) a polydiorganosiloxane component including: (A1) greater than 3.1 wt % to 20 wt % of an aliphatically unsaturated polydiorganosiloxane polymer and (A3) a hydroxyl-terminated polydiorganosiloxane gum of unit formula (A-III); (B) a polyorganosilicate resin component including (B1) a capped resin, (B2) >18.53 wt % to 54.3 wt % of an uncapped resin; where the weight ratio of the uncapped resin (B2) to the capped resin (B1) is greater than 0.51 to 58.82; where component (A) and component (B) are present in amounts to provide a weight ratio of (B):(A) of 1.2:1 to less than 1.62:1; (C) a polyorganohydrogensiloxane that is present in an amount to provide a molar ratio of silicon bonded hydrogen atoms to alkenyl groups for the curable composition of 5 to 50; (D) a hydrosilylation reaction catalyst in an amount sufficient to provide 1 to 1000 ppm of platinum group metal; and (E) a condensation reaction catalyst; where the content of alkenyl groups in the curable composition is 0.017 wt % to 0.089 wt %; and where wt % values are relative to the total weight of components (A), (B), (C), (D) and (E) unless otherwise stated.

    OIL-BLEEDING SILICONE RUBBER COMPOSITION
    9.
    发明公开

    公开(公告)号:US20240101764A1

    公开(公告)日:2024-03-28

    申请号:US18272440

    申请日:2022-01-13

    摘要: An oil-bleeding silicone rubber composition which comprises



    100 parts by mass of (A) an organopolysiloxane containing an alkenyl group,
    0.2-20 parts by mass of (B) an organohydrogenpolysiloxane containing a hydrogen atom bonded to a silicon atom,
    (C) a catalyst based on a platinum-group metal, the amount of which is 0.5-500 ppm in terms of platinum-group metal amount (in mass) with respect to the total mass of the components (A) and (B),
    1-10 parts by mass of (D) a specific phenyl-group-containing organopolysiloxane,
    1-25 parts by mass of (E) a specific nonfunctional dimethylpolysiloxane, and
    (F) a specific benzotriazole derivative, the amount of which is 2-100 mol per mol of the platinum atoms contained in the component (C).

    The oil-bleeding silicone rubber composition gives cured objects having improved heat resistance, without containing any of conventional additives for improving heat resistance.