Method for preparing transparent fluorine-free, super-lubricating and oil-proof coating

    公开(公告)号:US11851578B2

    公开(公告)日:2023-12-26

    申请号:US18102724

    申请日:2023-01-29

    申请人: FUZHOU UNIVERSITY

    摘要: A method for preparing a transparent fluorine-free, super-lubricating and oil-proof coating includes: dissolving a sulfhydryl compound, a styrene copolymer, a low surface energy component, and a photoinitiator in an organic solvent, conducting a uniform stirring to obtain a mixture, coating the mixture onto a substrate, and conducting a curing under an ultraviolet lamp to obtain the transparent fluorine-free, super-lubricating and oil-proof coating. The coating has excellent adhesion resistance to various organic solvents with low surface tension and even liquids with high viscosity, and has excellent chemical stability and mechanical durability. The coating can be applied to various substrates such as glass, an aluminum sheet, a steel sheet, and a polymer without limitations of a use environment, maintains excellent adhesion resistance in the environment of air, oil, and water, and has wide applicability. Moreover, according to the method, various ways such as spraying, dip-coating and spin-coating can be used.

    COMBINATION OF CROSSLINKERS TO IMPROVE COATING PROPERTIES

    公开(公告)号:US20230012924A1

    公开(公告)日:2023-01-19

    申请号:US17785889

    申请日:2020-12-14

    申请人: BASF SE

    摘要: Multiphase polymers comprising crosslinking monomers and polyfunctional amine are disclosed. The multiphase polymer comprises a first phase polymer having a Tg from 60° C. to 240° C., a second phase polymer having a Tg from 40° C. to 240° C., and a soft phase polymer having a Tg from -25° C. to 30° C. The crosslinking monomers include a triacrylate such as trimethylol propane triacrylate, an unsaturated alkoxysilane, and an unsaturated keto monomer reactive with the polyfunctional amine. In contrast to conventional knowledge, incorporation of trimethylolpropane triacrylate reduces the minimum film forming temperature of multiphase polymers. This unusual reduction in MFFT helps to reduce the VOC requirement to form a good film at low VOC. The other crosslinking monomers including unsaturated alkoxy silane and unsaturated keto monomer which react with the polyfunctional amine improve print resistance, block resistance and lower the tackiness of paint films. The multiphase polymer is particularly suitable for use in deep base paints.

    ADDITIVE MANUFACTURING BREAK AWAY SUPPORT MATERIAL

    公开(公告)号:US20220332968A1

    公开(公告)日:2022-10-20

    申请号:US17723848

    申请日:2022-04-19

    申请人: Jabil Inc.

    摘要: An additive manufacturing composition useful as a support material for common build materials (e.g., polyamide or polyester) is comprised of a blend of an elastomer toughened styrenic polymer having discreet domains of polymerized conjugate diene dispersed within a styrenic matrix and a vinyl aromatic-maleic anhydride copolymer. The composition may be used as a support material in additive manufacturing methods such as extrusion methods (e.g., fused filament fabrication). The compositions may be tuned to realize the desired adherence to facilitate the desired support while also allowing for the mechanical removal without breakage of the underlying part or residual adhered support material.

    Coating material for formation of matte hard coat, and decorative sheet using same

    公开(公告)号:US11466111B2

    公开(公告)日:2022-10-11

    申请号:US16464068

    申请日:2017-11-14

    摘要: Embodiments provide a coating material containing: (A) 100 parts by mass of an acrylic curable resin; (B) 5-200 parts by mass of aluminum oxide particles having an average particle size of 1-100 μm; (C) 0.1-20 parts by mass of aluminum oxide fine particles having an average particle size of 1-100 nm; and (D) 1-100 parts by mass of a compound having two or more isocyanate groups per molecule. In one embodiment, the acrylic curable resin (A) includes: (a1) a structural unit derived from a hydroxy group-containing (meth)acrylic acid ester; (a2) a structural unit derived from a vinyl aromatic compound; and (a3) a structural unit derived from a (meth)acrylic acid alkyl ester. In one embodiment, the acrylic curable resin (A) may contain, in addition to the structural units (a1) and (a2): (a3-1) a structural unit derived from methyl methacrylate; and (a3-2) a structural unit derived from an aliphatic (including alicyclic) alkyl ester having 4 or more carbon atoms of a (meth)acrylic acid.