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    PROCEDE DE PREPARATION DU DIAMINOMALEONITRILE
    2.
    发明申请
    PROCEDE DE PREPARATION DU DIAMINOMALEONITRILE 审中-公开
    制备DIAMINOMALEONITRILE的方法

    公开(公告)号：WO2014013151A1

    公开(公告)日：2014-01-23

    申请号：PCT/FR2013/051395

    申请日：2013-06-14

    Applicant: ARKEMA FRANCE

    Inventor： SCHMIDT, Grégory

    IPC: C07C253/00 ,  C07C255/30

    CPC classification number: C07C253/00 ,  C07C255/30

    Abstract: La présente invention concerne un procédé de fabrication de diaminomaléonitrile, caractérisé en ce qu'il comprend au moins une étape au cours de laquelle une cétone cyanhydrine de formule RR'COHCN, avec R et R' identique ou différent, représentant une chaîne aikyle linéaire ou ramifiée ayant de 1 à 5 carbones, réagit pour donner du diaminomaléonitrile.

    Abstract translation: 二氨基马来腈的制造方法技术领域本发明涉及二氨基马来腈的制造方法，其特征在于，所述方法包括至少一个步骤，在该步骤中，具有式RR'COHCN的氰醇酮，R和R'相同或不同，为直链或支链烷基 具有1至5个碳原子的链反应以提供二氨基马来腈。

    METHOD FOR PRODUCING 4-HALOALKYL NICOTINE NITRILES
    7.
    发明申请
    METHOD FOR PRODUCING 4-HALOALKYL NICOTINE NITRILES 审中-公开
    用于生产4-HALOALKYLNICOTINNITRILEN

    公开(公告)号：WO0248111A3

    公开(公告)日：2003-03-27

    申请号：PCT/EP0114584

    申请日：2001-12-12

    Applicant: BAYER CROPSCIENCE GMBH ,  PAZENOK SERGIY ,  BASTIAANS HENRICUS MARIA MARTI

    Inventor： PAZENOK SERGIY ,  BASTIAANS HENRICUS MARIA MARTI

    IPC: C07B61/00 ,  C07C255/24 ,  C07C255/27 ,  C07C255/30 ,  C07D211/78 ,  C07D211/90 ,  C07D213/82 ,  C07D213/85 ,  A01N43/42

    CPC classification number: C07C255/24 ,  C07C255/27 ,  C07C255/30 ,  C07D211/78 ,  C07D211/90 ,  C07D213/85

    Abstract: 4-haloalkyl nicotine nitriles (I) are suitable for use as intermediate products in the production of pesticides and can be obtained by means of a method which provides that a) 3-amino-1-haloalkyl-2-propen-1-one R-C(O)-CH=CH-NH2 (II) is reacted with a compound of formula (III) to (VII), (R Z)CH=CH-CN (III) (R Z)2CH-CH2-CN (IV) Hal-CH=CH-CN (V) Hal2CH-CH2CN (VI) HC=C-CN (VII) in a condensation reaction, R meaning (C1-C4)-haloalkyl R alkyl, Hal Cl or Br and Z meaning O, S, NR or OCO, and in the case of formula (IV), the two radicals Z being able to have the aforementioned meanings, independently of each other; to produce a compound of formula (VIII), (IX) and/or (X), R-C(O)-CH=CH-NH-CH=CH-CN (VIII) R-C(O)-CH=CH-NH-CH(ZR)-CH2-CN (IX) R-C(O)-CH=CH-NH-CH(Hal)-CH2-CN (X), R, Z and Hal having the meanings given above, and subjecting the product of the reaction b) to a ring closure reaction.

    Abstract translation: 4- Haloalkylnicotinnitrile（I）是如杀虫剂的有用的中间体和可获得通过一种方法，其包括：一CH-）3-氨基-1-卤代烷基-2-丙烯-1-酮RC（O）-CH = NH 2（II）与式（III）至（VII）的化合物，（R <1> Z）CH = CH-CN（III）（R <1> Z）2CH-CH2-CN（IV）的缩合反应 HAL-CH = CH-CN（V）Hal2CH-CH 2 CN（VI）HC = C-CN（VII）其中R是（C1-C4） - 卤烷基，R <1>是烷基，Hal是Cl或Br，Z为O，S，NR <1>或OCO指两个基团Z可以是其中在式的情况下，（IV）彼此独立地假设上文给出的含义，得到式（VIII），（IX）和/或（X），RC的化合物 （O）-CH = CH-NH-CH = CH-CN（VIII）RC（O）-CH = CH-NH-CH（ZR）-CH2-CN（IX）RC（O）-CH = CH-NH -CH（哈尔）-CH 2 CN（X），其中R，Z和Hal具有上面给出的含义，并且将反应产物b）中闭环反应的受试者。 式（I）

    AMINOMETHYLENECYANOACETIC ACID ESTERS AND AMIDES
    9.
    发明申请
    AMINOMETHYLENECYANOACETIC ACID ESTERS AND AMIDES 审中-公开
    氨基酸亚硝酸酯和氨基酸

    公开(公告)号：WO1993001164A1

    公开(公告)日：1993-01-21

    申请号：PCT/EP1992001432

    申请日：1992-06-25

    Applicant: BASF AKTIENGESELLSCHAFT ,  HOLDERBAUM, Martin ,  AUMUELLER, Alexander ,  TRAUTH, Hubert

    Inventor： BASF AKTIENGESELLSCHAFT

    IPC: C07C255/30

    CPC classification number: C07D213/74 ,  C07C255/30 ,  C07C2601/14

    Abstract: Disclosed are aminomethylenecyanoacetic acid esters and amides of formula (I), in which R?1 and R2¿, independently of each other, are phenyl, naphthyl, biphenyl or a five- or six-membered hetero-aryl group which has one, two or three nitrogen atoms or one oxygen atom or one sulphur atom or one nitrogen and one oxygen atom or one nitrogen and one sulphur atom, and which may be benzannulated, whereby these groups may be substituted by one to three C¿1?-C12-alkyl groups, C1-C12-alkoxy groups, halogen atoms, cyano groups, hydroxy groups or groups of the formulae COOR?3 COR3, CONHR3, OCOR3¿ or NHCOR3, where R3 is C1-C12-alkyl, C5-C8-cycloalkyl or phenyl; X is a C2-C30-alkylene group which may contain non-adjacent oxygen atoms, a C4-C12-alkylene or C4-C12-alkinylene group (the unsaturated bonds not being adjacent to the ester oxygen atoms), a C5-C8-cycloalkylene group or a phenylene group; and Y is O or NH. These compounds can be used as stabilizers for organic materials.

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