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    Process for the preparation of certain cyclopropane carboxylates
    2.
    发明授权
    Process for the preparation of certain cyclopropane carboxylates 失效
    制备某些环丙烷羧酸盐的方法

    公开(公告)号：US5245073A

    公开(公告)日：1993-09-14

    申请号：US747702

    申请日：1991-08-20

    申请人： Joseph Cadiergue ,  Jean-Pierre Demoute ,  Jean Tessier

    发明人： Joseph Cadiergue ,  Jean-Pierre Demoute ,  Jean Tessier

    IPC分类号： A01N53/00 ,  A01N55/00 ,  A01N57/14 ,  A01N57/36 ,  A23K1/16 ,  C07C61/40 ,  C07C69/62 ,  C07C69/743 ,  C07C69/757 ,  C07C255/53 ,  C07C309/65 ,  C07C309/66 ,  C07C309/72 ,  C07D213/64 ,  C07D213/647 ,  C07D317/24 ,  C07F9/117 ,  C07F9/177 ,  C07F9/58 ,  C07F9/655 ,  C07F9/6574

    CPC分类号： C07D213/647 ,  A01N53/00 ,  A01N55/00 ,  A01N57/14 ,  A01N57/36 ,  A23K20/00 ,  C07C309/00 ,  C07C309/65 ,  C07C309/66 ,  C07C309/72 ,  C07C61/40 ,  C07C69/757 ,  C07D317/24 ,  C07F9/117 ,  C07F9/177 ,  C07F9/581 ,  C07F9/65502 ,  C07F9/65742 ,  C07C2101/02

    摘要： Novel 2,2-dimethyl-cyclopropane carboxylic acid derivatives of the formula ##STR1## wherein X.sub.1 and X.sub.2 are individually halogen, R.sub.1 is selected from the group consisting of halogen, alkyl of 1 to 8 carbon atoms, optionally substituted aryl of 6 to 14 carbon atoms, perfluoroalkyl of 1 to 8 carbon atoms, --CN and ##STR2## R' is alkyl of 1 to 8 carbon atoms, Y is selected from the group consisting of --SO.sub.2 Alk.sub.1, --SO.sub.2 Ar, ##STR3## Alk.sub.1 is optionally unsaturated alkyl of 1 to 8 carbon atoms optionally substituted with at least one halogen, Ar is aryl of 6 to 14 carbon atoms optionally substituted with at least one halogen Alk.sub.2 and Alk.sub.3 and Alk.sub.2 ' and Alk.sub.3 ' are optionally unsaturated alkyl of up to 8 carbon atoms optionally substituted with at least one halogen or together with ##STR4## form the rings ##STR5## wherein A is optionally unsaturated alkyl of up to 6 carbon atoms optionally substituted with at least one halogen, R" is alkyl of 1 to 6 carbon atoms no substituted or substituted with at least one functional group or aryl of 6 to 14 carbon atoms no substituted or substituted with at least one functional group and R is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms and residue of an alcohol used in pyrethrinoid esters having pestioidal activity.

    摘要翻译： 新颖的式Ⅰa的2,2-二甲基 - 环丙烷羧酸衍生物，其中X1和X2分别为卤素，R1选自卤素，1至8个碳原子的烷基，任选取代的6至6位的芳基 14个碳原子，1至8个碳原子的全氟烷基，-CN和R'是1至8个碳原子的烷基，Y选自-SO 2 Alk 1，-SO 2 Ar，Alk1是任选不饱和的 任选被至少一个卤素取代的1至8个碳原子的烷基，Ar是任选被至少一个卤素Alk2和Alk3和Alk2'取代的6至14个碳原子的芳基，Alk3'是至多8个碳原子的任选不饱和烷基 任选地被至少一个卤素取代或与“IMAGE”一起形成环，其中A是任选被至多6个碳原子任意取代的不饱和烷基，任选被至少一个卤素取代，R“是1至6个碳原子的烷基 没有被取代或被替换为lea 第一官能团或未被至少一个官能团取代或取代的6至14个碳原子的芳基，R选自氢，1至8个碳原子的烷基和在除虫菊酯中使用的醇残基， pest虫活动。

    3-[2-cyano-2-halo-ethenyl]-2,2-dimethyl-cyclopropanecarboxylates
    3.
    发明授权
    3-[2-cyano-2-halo-ethenyl]-2,2-dimethyl-cyclopropanecarboxylates 失效
    3- [2-氰基-2-卤代乙烯基] -2,2-二甲基 - 环丙烷羧酸酯

    公开(公告)号：US5192801A

    公开(公告)日：1993-03-09

    申请号：US839093

    申请日：1992-02-20

    申请人： Didier Babin ,  Marc Benoit ,  Jean-Pierre Demoute ,  Jean Tessier

    发明人： Didier Babin ,  Marc Benoit ,  Jean-Pierre Demoute ,  Jean Tessier

    IPC分类号： A01N53/00 ,  A01N53/06 ,  A01N55/10 ,  C07C255/31

    CPC分类号： A01N53/00 ,  C07C255/31

    摘要： All stereoisomeric forms and mixtures thereof of a compound of the formula ##STR1## wherein the cyclopropane copula has (1R, cis) or (1R, trans) structure, the geometry of the double bond carried by the 3-carbon atom is (E) or (Z), X is halogen, Z is selected from the group consisting of hydrogen, methyl, --CN and --C.tbd.CH, n is an integer from 1 to 5, m represents the number 5-n, Y is selected from the group consisting of hydrogen, halogen, --CH.sub.2 --CN, --OH, optionally unsaturated alkyl of 1 to 8 carbon atoms unsubstituted or substituted with at least one halogen, --CN, --COOAlk, --COAlk, --(CH.sub.2).sub.m , OAlk, --(CH.sub.2).sub.m, --S--Alk, --(CH.sub.2).sub.m, --N(Alk).sub.2, --Si(Alk).sub.3, --OAr and (CH.sub.2).sub.m, --Ar, m' is 0, 1, 2, 3 or 4, Alk is optionally unsaturated alkyl of 1 to 8 carbon atom unsubstituted or substituted with at least one halogen and Ar is aryl of 6 to 14 carbon atoms and the Ys identical or different may be on any position of the phenyl having pesticidal properties.

    摘要翻译： 式（I）化合物的所有立体异构体形式及其混合物，其中环丙烷共聚物具有（1R，顺式）或（1R，反式）结构，由3-碳原子携带的双键的几何形状为（E ）或（Z）中，X为卤素，Z选自氢，甲基，-CN和-C 3BOND CH，n为1〜5的整数，m为5〜n的数，Y为 由氢，卤素，-CH 2 -CN，-OH，未取代或被至少一个卤素，-CN，-COOAlk，-COAlk， - （CH 2）m取代或被取代的碳原子数1〜8的任选不饱和烷基组成的组， OAlk， - （CH 2）m，-S-Alk， - （CH 2）m，-N（Alk）2，-Si（Alk）3，-OAr和（CH 2）m，-Ar，m' ，2,3或4中，Alk任选是未被取代或被至少一个卤素取代的1至8个碳原子的不饱和烷基，Ar是6至14个碳原子的芳基，并且Y相同或不同可以在苯基的任何位置 具有杀虫性。

    Process for resolving amino acids using substituted lactones
    4.
    发明授权
    Process for resolving amino acids using substituted lactones 失效
    使用取代的内酯拆分氨基酸的方法

    公开(公告)号：US5136050A

    公开(公告)日：1992-08-04

    申请号：US154799

    申请日：1988-02-11

    申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    IPC分类号： C07D207/16

    CPC分类号： C07D207/16

    摘要： Novel substituted lactones of amino acids in all their possible stereoisomeric forms or mixtures thereof of the formula ##STR1## wherein A is a hydrocarbon chain of 1 to 10 chain members containing one or more heteroatoms and one or more unsaturations and the chain members being a mono- or polycyclic system or comprises a system of spiro or endo type and may contain one or more chiral atoms or the lactone copula can present a supplementary chirality due to the asymetric spatial configuration of the molecule make up and R is selected from the group consisting of ##STR2## wherein Z is the organic remainder of an amino acid of the formula ##STR3## Y is derived from a primary, secondary or tertiary alcohol of the formula Y-OH and B is the remainder of a heterocycle amino acid of 3 to 6 carbon atoms of the formula ##STR4## and their preparation and their use for the resolution of amino acids.

    摘要翻译： 新颖的氨基酸的取代的内酯以其所有可能的立体异构体形式或其混合物，其中A为具有1至10个含有一个或多个杂原子和一个或多个不饱和基团的链成员的烃链，链成员为 单环或多环系统或包含螺或内型的系统，并且可以含有一个或多个手性原子，或由于分子组成的不对称空间构型，内酯共聚物可呈现辅助手性，并且R选自 其中Z是下式的氨基酸的有机剩余部分III1衍生自式Y-OH的伯，仲或叔醇，B是 其余的具有式（III）III2的3至6个碳原子的杂环氨基酸及其制备及其在分解氨基酸中的用途。

    Novel pyrethrinoids
    6.
    发明授权
    Novel pyrethrinoids 失效
    新型拟除虫菊酯类

    公开(公告)号：US4925862A

    公开(公告)日：1990-05-15

    申请号：US221948

    申请日：1988-07-20

    申请人： Jacques Demassey ,  Jean-Pierre Demoute ,  Jean Tessier

    发明人： Jacques Demassey ,  Jean-Pierre Demoute ,  Jean Tessier

    IPC分类号： A01N53/04 ,  C07D263/32 ,  C07D263/34 ,  C07D263/38 ,  C07D263/44 ,  C07D263/46 ,  C07D277/10 ,  C07D277/20 ,  C07D277/34 ,  C07D277/36 ,  C07D413/12 ,  C07D417/12

    CPC分类号： C07D413/12 ,  C07D263/32 ,  C07D263/38 ,  C07D263/46 ,  C07D277/10 ,  C07D277/34 ,  C07D277/36 ,  C07D417/12

    摘要： All stereoisomeric forms and mixtures thereof of a compound of the formula ##STR1## wherein X is --O-- or --S--, Y is --C.dbd.O, ##STR2## or --CH.sub.2 --, R.sub.1 is selected from the group consisting of hydrogen, halogen, optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally unsaturated cycloalkyl of 3 to 8 carbon atoms, the latter two being optionally substituted with one or more halogen and aryl of 6 to 14 carbon atoms, R.sub.2 is selected from the group consisting of hydrogen, --CF.sub.3, --NO.sub.2, --CN, halogen, alkoxy of 1 to 8 carbon atoms, aryl of 6 to 14 carbon atoms, an ester, optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally unsaturated cycloalkyl of 3 to 8 carbon atoms the latter two being optionally substituted with one or more halogen, R.sub.3 is selected from the group consisting of hydrogen, alkyl of 1 to 3 carbon atoms, --CN and --C.tbd.CH and A is the residue of an ACOOH pyrethrinoid acid having pesticidal properties.

    摘要翻译： 其中X为-O-或-S-，Y为-C = O， - 或 - 2-的式I化合物的所有立体异构形式及其混合物选自： 氢，卤素，1〜8个碳原子的任选不饱和的烷基和3〜8个碳原子的任选的不饱和环烷基，后两个任选被一个或多个6-14个碳原子的卤素和芳基取代，R2选自 由氢，-CF 3，-NO 2，-CN，卤素，1至8个碳原子的烷氧基，6至14个碳原子的芳基，酯，任选不饱和的1至8个碳原子的烷基和任选的不饱和的环烷基3至 8个碳原子，后两个任选被一个或多个卤素取代，R 3选自氢，1至3个碳原子的烷基，-CN和-C 3 C CH，A是ACOOH拟除虫菊酯酸的残基 具有杀虫性。

    Certain cyclopropanedicarboxylates with an unsaturated side chain having insecticidal activity
    8.
    发明授权
    Certain cyclopropanedicarboxylates with an unsaturated side chain having insecticidal activity 失效

    公开(公告)号：US4883806A

    公开(公告)日：1989-11-28

    申请号：US100284

    申请日：1987-09-23

    申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    IPC分类号： A01N53/00 ,  A23K1/16 ,  A61K31/22 ,  C07D209/48 ,  C07D213/64 ,  C07D213/647 ,  C07D233/72 ,  C07D307/20 ,  C07D307/45 ,  C07D309/12

    CPC分类号： C07D213/647 ,  A01N53/00 ,  A23K20/105 ,  A23K20/111 ,  A23K20/132 ,  A61K31/22 ,  C07D209/48 ,  C07D233/72 ,  C07D307/20 ,  C07D307/42 ,  C07D309/12

    摘要： Novel isomers and mixtures thereof of cyclopropane carboxylic acid derivatives with a 3-unsaturated side chain of the formula ##STR1## wherein A' is selected from the group consisting of (1) alkyl of 1 to 18 carbon atoms, (2) benzyl optionally substituted with at least one member of the group consisting of alkyl of 1 to 4 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkenyloxy of 2 to 6 carbon atoms, alkadienyl of 4 to 8 carbon atoms, methylenedioxy or halogen, ##STR2## wherein R.sub.1 is selected from the group consisting of hydrogen and methyl and R.sub.2 is selected from the group consisting of --CH.sub.2 --C.tbd.CH and monocyclic aryl, ##STR3## wherein a is selected from the group consisting of hydrogen and methyl and R.sub.3 is an aliphatic group of 2 to 6 carbon atoms containing at least one carbon-carbon unsaturation ##STR4## wherein a and and R.sub.3 have the above definition and R.sub.1 ' and R.sub.2 ' are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 6 carbon atoms, aryl of 6 to 10 carbon atoms, cyano and alkoxy carbonyl of 2 to 5 carbon atoms, (6) ##STR5## wherein B is selected from the group consisting of ##STR6## --O-- and --S--, R.sub.4 is selected from the group consisting of hydrogen, --CH.sub.3, --C.tbd.N--CONH.sub.2, --CSNH.sub.2 and --C.tbd.CH, n is an integer form 0, 1 or 2 and R.sub.5 is selected from the group consisting of halogen and --CH.sub.3 ##STR7## wherein R.sub.6, R.sub.7 , R.sub.8 and R.sub.9 are selected from the group consisting of hydrogen, chlorine and methyl and S/I symbolizes an aromatic ring or dihydro or tetrahydro ring, ##STR8## wherein R.sub.10 is selected from the group consisting of hydrogen and --CN, R.sub.12 is selected from the group consisting of --CH.sub.2 -- and --O-- and R.sub.11 is selected from the group consisting of thiazolyl and thiadiazolyl with the bond the bond to ##STR9## being in anyone of the positions, R.sub.12 being bonded to R.sub.11 by the carbon atom included between a sulfur atom and a nitrogen atom, ##STR10## wherein R.sub.13 is selected from the group consisting of hydrogen and --CN ##STR11## wherein R.sub.13 has the above definition and the benzoyl is in the 3- or 4-position; ##STR12## wherein R.sub.14 is; selected from the group consisting of hydrogen, methyl, ethynyl and --CN and R.sub.15 and R.sub.16 are individually selected from the group consisting of hydrogen, bromine and fluorine and ##STR13## wherein R.sub.14 has the above definition, p is 0, 1 or 2, each R.sub.17 is selected from the group consisting of alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, --CF.sub.3 3,4-methylenedioxy, chlorine, bromine and fluorine, B is selected from the group consisting of --O-- and --S-- and R is selected from the group consisting of alkyl of 1 to 18 carbon atoms substituted with one or more, optionally different functional groups, aryl of 6 to 14 carbon atoms optionally substituted with one or more optionally different functional groups, the double bond having Z or E geometry having insecticidal and nematocidal activity as well as plant and animal acaricidal activity and their preparation.

    Herbicidal method of using 5-pyrazolones
    9.
    发明授权
    Herbicidal method of using 5-pyrazolones 失效
    使用5-吡唑啉酮的除草方法

    公开(公告)号：US4808210A

    公开(公告)日：1989-02-28

    申请号：US096364

    申请日：1987-09-11

    申请人： Jean Tessier ,  Pierre Girault

    发明人： Jean Tessier ,  Pierre Girault

    IPC分类号： A01N43/56 ,  A01N43/78 ,  A01N47/38 ,  C07D231/20 ,  C07D231/22 ,  C07D401/04 ,  C07D403/04 ,  C07D417/04

    CPC分类号： C07D401/04 ,  A01N43/56 ,  A01N43/78 ,  A01N47/38 ,  C07D231/20 ,  C07D231/22 ,  C07D403/04 ,  C07D417/04

    摘要： A 5-pyrazolone of the formula ##STR1## wherein R is selected from the group consisting of mono- and polycyclic aromatic of 6 to 14 carbon atoms, heterocyclic optionally substituted with phenyl, ##STR2## and benzyl, all optionally substituted with at least one member of the group consisting of fluorine, chlorine, bromine, --CF.sub.3, optionally unsaturated alkyl of 1 to 8 carbon atoms and the radical OZ in which Z is an optionally unsaturated alkyl of 1 to 8 carbon atoms or an acyl of a carboxylic acid of 1 to 6 carbon atoms, A is selected from the group consisting of halogen, --CF.sub.3 and --CN, B and C are individually selected from the group consisting of hydrogen, halogen, --OH, --OR' and R' is optionally unsaturated alkyl of 1 to 8 carbon atoms, acyl of 1 to 6 carbon atoms, alkyl sulfonyl of 1 to 8 carbon atoms, aryl sulfonyl of 6 to 18 carbon atoms and benzyl optionally substituted with a member of the group consisting of fluorine, chlorine, bromine, --CF.sub.3, optionally unsaturated alkyl of 1 to 8 carbon atoms, optionally unsaturated alkyl and haloalkyl of 1 to 8 carbon atoms interrupted with at least one heteroatom, with the proviso that B and C can not both be fluorine or --OH having herbicidial activity.

    摘要翻译： 下式的5-吡唑啉酮其中R选自6至14个碳原子的单环和多环芳族化合物，任选被苯基取代的杂环基，和任选地被至少取代的苯甲基 由氟，氯，溴，-CF 3，1-8个碳原子的任选不饱和烷基和Z为任选不饱和的1至8个碳原子的烷基的基团OZ或羧酸酰基组成的组中的一个成员 1至6个碳原子，A选自卤素，-CF 3和-CN，B和C分别选自氢，卤素，-OH，-OR'，R'是任选不饱和的 1至8个碳原子的烷基，1至6个碳原子的酰基，1至8个碳原子的烷基磺酰基，6至18个碳原子的芳基磺酰基和任选被氟，氯，溴成员组成的基团取代的苄基 ，-CF 3，1〜8的任选的不饱和烷基 碳原子，任选不饱和的烷基和1至8个碳原子的卤代烷基与至少一个杂原子间隔，条件是B和C不能都是具有除草活性的氟或-OH。

    Novel pyrrole derivatives
    10.
    发明授权
    Novel pyrrole derivatives 失效
    新型吡咯衍生物

    公开(公告)号：US4798901A

    公开(公告)日：1989-01-17

    申请号：US127922

    申请日：1987-12-02

    申请人： Jean Tessier ,  Jean-Pierre Demoute ,  Laurent Taliani

    发明人： Jean Tessier ,  Jean-Pierre Demoute ,  Laurent Taliani

    IPC分类号： A01N43/36 ,  A01N53/00 ,  A01N53/04 ,  A01N53/06 ,  A23K1/16 ,  C07D207/32 ,  C07D207/333 ,  C07D207/337 ,  C07D207/34 ,  C07D207/42 ,  C07D207/325

    CPC分类号： C07D207/333 ,  A01N43/36 ,  A01N53/00 ,  A23K20/132 ,  C07D207/337 ,  C07D207/34 ,  C07D207/42

    摘要： Novel pyrrole derivatives of the formula ##STR1## wherein one of R.sub.2 and R.sub.3 is ##STR2## and the other of R.sub.2 and R.sub.3 as well as R.sub.4 and R.sub.5 are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 18 carbon atoms, aryl of 6 to 14 carbon atoms, aralkyl of 7 to 18 carbon atoms, --CN, --CF.sub.3, --NO.sub.2, --COOAlk and Alk is alkyl of 1 to 8 carbon atoms, alkoxy of 1 to 8 carbon atoms, ##STR3## n is 0, 1 or 2, R', R.sub.1 ' and R.sub.2 ' are alkyl of 1 to 8 carbon atoms and R.sub.4 and R.sub.5 taken together with the carbon atoms to which they are attached may form an optionally further unsaturated carbon homocycle of up to 8 carbon atoms, Z is selected from the group consisting of hydrogen, --CN, --C.tbd.CH, --CF.sub.3 and alkyl of 1 to 3 carbon atoms, A is the residue of a pyrethrinoid acid, R.sub.1 is selected from the group consisting of ##STR4## X', X, Y, Y' and Y" are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 8 carbon atoms and aryl of 6 to 14 carbon atoms, the dotted line indicating an optional double bond, r' is selected from the group consisting of hydrogen, alkyl of 1 to 18 carbon atoms, aryl of 6 to 14 carbon atoms, aralkyl of 7 to 18 carbon atoms, --CF.sub.3, --COOAlk and alkoxy of 1 to 8 carbon atoms and Alk has the above definition, R" and R"' are individually selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms, aryl of 6 to 14 carbon atoms, aralkyl of 6 to 18 carbon atoms, --CF.sub.3, --COOAlk' and alkoxy of 1 to 8 carbon atoms and Alk' is alkyl of 1 to 8 carbon atoms having pesticidal properties and novel intermediates.

    摘要翻译： 式（I）的新颖的吡咯衍生物，其中R 2和R 3之一是R 1和R 2之一，以及R 4和R 5中的另一个分别选自氢，卤素，1至18的烷基 碳原子数为6〜14的芳基，碳原子数为7〜18的芳烷基，-CN，-CF 3，-NO 2，-COOAlk，Alk为碳原子数为1〜8的烷基，碳原子数为1〜8的烷氧基， 图像> n是0,1或2，R'，R 1'和R 2'是1至8个碳原子的烷基，R 4和R 5与它们所连接的碳原子一起可以形成任选的另外的不饱和碳均质碳 Z最多为8个碳原子，Z选自氢，-CN，-C3BCH，-CF3和1至3个碳原子的烷基，A是除虫烯酸的残基，R1选自 由X，Y，Y'分别选自氢，卤素，碳原子数1〜8的烷基，碳原子数为6〜14的芳基组成的组合 n个原子，表示任选的双键的虚线，r'选自氢，1至18个碳原子的烷基，6至14个碳原子的芳基，7至18个碳原子的芳烷基，-CF 3， -COOAlk和1-8个碳原子的烷氧基，Alk具有上述定义，R“和R”'分别选自氢，1至8个碳原子的烷基，6至14个碳原子的芳基 6〜18个碳原子的芳烷基，-CF 3，-COOAlk'和1〜8个碳原子的烷氧基，Alk'是具有杀虫性的1〜8个碳原子的烷基和新的中间体。