公开(公告)号：US10011777B2

公开(公告)日：2018-07-03

申请号：US14054288

申请日：2013-10-15

Applicant: Virginia M. Roberts ,  Michel Daage ,  Kun Wang

Inventor： Virginia M. Roberts ,  Michel Daage ,  Kun Wang

IPC: C07C1/32 ,  C10G3/00 ,  B01J23/02 ,  B01J23/04 ,  B01J23/10 ,  B01J29/70 ,  B01J29/74 ,  B01J29/76 ,  C10G45/02 ,  C10G45/04 ,  C10G45/08 ,  C10G45/10 ,  C10G45/12

CPC classification number: C10G3/50 ,  B01J23/02 ,  B01J23/04 ,  B01J23/10 ,  B01J29/703 ,  B01J29/7046 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/7661 ,  B01J29/7692 ,  C10G3/44 ,  C10G3/45 ,  C10G45/02 ,  C10G45/04 ,  C10G45/08 ,  C10G45/10 ,  C10G45/12 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2300/302 ,  C10G2300/305 ,  C10G2300/307 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P30/20

Abstract: Systems and methods are provided for processing a feed derived from a biomass source that contains nitrogen in the form of fatty amides, e.g., derived from hydrothermal processing of a biomass source feed, while reducing/minimizing the amount of heteroatom removal performed during subsequent/concurrent hydroprocessing. Optionally, the feed can also contain free fatty acids. This is accomplished in part by first exposing the feed to a catalyst comprising a rare earth oxide, alkali oxide, and/or alkaline earth oxide, which can remove the nitrogen heteroatoms from the compounds within the feed or can convert the nitrogen to a form readily removed in subsequent hydroprocessing. The catalyst may also suitable for catalyzing coupling (such as condensation) or conversion reactions of amides, carboxylic acids, carboxylic acid derivatives, and/or other molecules in the feed suitable for participating in the coupling reaction.

公开(公告)号：US20150152343A1

公开(公告)日：2015-06-04

申请号：US14541393

申请日：2014-11-14

Applicant: Rohit VIJAY ,  Ajit Bhaskar DANDEKAR ,  Michel DAAGE ,  Christopher G. OLIVERI ,  Christine Nicole ELIA ,  Darryl Donald LACY ,  Scott J. WEIGEL ,  Bradley R. FINGLAND

Inventor： Rohit VIJAY ,  Ajit Bhaskar DANDEKAR ,  Michel DAAGE ,  Christopher G. OLIVERI ,  Christine Nicole ELIA ,  Darryl Donald LACY ,  Scott J. WEIGEL ,  Bradley R. FINGLAND

IPC: C10G67/14 ,  C10G69/08 ,  C10G67/02

CPC classification number: C10G67/14 ,  C10G65/12 ,  C10G67/02 ,  C10G69/08 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4025 ,  C10G2400/04 ,  C10G2400/10

Abstract: Methods are provided for improving the yield of distillate products from hydroprocessing of gas oil feedstocks, such as vacuum gas oils. It has been unexpectedly found that stripping of gases or fractionation to separate out a distillate fraction during initial hydrotreatment of a feed can provide a substantial increase in distillate yield at a desired amount of feedstock conversion. The improvement in yield of distillate products can allow a desired level of conversion to be performed on a feedstock for generating lubricating base oil products while reducing or minimizing the amount of naphtha (or lower) boiling range products. Alternatively, the improvement in yield of distillate products can correspond to an improved yield during a single pass through a reaction system, so that distillate yield is increased even though a lubricant boiling range product is not generated.

Abstract translation: 提供了用于提高瓦斯油原料如真空瓦斯油加氢处理的馏出物产率的方法。 已经意外地发现，在进料的初始加氢处理期间汽提汽提或分馏以分离出馏出物馏分可以在所需量的原料转化率下提供馏出物产率的显着增加。 馏出物产品的产率的提高可以使得在用于产生润滑基础油产品的原料上进行所需水平的转化，同时减少或最小化石脑油（或更低）沸点产物的量。 或者，馏出物产物的产率的提高可以对应于在单次通过反应体系期间提高的产率，使得即使不产生润滑剂沸程产物，馏出物产率也增加。

公开(公告)号：US20140275669A1

公开(公告)日：2014-09-18

申请号：US14196087

申请日：2014-03-04

Applicant: Michel Daage ,  Stephen H. Brown ,  Eugenio Sanchez ,  Nazeer A. Bhore ,  Robert Charles William Welch ,  Gretchen L. Holtzer ,  Arthur Thomas Andrews

Inventor： Michel Daage ,  Stephen H. Brown ,  Eugenio Sanchez ,  Nazeer A. Bhore ,  Robert Charles William Welch ,  Gretchen L. Holtzer ,  Arthur Thomas Andrews

IPC: C07C2/12 ,  C10L1/04 ,  C07C5/05

CPC classification number: C07C2/12 ,  B01J29/40 ,  B01J29/703 ,  B01J29/7042 ,  B01J29/7046 ,  C07C5/05 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  C07C2529/85 ,  C10G50/00 ,  C10G69/126 ,  C10G2300/1092 ,  C10G2300/301 ,  C10G2400/10 ,  C10L1/04 ,  C07C11/02

Abstract: Methods are provided for oligomerizing a dilute ethylene feed to form oligomers suitable for use as fuels and/or lubricant base oils. The fuels and/or lubricant base oils are formed by oligomerization of impure dilute ethylene with a zeolitic catalyst, where the zeolitic catalyst is resistant to the presence of poisons such as sulfur and nitrogen in the ethylene feed. The oligomers can also be formed in presence of diluents such as light paraffins.

Abstract translation: 提供了用于使稀乙烯进料低聚以形成适合用作燃料和/或润滑剂基础油的低聚物的方法。 燃料和/或润滑剂基础油通过使用沸石催化剂使不纯的乙烯低聚来形成，其中沸石催化剂对乙烯进料中的毒素如硫和氮的存在具有抗性。 低聚物也可以在稀释剂如轻链烷烃的存在下形成。

公开(公告)号：US08609912B2

公开(公告)日：2013-12-17

申请号：US13365328

申请日：2012-02-03

Applicant: Patrick L. Hanks ,  Michel Daage

Inventor： Patrick L. Hanks ,  Michel Daage

IPC: C07C5/02

CPC classification number: C10G45/72 ,  B01J8/0214 ,  B01J8/0257 ,  B01J8/0453 ,  B01J8/0465 ,  B01J2208/00309 ,  B01J2208/00938 ,  B01J2208/025 ,  C10G3/42 ,  C10G3/50 ,  C10G47/36 ,  C10G49/002 ,  C10G65/02 ,  C10G65/14 ,  C10G2300/1011 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/4081 ,  Y02P30/20

Abstract: Separated volumes can be created in a reactor using interior dividing wall or interior conduit structures. Feedstocks can be hydroprocessed in the separated volumes to allow multiple types of hydroprocessing conditions and/or feeds to be processed in a single reactor. The feedstocks can remain separate for the entire volume of the reactor, or the dividing barrier can end at some intermediate point in the reactor.

Abstract translation: 可以在使用内部分隔壁或内部管道结构的反应器中产生分离体积。 原料可以在分离的体积中加氢处理，以允许多种类型的加氢处理条件和/或进料在单个反应器中加工。 原料可以在反应器的整个体积中保持分开，或者分隔壁可以在反应器中的某个中间点处结束。

公开(公告)号：US20130281753A1

公开(公告)日：2013-10-24

申请号：US13652669

申请日：2012-10-16

Applicant: STEPHEN J. McCARTHY ,  TILMAN W. BEUTEL ,  MICHEL DAAGE ,  KARLTON J. HICKEY ,  BEAU WALDRUP

Inventor： STEPHEN J. McCARTHY ,  TILMAN W. BEUTEL ,  MICHEL DAAGE ,  KARLTON J. HICKEY ,  BEAU WALDRUP

IPC: B01J29/40 ,  C07C2/86

CPC classification number: B01J29/40 ,  B01J21/04 ,  B01J29/00 ,  B01J29/83 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/1004 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/06 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/42 ,  B82Y30/00 ,  B82Y40/00 ,  C01B39/54 ,  C07C1/20 ,  C07C1/22 ,  C07C1/24 ,  C07C2/864 ,  C07C41/09 ,  C10G3/49 ,  C10G2400/02 ,  C10G2400/04 ,  Y02P20/125 ,  Y02P30/20 ,  C07C43/043

Abstract: An unbound catalyst composition comprises a zeolite and phosphorus in an amount between about 0.01 wt % and about 3 wt % of the total catalyst composition. The catalyst composition, as calcined at ˜1000° F. (˜538° C.) for at least ˜3 hours, can exhibit (i) 2,2-dimethylbutane diffusivity >1.5×10−2 sec−1 when measured at ˜120° C. and ˜60 torr (˜8 kPa), (ii) coke deactivation rate constant 0.2 ml/g; (b) microporous surface area at least 375 m2/g; and (c) coke deactivation rate constant

Abstract translation: 未结合的催化剂组合物包含沸石和磷，其量为总催化剂组合物的约0.01重量％至约3重量％。 在约1000°F（〜538℃）下煅烧至少约3小时的催化剂组合物可以表现出（i）在〜（∞）时测量的2,2-二甲基丁烷扩散系数> 1.5×10 -2 sec -1， 120℃和〜60托（〜8kPa），（ii）焦炭钝化速率常数<〜0.15，和（iii）至少10的α值，并进一步显示以下至少一种：（a）中孔隙度> 0.2ml /G; （b）微孔表面积至少为375平方米/克; 和（c）在约1000°F（〜538℃）〜〜100％蒸汽蒸煮〜96小时后，焦化钝化速率常数<0.05。

公开(公告)号：US20130158137A1

公开(公告)日：2013-06-20

申请号：US13326017

申请日：2011-12-14

Applicant: Paul D. OLDENBURG ,  Michel DAAGE ,  Virginia M. ROBERTS ,  Paul J. BERLOWITZ ,  David C. LONG ,  James R. BIELENBERG

Inventor： Paul D. OLDENBURG ,  Michel DAAGE ,  Virginia M. ROBERTS ,  Paul J. BERLOWITZ ,  David C. LONG ,  James R. BIELENBERG

IPC: C07C27/00 ,  C11B1/00

CPC classification number: C07C29/1518 ,  C10G2/32 ,  C10J2300/0916 ,  C10J2300/1659 ,  C10J2300/1665 ,  C10J2300/1681 ,  C10K1/005 ,  C10K3/04 ,  C11B1/04 ,  C11B1/10 ,  C11C3/003 ,  C12P7/6463 ,  Y02E50/18 ,  Y02E50/343 ,  Y02P20/125 ,  Y02P20/145 ,  Y02P20/582 ,  C07C31/04

Abstract: Systems and methods are provided for enhancing the integration of processes for recovering products from algae-derived biomass. The enhanced process integration allows for increased use of input streams and other reagents that are derived from renewable sources. This increases the overall renewable character of the products extracted from the algae-derived biomass. The process integration can include exchange of input streams or energy between an algae processing system and a system for processing non-algal biomass. One example of improving process integration is using oxygenates that are generated in a renewable manner as a reagent for enhancing the algae processing system.

Abstract translation: 提供了系统和方法，用于增强从藻类衍生的生物质中回收产物的方法的整合。 增强的过程集成允许更多地使用从可再生来源获得的输入流和其他试剂。 这增加了从藻类来源的生物质提取的产品的整体可再生性。 过程集成可以包括在藻类处理系统和用于处理非藻类生物质的系统之间的输入流或能量的交换。 改进过程整合的一个实例是使用以可再生方式产生的含氧化合物作为增强藻类处理系统的试剂。

公开(公告)号：US08431756B2

公开(公告)日：2013-04-30

申请号：US13302145

申请日：2011-11-22

Applicant: Virginia M. Roberts ,  Michel Daage ,  William J. Novak

Inventor： Virginia M. Roberts ,  Michel Daage ,  William J. Novak

IPC: C07C1/20

CPC classification number: C10G3/42 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/49 ,  C10G3/50 ,  C10G45/58 ,  C10G2300/1014 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/304 ,  C10G2300/4018 ,  C10L1/08 ,  Y02P30/20

Abstract: This invention relates to a method for processing oxygenated hydrocarbons to form a hydroisomerized and/or dewaxed hydrocarbon product having a reduced oxygen content, an increased iso-paraffin content, a low n-paraffin content, and good cold flow properties. Advantageously, the method can utilize a zeolitic base catalyst, optionally but preferably containing at least one activated metal component, and a hydrothermally-stable binder such as titania.

Abstract translation: 本发明涉及一种处理含氧烃以形成具有降低的氧含量，增加的异链烷烃含量，低正链烷烃含量和良好的冷流特性的加氢异构化和/或脱蜡烃产物的方法。 有利地，该方法可以利用沸石碱催化剂，任选但优选含有至少一种活化的金属组分和水热稳定的粘合剂如二氧化钛。

公开(公告)号：US20120000829A1

公开(公告)日：2012-01-05

申请号：US13172196

申请日：2011-06-29

Applicant: Richard Charles Dougherty ,  Michel Daage

Inventor： Richard Charles Dougherty ,  Michel Daage

IPC: C10G45/00

CPC classification number: C10G45/58 ,  C10G21/003 ,  C10G21/14 ,  C10G21/16 ,  C10G21/27 ,  C10G45/02 ,  C10G45/04 ,  C10G45/64 ,  C10G65/04 ,  C10G67/04 ,  C10G67/0418 ,  C10G69/02 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/1096 ,  C10G2300/201 ,  C10G2300/202 ,  C10G2300/302 ,  C10G2300/4081 ,  C10G2300/44 ,  C10G2400/10

Abstract: The preparation of Group II and Group III lube base oils wherein liquid-continuous hydrotreating is used to treat a lube oil raffinate. The hydrotreated lube oil raffinate is then sent to a dewaxing stage that can be either a solvent or catalytic dewaxing stage.

Abstract translation: 组合II和III组润滑油基础油的制备，其中液体连续加氢处理用于处理润滑油萃余液。 然后将加氢处理的润滑油萃余液送至可以是溶剂或催化脱蜡阶段的脱蜡阶段。

公开(公告)号：US5928498A

公开(公告)日：1999-07-27

申请号：US917070

申请日：1997-08-22

Applicant: Gary B. McVicker ,  James J. Schorfheide ,  William C. Baird, Jr. ,  Michele S. Touvelle ,  Michel Daage ,  Darryl P. Klein ,  Edward S. Ellis ,  David E. W. Vaughan ,  Jingguang G. Chen ,  Sylvain S. Hantzer

Inventor： Gary B. McVicker ,  James J. Schorfheide ,  William C. Baird, Jr. ,  Michele S. Touvelle ,  Michel Daage ,  Darryl P. Klein ,  Edward S. Ellis ,  David E. W. Vaughan ,  Jingguang G. Chen ,  Sylvain S. Hantzer

IPC: C10G25/00 ,  C10G45/10 ,  C10G45/62 ,  C10G65/04 ,  C10G65/08 ,  C10G45/00

CPC classification number: C10G25/003 ,  C10G45/10 ,  C10G45/62 ,  C10G65/04 ,  C10G65/043 ,  C10G65/08

Abstract: A process for the hydrodesulfurization (HDS) of the multiple condensed ring heterocyclic organosulfur compounds and the ring opening of ring compounds present in petroleum and petrochemical streams. The process is conducted in the presence of hydrogen, one or more noble metal catalysts, and a hydrogen sulfide sorbent material.

公开(公告)号：US5474670A

公开(公告)日：1995-12-12

申请号：US245181

申请日：1994-05-17

Applicant: Michel Daage ,  Teh C. Ho ,  Kenneth L. Riley

Inventor： Michel Daage ,  Teh C. Ho ,  Kenneth L. Riley

IPC: B01J27/045 ,  B01J27/047 ,  C10G45/08 ,  C10G45/10 ,  C10G65/04 ,  C10G45/04

CPC classification number: C10G65/04 ,  B01J27/045

Abstract: The present invention relates to a method of removing sulfur from a hydrotreating process stream comprising contacting a sulfur containing feedstock with a stacked bed catalyst system comprising a first catalyst bed comprising hydrodesulfurization catalysts followed by a second catalyst bed comprising ruthenium sulfide having a surface area of at least about 30 m.sup.2 /g and wherein said hydrodesulfurization process is conducted at a temperature of about 150.degree. C. to about 400.degree. C. and a pressure of about 50 psig (344.74 kPa) to about 2500 psig (17236.89 kPa).

Abstract translation: 本发明涉及一种从加氢处理工艺流中除去硫的方法，包括使含硫原料与堆叠床催化剂体系接触，所述堆叠床催化剂体系包含第一催化剂床，所述第一催化剂床包含加氢脱硫催化剂，随后是第二催化剂床，所述第二催化剂床包含表面积为 至少约30m 2 / g，并且其中所述加氢脱硫方法在约150℃至约400℃的温度和约50psig（344.74kPa）至约2500psig（17236.89kPa）的压力下进行。