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公开(公告)号：US08399080B2
公开(公告)日：2013-03-19
申请号：US12202655
申请日：2008-09-02
申请人： Gianfranco Chicarella , Nao Yokota , Tracy A. Paolilli , John J. Fitch , Todd R. Sarnstrom , Dean Borchardt , Paul A. Ansolabehere , Steven Sargeant
发明人： Gianfranco Chicarella , Nao Yokota , Tracy A. Paolilli , John J. Fitch , Todd R. Sarnstrom , Dean Borchardt , Paul A. Ansolabehere , Steven Sargeant
CPC分类号： C23C14/20 , A63H27/10 , A63H2027/1025 , B32B27/08 , B32B27/32 , B32B27/36 , B32B2255/10 , B32B2255/205 , B32B2255/26 , B32B2255/28 , B32B2307/31 , B32B2307/40 , B32B2307/518 , B32B2307/5825 , B32B2307/702 , B32B2307/704 , B32B2307/7244 , C23C14/02 , Y10T428/13 , Y10T428/1303 , Y10T428/131 , Y10T428/1321 , Y10T428/1338 , Y10T428/1341 , Y10T428/1352 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31786
摘要： A long life balloon formed from a lamination. The lamination includes a polyester film with a total thickness of 4 μm to 12 μm. The polyester film includes a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The lamination also includes a sealant layer and a gas barrier layer on an opposite side of the polyester film from the sealant layer. The oxygen transmission rate of the balloon is less than 0.1 cc/100 sqin/day, a bonding strength of the gas barrier layer to the surface of the polyester film is more than 300 g/in at dry conditions, a sealing strength of the balloon is more than 3.5 kg/in, and a floating time of the balloon is more than 20 days.
摘要翻译： 由层压形成的长寿命气球。 层压包括总厚度为4μm至12μm的聚酯膜。 聚酯膜包括双轴取向聚酯芯层和至少一个非晶共聚酯表皮层。 层压体还包括在密封剂层与聚酯膜的相对侧上的密封层和阻气层。 气球的氧气透过率小于0.1cc / 100平方/天，在干燥条件下阻气层与聚酯薄膜表面的接合强度大于300g / l，气囊的密封强度 超过3.5公斤/英寸，气球的浮动时间超过20天。
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公开(公告)号：US08323759B2
公开(公告)日：2012-12-04
申请号：US13196554
申请日：2011-08-02
申请人： Gianfranco Chicarella , Nao Yokota , Tracy A. Paolilli , John J. Fitch , Todd Richard Sarnstrom , Dean Borchardt , Paul Andrew Ansolabehere , Steven Sargeant
发明人： Gianfranco Chicarella , Nao Yokota , Tracy A. Paolilli , John J. Fitch , Todd Richard Sarnstrom , Dean Borchardt , Paul Andrew Ansolabehere , Steven Sargeant
CPC分类号： C23C14/20 , A63H27/10 , A63H2027/1025 , B32B27/08 , B32B27/32 , B32B27/36 , B32B2255/10 , B32B2255/205 , B32B2255/26 , B32B2255/28 , B32B2307/31 , B32B2307/40 , B32B2307/518 , B32B2307/5825 , B32B2307/702 , B32B2307/704 , B32B2307/7244 , C23C14/02 , Y10T428/13 , Y10T428/1303 , Y10T428/131 , Y10T428/1321 , Y10T428/1338 , Y10T428/1341 , Y10T428/1352 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31786
摘要： A long life balloon formed from a lamination. The lamination includes a polyester film with a total thickness of 4 μm to 12 μm. The polyester film includes a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The lamination also includes a sealant layer and a gas barrier layer on an opposite side of the polyester film from the sealant layer. The oxygen transmission rate of the balloon is less than 0.1 cc/100 sqin/day, a bonding strength of the gas barrier layer to the surface of the polyester film is more than 300 g/in at dry conditions, a sealing strength of the balloon is more than 3.5 kg/in, and a floating time of the balloon is more than 20 days.
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3.发明申请BIAXIALLY ORIENTED POLYLACTIC ACID FILM WITH REDUCED NOISE LEVEL AND IMPROVED MOISTURE BARRIER 有权具有减少噪声水平和改进的水分障碍物的双向聚对苯二甲酸乙二醇酯公开(公告)号：US20110244186A1
公开(公告)日：2011-10-06
申请号：US13077302
申请日：2011-03-31
申请人： Shichen Dou , Mark S. Lee , Claudio M. Paulino , Nao Yokota , Keunsuk P. Chang
发明人： Shichen Dou , Mark S. Lee , Claudio M. Paulino , Nao Yokota , Keunsuk P. Chang
CPC分类号： B29C47/0021 , B29C47/043 , B29C47/065 , B29C47/067 , B29K2021/00 , B29K2105/256 , B29K2995/006 , B29K2995/0067 , B29L2009/00 , B32B27/08 , B32B27/302 , B32B27/36 , B32B2255/205 , B32B2274/00 , B32B2307/31 , B32B2307/518 , B32B2307/54 , B32B2307/7163 , B32B2439/70 , Y10T428/24479 , Y10T428/265 , Y10T428/2826 , Y10T428/31681
摘要： Described are metallized biaxially oriented polylactic acid (BOPLA) films with a novel formulation that exhibits a softer feel and quieter sound, without jeopardizing film making stability. It has been found that when these films are metallized, moisture barrier properties are surprisingly improved compared to conventional metallized BOPLA films. Specifically, the moisture barrier of the films may be 2.0 g/m2/day or less at 38° C. and 90% relative humidity. The films can be used, for example, in packaging applications. The films have characteristics that are beneficial to converting processes, are economical, and maintain bio-compostability similar to typical BOPLA films.
摘要翻译： 描述了具有新颖配方的金属化双轴取向聚乳酸（BOPLA）膜，其表现出更柔软的手感和更安静的声音，而不损害成膜稳定性。 已经发现，当这些膜被金属化时，与常规的金属化BOPLA膜相比，防潮性能惊人地得到改善。 具体而言，在38℃，90％相对湿度下，膜的防潮性可以为2.0g / m 2 /天以下。 这些膜可以用于例如包装应用中。 这些膜具有有利于转化过程的特性，是经济的，并且保持与典型的BOPLA膜类似的生物可堆肥性。
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4.发明申请BIAXIALLY ORIENTED METALLIZED POLYLACTIC ACID FILM WITH HIGH METAL ADHESION AND HIGH BARRIER PROPERTIES 有权具有高金属粘合性和高阻隔性的双向方向金属化聚乙烯膜公开(公告)号：US20100247886A1
公开(公告)日：2010-09-30
申请号：US12731925
申请日：2010-03-25
申请人： Mark S. Lee , Claudio M. Paulino , Takeshi Mizumura , Keunsuk P. Chang , Nao Yokota , Jun'ichi Masuda
发明人： Mark S. Lee , Claudio M. Paulino , Takeshi Mizumura , Keunsuk P. Chang , Nao Yokota , Jun'ichi Masuda
CPC分类号： B32B27/36 , B32B27/08 , B32B27/18 , B32B2250/244 , B32B2255/10 , B32B2255/205 , B32B2264/104 , B32B2307/308 , B32B2307/31 , B32B2307/518 , B32B2307/538 , B32B2307/558 , B32B2307/704 , B32B2307/7246 , B32B2307/75 , B32B2439/70 , B32B2451/00 , B32B2519/00 , B32B2553/00 , Y10T428/24479 , Y10T428/24975 , Y10T428/25 , Y10T428/256 , Y10T428/265 , Y10T428/2813 , Y10T428/2817 , Y10T428/2826 , Y10T428/31681 , Y10T428/31685 , Y10T428/31786
摘要： Metallized multi-layer biaxially oriented polylactic acid base polymer (BOPLA) films that exhibits improved barrier properties and metal adhesion. The films include a core layer including crystalline polylactic acid base polymer, a first skin layer consisting essentially of amorphous polylactic acid base polymer, and a metal layer on the first skin layer. The films may include a second skin layer consisting essentially of amorphous polylactic acid base polymer.
摘要翻译： 金属化的多层双轴取向聚乳酸基聚合物（BOPLA）膜，其表现出改善的阻隔性能和金属粘附性。 膜包括包含结晶聚乳酸基聚合物的核心层，基本上由无定形聚乳酸基聚合物组成的第一表皮层和在第一表皮层上的金属层。 膜可以包括基本上由无定形聚乳酸基聚合物组成的第二表皮层。
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公开(公告)号：US20080038539A1
公开(公告)日：2008-02-14
申请号：US11835939
申请日：2007-08-08
申请人： Nao Yokota , Steven Sargeant , Arron Carroll , Hiroshi Furuya , Thomas Lemanski
发明人： Nao Yokota , Steven Sargeant , Arron Carroll , Hiroshi Furuya , Thomas Lemanski
CPC分类号： B32B33/00 , B29C48/08 , B29C48/18 , B29K2029/04 , B29K2067/00 , B29K2105/16 , B29K2995/0026 , B32B27/20 , B32B27/36 , B32B37/153 , B32B2305/30 , B32B2307/40 , B32B2307/412 , B32B2367/00 , Y10T428/25
摘要： A thermoplastic polyester film including a virtually particle free polyethyleneterephthalate core layer and a skin layer comprising inorganic and organic fillers disposed on the core layer. The inorganic fillers may include aluminum oxide particles, silicon dioxide, zirconium oxide, titanium dioxide, tin oxide, calcium carbonate, barium sulfate, calcium phosphate, zeolite, hydroxy apatite, aluminum silicate and mixtures thereof. The inorganic fillers may have a particle size of from 0.01 μm to 0.60 μm. The organic filler particles may have an average particle size of less than or equal to 1 μm and may be present in an amount of less than 0.1% by weight, based on the weight of the polyethyleneterephthalate. The skin layer may have a thickness of less than 7 μm.
摘要翻译： 一种热塑性聚酯薄膜，其包括实际上无颗粒的聚对苯二甲酸乙二醇酯芯层和包含设置在芯层上的无机和有机填料的表皮层。 无机填料可包括氧化铝颗粒，二氧化硅，氧化锆，二氧化钛，氧化锡，碳酸钙，硫酸钡，磷酸钙，沸石，羟基磷灰石，硅酸铝及其混合物。 无机填料的粒径可以为0.01μm至0.60μm。 有机填料颗粒可以具有小于或等于1μm的平均粒度，并且可以基于聚对苯二甲酸乙二醇酯的重量小于0.1重量％的量存在。 表层可以具有小于7μm的厚度。
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6.发明授权Biaxially oriented metallized polylactic acid film with high metal adhesion and high barrier properties 有权双向拉伸金属化聚乳酸薄膜，具有高金属粘附性和高阻隔性能公开(公告)号：US08652626B2
公开(公告)日：2014-02-18
申请号：US12731925
申请日：2010-03-25
申请人： Mark S. Lee , Claudio M. Paulino , Takeshi Mizumura , Keunsuk P. Chang , Nao Yokota , Jun'ichi Masuda
发明人： Mark S. Lee , Claudio M. Paulino , Takeshi Mizumura , Keunsuk P. Chang , Nao Yokota , Jun'ichi Masuda
CPC分类号： B32B27/36 , B32B27/08 , B32B27/18 , B32B2250/244 , B32B2255/10 , B32B2255/205 , B32B2264/104 , B32B2307/308 , B32B2307/31 , B32B2307/518 , B32B2307/538 , B32B2307/558 , B32B2307/704 , B32B2307/7246 , B32B2307/75 , B32B2439/70 , B32B2451/00 , B32B2519/00 , B32B2553/00 , Y10T428/24479 , Y10T428/24975 , Y10T428/25 , Y10T428/256 , Y10T428/265 , Y10T428/2813 , Y10T428/2817 , Y10T428/2826 , Y10T428/31681 , Y10T428/31685 , Y10T428/31786
摘要： Metallized multi-layer biaxially oriented polylactic acid base polymer (BOPLA) films that exhibits improved barrier properties and metal adhesion. The films include a core layer including crystalline polylactic acid base polymer, a first skin layer consisting essentially of amorphous polylactic acid base polymer, and a metal layer on the first skin layer. The films may include a second skin layer consisting essentially of amorphous polylactic acid base polymer.
摘要翻译： 金属化的多层双轴取向聚乳酸基聚合物（BOPLA）膜，其表现出改善的阻隔性能和金属粘附性。 膜包括包含结晶聚乳酸基聚合物的核心层，基本上由无定形聚乳酸基聚合物组成的第一表皮层和在第一表皮层上的金属层。 膜可以包括基本上由无定形聚乳酸基聚合物组成的第二表皮层。
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公开(公告)号：US20130122280A1
公开(公告)日：2013-05-16
申请号：US13673564
申请日：2012-11-09
申请人： Nao YOKOTA , Mark S. LEE , Claudio M. PAULINO
发明人： Nao YOKOTA , Mark S. LEE , Claudio M. PAULINO
IPC分类号： C08J9/00
CPC分类号： C08J9/0038 , B29C47/0021 , B29C47/0057 , B29C47/06 , B29C55/12 , B32B3/26 , B32B15/09 , B32B15/20 , B32B27/08 , B32B27/18 , B32B27/205 , B32B27/36 , B32B37/153 , B32B38/0032 , B32B2037/243 , B32B2037/246 , B32B2038/0028 , B32B2255/10 , B32B2255/205 , B32B2305/02 , B32B2307/41 , B32B2307/518 , B32B2307/54 , B32B2307/7163 , B32B2307/72 , B32B2307/7244 , B32B2307/7246 , B32B2311/24 , B32B2367/00 , C08J5/18 , C08J2367/04 , C08K5/49 , C08K5/51 , C08K5/5317 , C08L23/0869 , C08L67/04 , C09J167/04 , Y10T428/1338 , Y10T428/1341 , Y10T428/1355 , Y10T428/1379 , Y10T428/249953 , Y10T428/249987 , Y10T428/249988 , Y10T428/249991 , Y10T428/31681 , Y10T428/31786
摘要： A biaxially oriented laminate film including a core layer including a blend of crystalline polylactic acid polymer and a metal salt phosphorus-containing compound nucleating agent which is biaxially oriented at low transverse direction orientation temperatures to impart a degree of cavitation around the metal salt phosphorus-containing metal such that a white opaque cavitated appearance and a lower film density and improved mechanical properties are obtained. The laminate film could further have additional layers such as a heat sealable layer disposed on one side of said core layer including an amorphous polylactic acid resin and/or a polylactic acid resin-containing layer disposed on the side of the core layer opposite the heat sealable layer, a metal layer, or combinations thereof.
摘要翻译： 一种双轴取向层压膜，其包括芯层，其包含结晶性聚乳酸聚合物和金属盐含磷化合物成核剂的混合物，所述核心层在低横向取向温度下双轴取向，以在金属盐含磷的周围赋予空化程度 金属，从而获得白色不透明的气泡外观和较低的膜密度和改进的机械性能。 层压膜还可以具有另外的层，例如设置在所述芯层的一侧上的可热封层，包括无定形聚乳酸树脂和/或设置在芯层的与可热封的相反侧的聚乳酸树脂含有层 层，金属层或其组合。
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公开(公告)号：US08236399B2
公开(公告)日：2012-08-07
申请号：US13196495
申请日：2011-08-02
申请人： Gianfranco Chicarella , Nao Yokota , Tracy A. Paolilli , John J. Fitch , Todd Richard Sarnstrom , Dean Borchardt , Paul Andrew Ansolabehere , Steven Sargeant
发明人： Gianfranco Chicarella , Nao Yokota , Tracy A. Paolilli , John J. Fitch , Todd Richard Sarnstrom , Dean Borchardt , Paul Andrew Ansolabehere , Steven Sargeant
CPC分类号： C23C14/20 , A63H27/10 , A63H2027/1025 , B32B27/08 , B32B27/32 , B32B27/36 , B32B2255/10 , B32B2255/205 , B32B2255/26 , B32B2255/28 , B32B2307/31 , B32B2307/40 , B32B2307/518 , B32B2307/5825 , B32B2307/702 , B32B2307/704 , B32B2307/7244 , C23C14/02 , Y10T428/13 , Y10T428/1303 , Y10T428/131 , Y10T428/1321 , Y10T428/1338 , Y10T428/1341 , Y10T428/1352 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31786
摘要： A long life balloon formed from a lamination. The lamination includes a polyester film with a total thickness of 4 μm to 12 μm. The polyester film includes a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The lamination also includes a sealant layer and a gas barrier layer on an opposite side of the polyester film from the sealant layer. The oxygen transmission rate of the balloon is less than 0.1 cc/100 sqin/day, a bonding strength of the gas barrier layer to the surface of the polyester film is more than 300 g/in at dry conditions, a sealing strength of the balloon is more than 3.5 kg/in, and a floating time of the balloon is more than 20 days.
摘要翻译： 由层压形成的长寿命气球。 叠层包括总厚度为4μm至12μm的聚酯膜。 聚酯膜包括双轴取向聚酯芯层和至少一个非晶共聚酯表皮层。 层压体还包括在密封剂层与聚酯膜的相对侧上的密封层和阻气层。 气球的氧气透过率小于0.1cc / 100平方/天，在干燥条件下阻气层与聚酯薄膜表面的接合强度大于300g / l，气囊的密封强度 超过3.5公斤/英寸，气球的浮动时间超过20天。
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公开(公告)号：US20110081543A1
公开(公告)日：2011-04-07
申请号：US12894647
申请日：2010-09-30
申请人： Mark Lee , Keunsuk P. Chang , Nao Yokota
发明人： Mark Lee , Keunsuk P. Chang , Nao Yokota
CPC分类号： B65D65/466 , B32B27/08 , B32B27/18 , B32B27/28 , B32B27/32 , B32B27/36 , B32B2250/02 , B32B2250/03 , B32B2250/244 , B32B2255/10 , B32B2255/20 , B32B2255/205 , B32B2270/00 , B32B2307/31 , B32B2307/514 , B32B2307/702 , B32B2307/7163 , B32B2307/7246 , B32B2439/70 , Y10T428/12014 , Y10T428/1352 , Y10T428/1355 , Y10T428/1379 , Y10T428/273 , Y10T428/2813 , Y10T428/2817 , Y10T428/2826 , Y10T428/31678 , Y10T428/31681 , Y10T428/31786
摘要： The present invention is directed to a multilayer film having, as its main component, a hydroxy acid polymer with improved gas barrier and optional heat sealability. The oriented film of predominately hydroxy acid polymer having controlled shrink can be produced by melting and coextruding a hydroxy acid polymer with a much thinner layer of an amorphous aromatic copolyester to form a multilayer film that is quench cooled, then biaxially stretched at a process temperature above the glass transition and below the cold crystallization temperature of the hydroxy acid polymer. A heat-setting treatment with a controlled relaxation of the film above the hydroxy acid polymer glass transition temperature and below its melt temperature may be used to control shrinkage. The films thus obtained are vacuum metallized on the aromatic copolyester surface to produce environmentally friendly packaging from predominately renewable resources having improved gas barrier properties.
摘要翻译： 本发明涉及一种具有改进的阻气性和任选的热封性的羟基酸聚合物作为其主要成分的多层膜。 具有受控收缩的主要羟基酸聚合物的定向膜可以通过用非常薄的无定形芳族共聚酯层的熔融和共挤出羟基酸聚合物来形成多层膜，所述多层膜被淬火冷却，然后在上述过程温度下双轴拉伸 玻璃化转变并低于羟基酸聚合物的冷结晶温度。 可以使用在羟基酸聚合物玻璃化转变温度以上且低于其熔融温度下控制松弛膜的热定型处理来控制收缩。 由此获得的薄膜在芳族共聚酯表面上真空金属化，以产生具有改进的气体阻隔性能的主要可再生资源的环境友好的包装。
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公开(公告)号：US20090022919A1
公开(公告)日：2009-01-22
申请号：US12202655
申请日：2008-09-02
申请人： Gianfranco CHICARELLA , Nao Yokota , Tracy A. Paolilli , John J. Fitch , Todd R. Sarnstrom , Dean Borchardt , Paul A. Ansolabehere , Steven Sargeant
发明人： Gianfranco CHICARELLA , Nao Yokota , Tracy A. Paolilli , John J. Fitch , Todd R. Sarnstrom , Dean Borchardt , Paul A. Ansolabehere , Steven Sargeant
IPC分类号： B32B1/00
CPC分类号： C23C14/20 , A63H27/10 , A63H2027/1025 , B32B27/08 , B32B27/32 , B32B27/36 , B32B2255/10 , B32B2255/205 , B32B2255/26 , B32B2255/28 , B32B2307/31 , B32B2307/40 , B32B2307/518 , B32B2307/5825 , B32B2307/702 , B32B2307/704 , B32B2307/7244 , C23C14/02 , Y10T428/13 , Y10T428/1303 , Y10T428/131 , Y10T428/1321 , Y10T428/1338 , Y10T428/1341 , Y10T428/1352 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31786
摘要： A long life balloon formed from a lamination. The lamination includes a polyester film with a total thickness of 4 μm to 12 μm. The polyester film includes a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The lamination also includes a sealant layer and a gas barrier layer on an opposite side of the polyester film from the sealant layer. The oxygen transmission rate of the balloon is less than 0.1 cc/100 sqin/day, a bonding strength of the gas barrier layer to the surface of the polyester film is more than 300 g/in at dry conditions, a sealing strength of the balloon is more than 3.5 kg/in, and a floating time of the balloon is more than 20 days.
摘要翻译： 由层压形成的长寿命气球。 叠层包括总厚度为4μm至12μm的聚酯膜。 聚酯膜包括双轴取向聚酯芯层和至少一个非晶共聚酯表皮层。 层压体还包括在密封剂层与聚酯膜的相对侧上的密封层和阻气层。 气球的氧气透过率小于0.1cc / 100平方/天，在干燥条件下阻气层与聚酯薄膜表面的接合强度大于300g / l，气囊的密封强度 超过3.5公斤/英寸，气球的浮动时间超过20天。
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