PRODUCTION OF GRAFTED POLYETHYLENE FROM RENEW ABLE MATERIALS, THE OBTAINED POLYETHYLENE AND USES THEREOF
    3.
    发明申请
    PRODUCTION OF GRAFTED POLYETHYLENE FROM RENEW ABLE MATERIALS, THE OBTAINED POLYETHYLENE AND USES THEREOF 有权
    从重新生产的聚乙烯生产聚乙烯,获得的聚乙烯及其用途

    公开(公告)号:US20110152454A1

    公开(公告)日:2011-06-23

    申请号:US13055857

    申请日:2009-07-27

    摘要: The invention relates to a method for production of grafted polyethylene comprising the following steps: a) fermentation of primary renewable material with optional purification to give at least one alcohol chosen from ethanol or a mixture of alcohols comprising ethanol; b) dehydration of the alcohol obtained to give in a first reactor at least one alkene selected from ethylene and mixtures of alkenes containing ethylene and optional purification of the alkene to give ethylene; c) polymerization, in a second reactor, of the ethylene to give polyethylene; d) isolation of the polyethylene obtained in step c); e) grafting the polyethylene with at least one grafting monomer selected from the unsaturated carboxylic acids or theifunctional derivatives thereof, the unsaturated dicarboxylic acids having 4-10 carbon atoms and the functional derivatives thereof being C1-C8 alkyl esters or glycidyl ester derivatives of the unsaturated carboxylic acids and the metal salts of the unsaturated carboxylic acids. The invention further relates to the grafted polyethylene obtained by said method, the copolymers and compositions comprising said polyethylene and the use of said polyethylene.

    摘要翻译: 本发明涉及生产接枝聚乙烯的方法,包括以下步骤:a)可任选地纯化初级可再生材料发酵,得到至少一种选自乙醇或包含乙醇的醇的混合物的醇; b)在第一反应器中获得的醇的脱水得到至少一种选自乙烯的烯烃和含乙烯的烯烃的混合物和任选的烯烃纯化以得到乙烯; c)在第二反应器中聚合乙烯,得到聚乙烯; d)分离步骤c)中获得的聚乙烯; e)用至少一种选自不饱和羧酸或其官能衍生物的接枝单体,具有4-10个碳原子的不饱和二羧酸接枝聚乙烯,其官能衍生物是不饱和羧酸或其不饱和羧酸的缩水甘油酯衍生物 羧酸和不饱和羧酸的金属盐。 本发明还涉及通过所述方法获得的接枝聚乙烯,所述共聚物和组合物包含所述聚乙烯和所述聚乙烯的用途。