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公开(公告)号:US06660796B2
公开(公告)日:2003-12-09
申请号:US10022878
申请日:2001-12-20
申请人: Ralf Schueler , Heinz Peirick , Guido Schmitz , Georg Oenbrink , Harald Haeger
发明人: Ralf Schueler , Heinz Peirick , Guido Schmitz , Georg Oenbrink , Harald Haeger
IPC分类号: C08J300
CPC分类号: C08L67/02 , C08L23/08 , C08L33/06 , C08L53/00 , C08L2666/02
摘要: The present invention relates to a molding composition containing thermoplastic polyesters, impact-modifying component which contains anhydride groups, a copolymer of &agr;-olefin, acrylic compound, olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline and/or oxazinone, which has improved low-temperature impact strength; methods of making molding with the molding composition and molding containing the composition.
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公开(公告)号:US06677015B2
公开(公告)日:2004-01-13
申请号:US10021355
申请日:2001-12-19
申请人: Martin Himmelmann , Wilfried Bartz , Franz-Erich Baumann , Guido Schmitz , Georg Oenbrink , Harald Haeger , Ralf Richter
发明人: Martin Himmelmann , Wilfried Bartz , Franz-Erich Baumann , Guido Schmitz , Georg Oenbrink , Harald Haeger , Ralf Richter
IPC分类号: B32B102
CPC分类号: C08G73/028 , C08L79/02 , Y10T428/1352 , Y10T428/31725 , Y10T428/31732
摘要: A molding composition of at least 50% by weight of a polyamine-polyamide copolymer obtained from 0.05 to 2.5% by weight of a polyamine having at least 4 nitrogen atoms and having a viscosity of at least 5 000 Pa•s at 250° C. and at a shear rate of 0.1 l/s, and having a viscosity ratio of at least 7 at 250° C., when the melt viscosities at shear rates of 0.1 l/s and 100 l/s are compared with one another, has high melt stiffness and is easy to cut, and performs well in blow molding.
摘要翻译: 一种至少50重量%的多胺 - 聚酰胺共聚物的模塑组合物,其由0.05至2.5重量%的具有至少4个氮原子并且在250℃下具有至少5 000Pa.s的粘度的多胺获得。 并且以0.1l / s的剪切速率,并且在250℃下具有至少7的粘度比,当在0.1l / s和100l / s的剪切速率下的熔体粘度相互比较时,具有 熔体刚度高,易切削,吹塑性能好。
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公开(公告)号:US06335101B1
公开(公告)日:2002-01-01
申请号:US09510302
申请日:2000-02-22
IPC分类号: B32B2734
CPC分类号: B32B27/08 , B32B1/08 , B32B3/28 , B32B25/08 , B32B27/34 , B32B27/36 , B32B37/153 , B32B2307/202 , B32B2367/00 , B32B2377/00 , B32B2439/00 , B32B2597/00 , Y10T428/1393 , Y10T428/31728 , Y10T428/31736 , Y10T428/3175 , Y10T428/31765 , Y10T428/31786
摘要: A thermoplastic composite having a multiplicity of layers and comprising: I) a layer of a polyamide molding composition, II) a layer of a polyester molding composition, and III) a layer of an adhesion promoter adherent to I and II comprising at least 50% by weight of a blend of: a) from 20 to 80% by weight of a polyamide, prepared from &agr;) at least one diamine having from 6 to 12 carbon atoms, and &bgr;) an essentially stoichiometrically equivalent amount of at least one dicarboxylic acid comprising at least 5 mol % of a dicarboxylic acid having from 10 to 36 carbon atoms, and b) from 80 to 20% by weight of a polyester, prepared from &agr;) a mixture of from 30 to 95 mol % of an aromatic dicarboxylic acid having from 6 to 20 carbon atoms and from 70 to 5 mol % of the same dicarboxylic acid as in the polyamide of the adhesion promoter, having from 10 to 36 carbon atoms, and &bgr;) at least one diol having from 2 to 12 carbon atoms.
摘要翻译: 一种具有多层的热塑性复合材料,包括:I)聚酰胺模塑组合物层,II)聚酯模塑组合物层,和III)与I和II附着的粘合促进剂层,其包含至少50% 共混物的重量为:a)20至80重量%的由α制备的聚酰胺,至少一种具有6至12个碳原子的二胺,和b)基本上化学计量等同量的至少一种二羧酸,至少包含 5摩尔%具有10至36个碳原子的二羧酸,和b)80至20重量%的由下式制备的聚酯:30至95摩尔%的具有6至20个碳原子的芳族二羧酸的混合物 和具有10至36个碳原子的粘合促进剂的聚酰胺中的70至5摩尔%的相同的二羧酸,和至少一种具有2至12个碳原子的二醇。
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公开(公告)号:US06579581B2
公开(公告)日:2003-06-17
申请号:US09886217
申请日:2001-06-22
IPC分类号: C08L7700
CPC分类号: C08L77/02 , C08L23/08 , C08L53/02 , C08L77/00 , C08L77/06 , Y10T428/1321 , Y10T428/1352 , Y10T428/31739 , C08L23/00 , C08L53/00 , C08L2666/02
摘要: A molding which comprises the following components: (I) from 60 to 96.5 parts by weight of polyamide; (II) from 3 to 39.5 parts by weight of an impact-modifying component which contains anhydride groups, (III) from 0.5 to 20 parts by weight of a copolymer which contains units of the monomers: (a) &agr;-olefin, (b) acrylic compound, and also (c) olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline or oxazinone, where the total of the parts by weight of components I, II, and III is 100, and where moreover the polyamide has an excess of amino end groups, has improved low-temperature impact strength, even if the molding composition also comprises a plasticizer.
摘要翻译: 一种成型体,其包含以下组分:(I)60至96.5重量份的聚酰胺;(II)3至39.5重量份的含有酸酐基团的冲击改性组分,(III)为0.5至20份 重量的包含单体单元的共聚物:(a)α-烯烃,(b)丙烯酸化合物,和(c)烯属不饱和环氧化物,羧酸酐,羰酰亚胺,恶唑啉或恶嗪酮,其中部分的总数由 组分I,II和III的重量为100,此外,聚酰胺具有过量的氨基端基,即使成型组合物还包含增塑剂,也具有改善的低温冲击强度。
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公开(公告)号:US06355358B1
公开(公告)日:2002-03-12
申请号:US09605363
申请日:2000-06-29
申请人: Michael Böer , Guido Schmitz , Georg Oenbrink , Harald Häger , Ralf Richter
发明人: Michael Böer , Guido Schmitz , Georg Oenbrink , Harald Häger , Ralf Richter
IPC分类号: B32B702
CPC分类号: B32B27/08 , B32B1/08 , B32B25/08 , B32B27/34 , B32B27/36 , B32B2307/202 , B32B2367/00 , B32B2377/00 , B32B2597/00 , C08G69/48 , C08L77/00 , C08L77/02 , C08L77/06 , Y10T428/13 , Y10T428/1321 , Y10T428/139 , Y10T428/1393 , Y10T428/31504 , Y10T428/31725 , Y10T428/31736 , Y10T428/31786 , C08L51/00
摘要: A thermoplastic multilayer composite, and articles made therefrom, which has at least one layer I of a thermoplastic molding composition, at least one layer II of a further thermoplastic molding composition, bonded together with at least one layer of an adhesion promoter disposed between at least one layer I and at least one layer II. The adhesion promoter is at least 5% by weight of a graft copolymer prepared from 0.5 to 25% by weight, based on the total amount of graft copolymer, of a polyamine having at least 4 nitrogen atoms and having a number average molecular weight Mn of at least 146 g/mol, and polyamide-forming monomers selected from lactams, &ohgr;-aminocarboxylic acids, equimolar mixtures of diamines and dicarboxylic acids, and their mixtures.
摘要翻译: 一种热塑性多层复合材料及其制成的制品,其具有至少一层热塑性模塑组合物,至少一层另外的热塑性模塑组合物,其至少与至少一层粘附促进剂层结合在一起, 一层I和至少一层II。 粘合促进剂为至少5重量%的接枝共聚物,其接枝共聚物的制备方法为0.5至25重量%,基于接枝共聚物的总量,具有至少4个氮原子且具有数均分子量Mn的多胺 至少146g / mol和选自内酰胺,ω-氨基羧酸,二胺和二羧酸的等摩尔混合物的聚酰胺形成单体及其混合物。
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公开(公告)号:US06794048B2
公开(公告)日:2004-09-21
申请号:US10025547
申请日:2001-12-26
申请人: Guido Schmitz , Harald Haeger
发明人: Guido Schmitz , Harald Haeger
IPC分类号: B32B2732
CPC分类号: B32B7/12 , B32B27/32 , B32B27/34 , Y10T428/1393 , Y10T428/31728 , Y10T428/31732 , Y10T428/31757
摘要: A multilayer composite comprising the following layers bound directly to one another: I. a layer I of a polyamide molding composition; II. a layer II of a bonding agent comprising at least 50% by weight of a mixture of a) from 30 to 70 parts by volume of polyamide and b) from 70 to 30 parts by volume of polyolefin, where the sum of the parts by volume is 100 and in addition at least some of the polyamide is present either in the form of a polyamide-polyolefin graft copolymer or as a highly branched polyamine-polyamide copolymer; III. if desired a layer III of a polyolefin molding composition, displays good adhesion between layers which remains largely intact even on prolonged contact with alcohol-containing or aqueous media at elevated temperature.
摘要翻译: 一种多层复合材料,其包含彼此直接结合的以下层: 聚酰胺模塑组合物的层I; II。 粘合剂的层II包含至少50重量%的a)30至70体积份的聚酰胺和b)70至30体积份的聚烯烃的混合物,其中部分体积的总和为100 另外至少一些聚酰胺以聚酰胺 - 聚烯烃接枝共聚物或高度支化的聚胺 - 聚酰胺共聚物的形式存在; III。 如果需要,聚烯烃模塑组合物的层III显示出在高温下与含醇介质或含水介质的长时间接触时仍保持很大程度上完好的层之间的良好粘合性。
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公开(公告)号:US08048504B2
公开(公告)日:2011-11-01
申请号:US11357971
申请日:2006-02-22
申请人: Guido Schmitz , Harald Haeger , Hans Ries , Wilfried Bartz
发明人: Guido Schmitz , Harald Haeger , Hans Ries , Wilfried Bartz
CPC分类号: B32B27/34 , B32B1/02 , B32B1/08 , B32B3/28 , B32B27/08 , B32B27/28 , B32B27/306 , B32B27/32 , B32B2250/03 , B32B2250/24 , B32B2250/40 , B32B2270/00 , B32B2272/00 , B32B2307/202 , B32B2307/308 , B32B2307/50 , B32B2307/714 , B32B2307/7242 , B32B2307/7244 , B32B2307/7265 , B32B2323/04 , B32B2331/04 , B32B2377/00 , B32B2439/40 , B32B2439/70 , B32B2597/00 , B32B2605/08 , C08L77/00 , C08L77/02 , C08L77/06 , Y10T428/1352 , Y10T428/1379 , Y10T428/139 , Y10T428/1393 , Y10T428/31725 , Y10T428/31732 , Y10T428/3175
摘要: A layered composite which includes the following layers (I) and (II), wherein layer (I) includes (a) from 0 to 80 part by weight of at least one particular polyamide; (b) from 0 to 100 parts by weight of at least one polyamine-polyamide copolymer; and (c) from 0 to 80 parts by weight of at least one particular polyamide which is different from (a), wherein various monomer units are present in at least 20 parts by weight of the entirety of (a) and (b) and various other monomer units are present in at least 20 parts by weight of the entirety of (b) and (c); and layer (II) includes at least one ethylene-vinyl alcohol copolymer.
摘要翻译: 包括以下层(I)和(II)的层状复合材料,其中层(I)包括(a)0至80重量份的至少一种特定聚酰胺; (b)0-100重量份的至少一种聚胺 - 聚酰胺共聚物; 和(c)0至80重量份的至少一种与(a)不同的特定聚酰胺,其中各种单体单元以(a)和(b)的全部至少20重量份存在,以及 各种其它单体单元存在于(b)和(c)全部的至少20重量份中; 和层(II)包括至少一种乙烯 - 乙烯醇共聚物。
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公开(公告)号:US08221890B2
公开(公告)日:2012-07-17
申请号:US11240493
申请日:2005-10-03
申请人: Guido Schmitz , Harald Haeger , Hans Ries
发明人: Guido Schmitz , Harald Haeger , Hans Ries
IPC分类号: B32B1/08 , B32B27/06 , B32B25/16 , B32B27/00 , B32B27/04 , B32B27/08 , B32B27/28 , B32B27/32 , B32B27/34 , B32B27/36 , B32B37/00 , B29C47/06 , B29C45/00
CPC分类号: C08L77/00 , A22C13/0013 , A22C2013/0053 , A22C2013/0059 , B32B1/08 , B32B27/08 , B32B27/18 , B32B27/304 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2250/24 , B32B2307/718 , B32B2307/7242 , B32B2307/7265 , B32B2597/00 , B32B2605/08 , C08L67/02 , C08L77/06 , Y10T428/1321 , Y10T428/1334 , Y10T428/1352 , Y10T428/1372 , Y10T428/1386 , Y10T428/1393 , Y10T428/3154 , Y10T428/31544 , Y10T428/31736 , Y10T428/31739 , Y10T428/31743 , Y10T428/31746 , Y10T428/31786 , Y10T428/31938 , C08L2666/02 , C08L2666/06
摘要: A multilayer composite which has improved adhesion between the layers, with the following layers: I. an inner layer I selected from among a fluoropolymer molding composition and a polyolefin molding composition; II. a bonding layer II which has the following composition: a) from 2 to 80 parts by weight of a polyamine-polyamide graft copolymer, b) from 0 to 85 parts by weight of a polyester, c) from 0 to 85 parts by weight of a polymer selected from among polyamides, fluoropolymers and polyolefins, where the sum of the parts by weight of a), b) and c) is 100; d) not more than 50 parts by weight of additives; III. a layer III of a polyester molding composition.
摘要翻译: 具有改进的层之间的粘合性的多层复合材料,具有以下层:I.选自氟聚合物模塑组合物和聚烯烃模塑组合物的内层I; 二, 具有以下组成的粘合层II:a)2至80重量份的聚胺 - 聚酰胺接枝共聚物,b)0至85重量份的聚酯,c)0至85重量份的 选自聚酰胺,含氟聚合物和聚烯烃的聚合物,其中a),b)和c)的重量份之和为100; d)不超过50重量份的添加剂; 三, 聚酯模塑组合物的层III。
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公开(公告)号:US06783821B2
公开(公告)日:2004-08-31
申请号:US10024379
申请日:2001-12-21
申请人: Hans Ries , Guido Schmitz , Harald Haeger
发明人: Hans Ries , Guido Schmitz , Harald Haeger
IPC分类号: B32B102
CPC分类号: C08L77/00 , B32B27/34 , C08L77/02 , C08L77/06 , Y10T428/13 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/1393 , Y10T428/31562 , Y10T428/31728 , Y10T428/31732
摘要: A good layer adhesion can be achieved in a composite having two or more layers wherein a layer I is obtained from a molding composition which has the following components: a) from 0 to 80 parts by weight of a polyamide selected from the group consisting of PA6, PA66, PA6/66 and a mixture thereof; b) from 0.05 to 100 parts by weight of a polyamine-polyamide copolymer; and c) from 0 to 80 parts by weight of a polyamide selected from the group consisting of PA11, PA12, PA612, PA1012, PA1212 and a mixture thereof; wherein a total of the parts by weight of components a), b) and c) is 100; wherein at least 20 parts by weight of components a) and b) is a monomer unit which is obtained from caprolactam and/or from a combination of hexamethylenediamine/adipic acid; and wherein at least 20 parts by weight of components b) and c) is a monomer unit which is obtained from &ohgr;-aminoundecanoic acid, laurolactam, a mixture of hexamethylenediamine and 1,12-dodecanedioic acid, a mixture of 1,10-decanediamine and 1,12-dodecanedioic acid, and/or a mixture of 1,12-dodecanediamine and 1,12-dodecanedioic acid.
摘要翻译: 在具有两层或更多层的复合材料中可以实现良好的层粘合性,其中层I由具有以下组分的模塑组合物获得:a)0至80重量份选自PA6, PA66,PA6 / 66及其混合物; b)0.05-100重量份的聚胺 - 聚酰胺共聚物; 和c)0至80重量份选自PA11,PA12,PA612,PA1012,PA1212的聚酰胺及其混合物;其中组分a),b)和c)的总重量份, 为100;其中至少20重量份的组分a)和b)是由己内酰胺和/或六亚甲基二胺/己二酸的组合获得的单体单元; 并且其中至少20重量份的组分b)和c)是由ω-氨基十一烷酸,月桂内酰胺,六亚甲基二胺和1,12-十二烷二酸的混合物得到的单体单元,1,10-癸二胺和 1,12-十二烷二酸和/或1,12-十二烷二胺和1,12-十二烷二酸的混合物。
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10.
公开(公告)号:US08133561B2
公开(公告)日:2012-03-13
申请号:US10588487
申请日:2005-08-10
申请人: Guido Schmitz , Harald Haeger , Hans Ries
发明人: Guido Schmitz , Harald Haeger , Hans Ries
IPC分类号: B32B1/08
CPC分类号: C08L23/04 , B32B1/08 , B32B3/28 , B32B7/12 , B32B27/08 , B32B27/16 , B32B27/18 , B32B27/304 , B32B27/306 , B32B27/32 , B32B27/322 , B32B27/34 , B32B2250/24 , B32B2264/0207 , B32B2270/00 , B32B2307/202 , B32B2307/558 , B32B2307/7242 , B32B2307/7265 , B32B2439/40 , B32B2597/00 , B32B2605/08 , C08L23/10 , C08L77/02 , C08L77/06 , C08L2666/04 , C09J177/02 , C09J177/06 , F16L9/133 , Y10S138/01 , Y10S138/07 , Y10T428/1352 , Y10T428/1379 , Y10T428/139 , Y10T428/1393 , Y10T428/31725 , Y10T428/31732 , C08L2666/20
摘要: A multilayer composite which comprises the following layers: I. an interior layer I selected from among a fluoropolymer molding composition and a polyolefin molding composition; II. a bonding agent layer II which has the following composition: a) from 0 to 80 parts by weight of a polyamine-polyamide graft copolymer, b) from 0 to 85 parts by weight of polyamide, c) from 0 to 85 parts by weight of a polymer selected from among fluoropolymers and polyolefins; with the sum of the parts by weight of a), b) and c) being 100; and, in addition, the sum of the components a) and b) comprising at least 20 parts by weight of monomer units derived from caprolactam and/or the combination hexamethylenediamine/adipic acid, hexamethylenediamine/suberic acid, hexamethylenediamine/sebacic acid, hexamethylenediamine/dodecanedioic acid, hexamethylenediamine/isophthalic acid or hexamethylenediamine/terephthalic acid and d) not more than 50 parts by weight of additives selected from among impact-modifying rubber and customary auxiliaries and additives; III. a layer III comprising an EVOH molding composition, has improved adhesion of the layers.
摘要翻译: 一种多层复合材料,其包含以下层:I.选自氟聚合物模塑组合物和聚烯烃模塑组合物的内层I; 二, 具有以下组成的粘合剂层II:a)0至80重量份的聚胺 - 聚酰胺接枝共聚物,b)0至85重量份的聚酰胺,c)0至85重量份的 选自含氟聚合物和聚烯烃的聚合物; a),b)和c)的重量份数之和为100; 另外,组分a)和b)的总和包含至少20重量份衍生自己内酰胺和/或六亚甲基二胺/己二酸的组合的单体单元,六亚甲基二胺/辛二酸,六亚甲基二胺/癸二酸,六亚甲基二胺/ 十二烷二酸,六亚甲基二胺/间苯二甲酸或六亚甲基二胺/对苯二甲酸,以及d)不超过50重量份的选自冲击改性橡胶和常规助剂和添加剂的添加剂; 三, 包含EVOH模塑组合物的层III具有改善的层的粘附性。
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