Composite having more than one layer
    3.
    发明授权
    Composite having more than one layer 失效
    复合材料有多于一层

    公开(公告)号:US06335101B1

    公开(公告)日:2002-01-01

    申请号:US09510302

    申请日:2000-02-22

    IPC分类号: B32B2734

    摘要: A thermoplastic composite having a multiplicity of layers and comprising: I) a layer of a polyamide molding composition, II) a layer of a polyester molding composition, and III) a layer of an adhesion promoter adherent to I and II comprising at least 50% by weight of a blend of: a) from 20 to 80% by weight of a polyamide, prepared from &agr;) at least one diamine having from 6 to 12 carbon atoms, and &bgr;) an essentially stoichiometrically equivalent amount of at least one dicarboxylic acid comprising at least 5 mol % of a dicarboxylic acid having from 10 to 36 carbon atoms, and b) from 80 to 20% by weight of a polyester, prepared from &agr;) a mixture of from 30 to 95 mol % of an aromatic dicarboxylic acid having from 6 to 20 carbon atoms and from 70 to 5 mol % of the same dicarboxylic acid as in the polyamide of the adhesion promoter, having from 10 to 36 carbon atoms, and &bgr;) at least one diol having from 2 to 12 carbon atoms.

    摘要翻译: 一种具有多层的热塑性复合材料,包括:I)聚酰胺模塑组合物层,II)聚酯模塑组合物层,和III)与I和II附着的粘合促进剂层,其包含至少50% 共混物的重量为:a)20至80重量%的由α制备的聚酰胺,至少一种具有6至12个碳原子的二胺,和b)基本上化学计量等同量的至少一种二羧酸,至少包含 5摩尔%具有10至36个碳原子的二羧酸,和b)80至20重量%的由下式制备的聚酯:30至95摩尔%的具有6至20个碳原子的芳族二羧酸的混合物 和具有10至36个碳原子的粘合促进剂的聚酰胺中的70至5摩尔%的相同的二羧酸,和至少一种具有2至12个碳原子的二醇。

    Polymer blend having good low-temperature impact strength
    4.
    发明授权
    Polymer blend having good low-temperature impact strength 有权
    聚合物共混物具有良好的低温冲击强度

    公开(公告)号:US06579581B2

    公开(公告)日:2003-06-17

    申请号:US09886217

    申请日:2001-06-22

    IPC分类号: C08L7700

    摘要: A molding which comprises the following components: (I) from 60 to 96.5 parts by weight of polyamide; (II) from 3 to 39.5 parts by weight of an impact-modifying component which contains anhydride groups, (III) from 0.5 to 20 parts by weight of a copolymer which contains units of the monomers: (a) &agr;-olefin, (b) acrylic compound, and also (c) olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline or oxazinone, where the total of the parts by weight of components I, II, and III is 100, and where moreover the polyamide has an excess of amino end groups, has improved low-temperature impact strength, even if the molding composition also comprises a plasticizer.

    摘要翻译: 一种成型体,其包含以下组分:(I)60至96.5重量份的聚酰胺;(II)3至39.5重量份的含有酸酐基团的冲击改性组分,(III)为0.5至20份 重量的包含单体单元的共聚物:(a)α-烯烃,(b)丙烯酸化合物,和(c)烯属不饱和环氧化物,羧酸酐,羰酰亚胺,恶唑啉或恶嗪酮,其中部分的总数由 组分I,II和III的重量为100,此外,聚酰胺具有过量的氨基端基,即使成型组合物还包含增塑剂,也具有改善的低温冲击强度。

    Multilayer composite based on polyamide/polyolefin
    6.
    发明授权
    Multilayer composite based on polyamide/polyolefin 失效
    基于聚酰胺/聚烯烃的多层复合材料

    公开(公告)号:US06794048B2

    公开(公告)日:2004-09-21

    申请号:US10025547

    申请日:2001-12-26

    IPC分类号: B32B2732

    摘要: A multilayer composite comprising the following layers bound directly to one another: I. a layer I of a polyamide molding composition; II. a layer II of a bonding agent comprising at least 50% by weight of a mixture of a) from 30 to 70 parts by volume of polyamide and b) from 70 to 30 parts by volume of polyolefin, where the sum of the parts by volume is 100 and in addition at least some of the polyamide is present either in the form of a polyamide-polyolefin graft copolymer or as a highly branched polyamine-polyamide copolymer; III. if desired a layer III of a polyolefin molding composition, displays good adhesion between layers which remains largely intact even on prolonged contact with alcohol-containing or aqueous media at elevated temperature.

    摘要翻译: 一种多层复合材料,其包含彼此直接结合的以下层: 聚酰胺模塑组合物的层I; II。 粘合剂的层II包含至少50重量%的a)30至70体积份的聚酰胺和b)70至30体积份的聚烯烃的混合物,其中部分体积的总和为100 另外至少一些聚酰胺以聚酰胺 - 聚烯烃接枝共聚物或高度支化的聚胺 - 聚酰胺共聚物的形式存在; III。 如果需要,聚烯烃模塑组合物的层III显示出在高温下与含醇介质或含水介质的长时间接触时仍保持很大程度上完好的层之间的良好粘合性。

    Polyamide composite having two or more layers
    9.
    发明授权
    Polyamide composite having two or more layers 有权
    具有两层或更多层的聚酰胺复合物

    公开(公告)号:US06783821B2

    公开(公告)日:2004-08-31

    申请号:US10024379

    申请日:2001-12-21

    IPC分类号: B32B102

    摘要: A good layer adhesion can be achieved in a composite having two or more layers wherein a layer I is obtained from a molding composition which has the following components: a) from 0 to 80 parts by weight of a polyamide selected from the group consisting of PA6, PA66, PA6/66 and a mixture thereof; b) from 0.05 to 100 parts by weight of a polyamine-polyamide copolymer; and c) from 0 to 80 parts by weight of a polyamide selected from the group consisting of PA11, PA12, PA612, PA1012, PA1212 and a mixture thereof; wherein a total of the parts by weight of components a), b) and c) is 100; wherein at least 20 parts by weight of components a) and b) is a monomer unit which is obtained from caprolactam and/or from a combination of hexamethylenediamine/adipic acid; and wherein at least 20 parts by weight of components b) and c) is a monomer unit which is obtained from &ohgr;-aminoundecanoic acid, laurolactam, a mixture of hexamethylenediamine and 1,12-dodecanedioic acid, a mixture of 1,10-decanediamine and 1,12-dodecanedioic acid, and/or a mixture of 1,12-dodecanediamine and 1,12-dodecanedioic acid.

    摘要翻译: 在具有两层或更多层的复合材料中可以实现良好的层粘合性,其中层I由具有以下组分的模塑组合物获得:a)0至80重量份选自PA6, PA66,PA6 / 66及其混合物; b)0.05-100重量份的聚胺 - 聚酰胺共聚物; 和c)0至80重量份选自PA11,PA12,PA612,PA1012,PA1212的聚酰胺及其混合物;其中组分a),b)和c)的总重量份, 为100;其中至少20重量份的组分a)和b)是由己内酰胺和/或六亚甲基二胺/己二酸的组合获得的单体单元; 并且其中至少20重量份的组分b)和c)是由ω-氨基十一烷酸,月桂内酰胺,六亚甲基二胺和1,12-十二烷二酸的混合物得到的单体单元,1,10-癸二胺和 1,12-十二烷二酸和/或1,12-十二烷二胺和1,12-十二烷二酸的混合物。