摘要:
A molding composition of at least 50% by weight of a polyamine-polyamide copolymer obtained from 0.05 to 2.5% by weight of a polyamine having at least 4 nitrogen atoms and having a viscosity of at least 5 000 Pa•s at 250° C. and at a shear rate of 0.1 l/s, and having a viscosity ratio of at least 7 at 250° C., when the melt viscosities at shear rates of 0.1 l/s and 100 l/s are compared with one another, has high melt stiffness and is easy to cut, and performs well in blow molding.
摘要:
A molding which comprises the following components: (I) from 60 to 96.5 parts by weight of polyamide; (II) from 3 to 39.5 parts by weight of an impact-modifying component which contains anhydride groups, (III) from 0.5 to 20 parts by weight of a copolymer which contains units of the monomers: (a) &agr;-olefin, (b) acrylic compound, and also (c) olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline or oxazinone, where the total of the parts by weight of components I, II, and III is 100, and where moreover the polyamide has an excess of amino end groups, has improved low-temperature impact strength, even if the molding composition also comprises a plasticizer.
摘要:
A thermoplastic composite having a multiplicity of layers and comprising: I) a layer of a polyamide molding composition, II) a layer of a polyester molding composition, and III) a layer of an adhesion promoter adherent to I and II comprising at least 50% by weight of a blend of: a) from 20 to 80% by weight of a polyamide, prepared from &agr;) at least one diamine having from 6 to 12 carbon atoms, and &bgr;) an essentially stoichiometrically equivalent amount of at least one dicarboxylic acid comprising at least 5 mol % of a dicarboxylic acid having from 10 to 36 carbon atoms, and b) from 80 to 20% by weight of a polyester, prepared from &agr;) a mixture of from 30 to 95 mol % of an aromatic dicarboxylic acid having from 6 to 20 carbon atoms and from 70 to 5 mol % of the same dicarboxylic acid as in the polyamide of the adhesion promoter, having from 10 to 36 carbon atoms, and &bgr;) at least one diol having from 2 to 12 carbon atoms.
摘要:
The present invention relates to a molding composition containing thermoplastic polyesters, impact-modifying component which contains anhydride groups, a copolymer of &agr;-olefin, acrylic compound, olefinically unsaturated epoxide, carboxylic anhydride, carboximide, oxazoline and/or oxazinone, which has improved low-temperature impact strength; methods of making molding with the molding composition and molding containing the composition.
摘要:
A layered composite which includes the following layers (I) and (II), wherein layer (I) includes (a) from 0 to 80 part by weight of at least one particular polyamide; (b) from 0 to 100 parts by weight of at least one polyamine-polyamide copolymer; and (c) from 0 to 80 parts by weight of at least one particular polyamide which is different from (a), wherein various monomer units are present in at least 20 parts by weight of the entirety of (a) and (b) and various other monomer units are present in at least 20 parts by weight of the entirety of (b) and (c); and layer (II) includes at least one ethylene-vinyl alcohol copolymer.
摘要:
A layered composite contains the following layers: (I) a layer I composition containing (a) from 0 to 80 parts by weight of at least one polyamide; (b) from 0 to 100 parts by weight of at least one polyamine-polyamide copolymer; and (c) from 0 to 80 parts by weight of at least one polyamide; and (II) a layer II composition containing at least one ethylene-vinyl alcohol copolymer.
摘要:
The invention provides a method to produce primary diamines by catalytic conversion of diols having a linear main chain of from 4 to 31 carbon atoms into the corresponding diamines. The reaction is conducted in a liquid or supercritical phase and is catalyzed by a homogeneous ruthenium-containing complex. The primary diamines obtained may be suitable for polyamide syntheses.
摘要:
A moulding composition, comprising at least 40 wt. % of the following components: a) 60 to 99 parts by wt. of a partially aromatic copolyamide which comprises as polymerized monomer units: I. 30 to 90 mol % of a combination of hexamethylenediamine and terephthalic acid; and II. 70 to 10 mol % of a lactam and/or of an ω-aminocarboxylic acid with 11 or 12 C atoms; and b) 40 to 1 parts by wt. of an olefinic copolymer comprising as polymerized monomer units: i) 35 to 94.9 wt. % of ethene-based monomer units, ii) 5 to 65 wt. % of monomer units based on a 1-alkene with 4 to 8 C atoms, iii) 0 to 10 wt. % of monomer units based on an olefin different from i) and ii), and iv) 0.1 to 2.5 wt. % of monomer units based on an aliphatically unsaturated dicarboxylic acid anhydride, wherein a sum of the weight % values of i), ii), iii) and iv) is 100%, and the sum of the parts by wt. of a) and b) is 100; which can is processed into moulded articles with improved thermal aging resistance is provided.
摘要:
A film whose outer layer is composed of a molding composition which is in essence composed of the following components: a) from 3 to 50% by weight of a polyamide, selected from the group of PA11 and PA12, and b) from 50 to 97% by weight of a polyamide, selected from the group of PA1012 and PA1212, where the percentages are based on the entirety of components a) and b), is suitable for decoration of moldings which retain their gloss during their service time.
摘要:
A film whose outer layer is composed of a molding composition which is in essence composed of the following components: a) from 3 to 50% by weight of a polyamide, selected from the group of PA11 and PA12, and b) from 50 to 97% by weight of a polyamide, selected from the group of PA1012 and PA1212, where the percentages are based on the entirety of components a) and b), is suitable for decoration of moldings which retain their gloss during their service time.