公开(公告)号：US20180117568A1

公开(公告)日：2018-05-03

申请号：US15856026

申请日：2017-12-27

Applicant: SHELL OIL COMPANY

Inventor： David Allen COOPER ,  Sjoerd ALKEMA ,  Lay Hwa ONG ,  Bart PELGRIM ,  László DOMOKOS ,  Ferry WINTER

IPC: B01J23/888 ,  C10G47/14 ,  C10G47/12 ,  B01J37/02 ,  B01J37/00 ,  B01J35/10 ,  B01J21/12 ,  B01J37/20 ,  B01J37/03

CPC classification number: B01J23/888 ,  B01J21/12 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/03 ,  B01J37/036 ,  B01J37/20 ,  C10G47/12 ,  C10G47/14

Abstract: A process for preparing a hydrocarbon conversion catalyst that comprises a specially made silica-alumina composition and a metal or metal compound selected from Group VIB and Group VIII metals. The silica-alumina composition is made by preparing an aqueous mixture containing aluminum sulfate followed by adding alkali metal aluminate to the mixture to enhance the pH to within specified range and then adding aluminum sulfate to the mixture to lower the pH. Then alkali metal silicate is added followed by several other pH swings to provide a mixture containing silica-alumina. The resulting mixture is treated with an alkaline solution to provide a precipitate solid that is recovered to obtain a silica-alumina composition containing of from 30 to 70% wt silica and of from 70 to 30% wt of alumina.

公开(公告)号：US20170190980A1

公开(公告)日：2017-07-06

申请号：US15313726

申请日：2015-05-26

Applicant: SHELL OIL COMPANY

Inventor： Johannes Bernardus Wilhelmus MORSINK ,  Johannes TURFBOER ,  Rendert Jan WIERSMA ,  Ferry WINTER

IPC: C10G2/00 ,  C09D11/033 ,  C09D7/00

CPC classification number: C10G2/332 ,  C09D5/00 ,  C09D7/40 ,  C09D7/43 ,  C09D11/033 ,  C10G2/30 ,  C10G2300/1022 ,  C10G2300/1051 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2400/04 ,  C10G2400/06 ,  C10L1/04 ,  C10L2200/0492

Abstract: The present invention provides a Fischer-Tropsch gasoil fraction having an initial boiling point of at least 160° C. and a final boiling point of at most 215° C. In another aspect the present invention provides a composition and the use of a Fischer-Tropsch gasoil fraction according to the invention.

公开(公告)号：US20160271594A1

公开(公告)日：2016-09-22

申请号：US15033926

申请日：2014-11-04

Applicant: SHELL OIL COMPANY

Inventor： Ferry WINTER ,  Jen Arend VAN WELSENES ,  Marcello Stefano RIGUTTO ,  Patricia Johanna Anne Maria GILTAY ,  Johannes Jacobus Maria VAN VLAANDEREN ,  Ali AZGHAY

IPC: B01J27/19 ,  B01J35/02 ,  B01J37/08 ,  B01J37/20 ,  C10G45/08 ,  B01J37/02

CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J23/883 ,  B01J31/0202 ,  B01J31/04 ,  B01J35/0006 ,  B01J35/0026 ,  B01J35/026 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/0215 ,  B01J37/0236 ,  B01J37/024 ,  B01J37/08 ,  B01J37/086 ,  B01J37/088 ,  B01J37/20 ,  B01J37/28 ,  B01J2523/00 ,  C10G45/08 ,  B01J2523/31 ,  B01J2523/51 ,  B01J2523/68 ,  B01J2523/845 ,  B01J2523/847

Abstract: Process for preparing a hydrotreating catalyst comprising of from 5 wt % to 50 wt % of molybdenum, of from 0.5 wt % to 20 wt % of cobalt, and of from 0 to 5 wt % of phosphorus, all based on total dry weight of catalyst, which process comprises (a) treating a nickel containing carrier with molybdenum, cobalt and of from 1 to 60% wt of gluconic acid, based on weight of carrier, and optionally phosphorus, (b) optionally drying the treated carrier at a temperature of from 40 to 200° C., and (c) calcining the treated and optionally dried carrier at a temperature of from 200 to 650° C. to obtain the calcined treated carrier.

Abstract translation: 制备加氢处理催化剂的方法，所述加氢处理催化剂包含5重量％至50重量％的钼，0.5重量％至20重量％的钴和0至5重量％的磷，均基于催化剂的总干重 ，该方法包括（a）基于载体的重量和任选的磷，用钼，钴和1至60重量％的葡萄糖酸处理含镍载体，（b）任选地在经处理的载体的温度 40℃至200℃，和（c）在200至650℃的温度下煅烧经处理和任选干燥的载体以获得经煅烧处理的载体。

公开(公告)号：US20160264879A1

公开(公告)日：2016-09-15

申请号：US15033927

申请日：2014-11-04

Applicant: SHELL OIL COMPANY

Inventor： Ferry WINTER ,  Jan Arend VAN WELSENES ,  Marcello Stefano RIGUTTO ,  Patricia Johanna Anne Maria GILTAY ,  Johannes Jacobus Maria VAN VLAANDEREN ,  Ali AZGHAY

IPC: C10G45/08 ,  B01J37/08 ,  B01J37/20 ,  B01J27/19 ,  B01J21/04 ,  B01J37/02 ,  B01J35/00

CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J23/883 ,  B01J31/0202 ,  B01J31/04 ,  B01J35/0006 ,  B01J35/0026 ,  B01J35/026 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/0215 ,  B01J37/0236 ,  B01J37/024 ,  B01J37/08 ,  B01J37/086 ,  B01J37/088 ,  B01J37/20 ,  B01J37/28 ,  B01J2523/00 ,  C10G45/08 ,  B01J2523/31 ,  B01J2523/51 ,  B01J2523/68 ,  B01J2523/845 ,  B01J2523/847

Abstract: Process for preparing a hydrotreating catalyst comprising of from 5 wt % to 50 wt % of molybdenum, of from 0.5 wt % to 20 wt % of nickel and of from 0 to 5 wt % of phosphorus, all based on total dry weight of catalyst, which process comprises (a) treating alumina carrier with molybdenum and nickel and of from 1 to 60% wt of gluconic acid, based on weight of carrier, and op tionally phosphorus, (b) optionally drying the treated carrier at a temperature of from 40 to 200° C., and (c) calcining the treated and optionally dried carrier at a temperature of from 200 to 650° C. to obtain the calcined treated carrier.

Abstract translation: 制备加氢处理催化剂的方法，其包含5重量％至50重量％的钼，0.5重量％至20重量％的镍和0至5重量％的磷，均基于催化剂的总干重， 该方法包括（a）以钼和镍为原料处理氧化铝载体，以及基于载体的重量计，1至60重量％的葡萄糖酸，和磷酸作用，（b）任选地在40℃的温度下干燥经处理的载体 至200℃，和（c）在200-650℃的温度下煅烧经处理和任选干燥的载体以获得经煅烧处理的载体。

公开(公告)号：US20170191007A1

公开(公告)日：2017-07-06

申请号：US15313650

申请日：2015-05-26

Applicant: SHELL OIL COMPANY

Inventor： Johannes Bernardus Wilhelmus MORSINK ,  Johannes TURFBOER ,  Rendert Jan WIERSMA ,  Ferry WINTER

IPC: C11D7/24 ,  C10G47/00 ,  C11D11/00 ,  C10G2/00

CPC classification number: C11D7/24 ,  C10G2/332 ,  C10G47/00 ,  C10G2300/1022 ,  C10G2300/301 ,  C10G2300/302 ,  C10L1/04 ,  C11D3/43 ,  C11D7/5027 ,  C11D11/0017 ,  C11D11/0029 ,  C23G5/024 ,  D06L1/02

Abstract: The present invention provides a Fischer-Tropsch gasoil fraction having an initial boiling point of at least 165° C. and a final boiling point of at most 220° C. In another aspect the present invention provides a cleaning composition and the use of a Fischer-Tropsch gasoil fraction according to the invention.

公开(公告)号：US20140183098A1

公开(公告)日：2014-07-03

申请号：US14132741

申请日：2013-12-18

Applicant: Shell Oil Company

Inventor： David Allen COOPER ,  Sjoerd ALKEMA ,  Lay Hwa ONG ,  Bart PELGRIM ,  Laszlo DOMOKOS ,  Ferry WINTER

IPC: B01J23/888 ,  C10G47/20

CPC classification number: B01J23/888 ,  B01J21/12 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/03 ,  B01J37/036 ,  B01J37/20 ,  C10G47/12 ,  C10G47/14

Abstract: A process for preparing a hydrocarbon conversion catalyst that comprises a specially made silica-alumina composition and a metal or metal compound selected from Group VIB and Group VIII metals. The silica-alumina composition is made by preparing an aqueous mixture containing aluminum sulfate followed by adding alkali metal aluminate to the mixture to inhance the pH to within specified range and then adding aluminum sulfate to the mixture to lower the pH. Then alkali metal silicate is added followed by several other pH swings to provide a mixture containing silica-alumina. The resulting mixture is treated with an alkaline solution to provide a precipitate solid that is recovered to obtain a silica-alumina composition containing of from 30 to 70% wt silica and of from 70 to 30% wt of alumina.

Abstract translation: 一种制备烃转化催化剂的方法，其包含特殊制备的二氧化硅 - 氧化铝组合物和选自VIB族和VIII族金属的金属或金属化合物。 二氧化硅 - 氧化铝组合物通过制备含有硫酸铝的含水混合物，然后向混合物中加入碱金属铝酸盐以将pH提高到规定范围内，然后向混合物中加入硫酸铝以降低pH。 然后加入碱金属硅酸盐，然后加入几种其它pH波动，以提供含有二氧化硅 - 氧化铝的混合物。 所得混合物用碱性溶液处理以提供沉淀固体，回收得到二氧化硅 - 氧化铝组合物，其含有30至70重量％的二氧化硅和70至30重量％的氧化铝。

公开(公告)号：US20170190981A1

公开(公告)日：2017-07-06

申请号：US15313755

申请日：2015-05-26

Applicant: SHELL OIL COMPANY

Inventor： Johannes Bernardus Wilhelmus MORSINK ,  Johannes TURFBOER ,  Rendert Jan WIERSMA ,  Ferry WINTER

IPC: C10G2/00 ,  C09K8/34 ,  C09K3/10 ,  C10G47/00

CPC classification number: C10G2/332 ,  C09K3/1006 ,  C09K8/035 ,  C09K8/34 ,  C09K8/36 ,  C10G2/30 ,  C10G47/00 ,  C10G2300/1022 ,  C10G2300/1055 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2400/06

Abstract: The present invention provides a Fischer-Tropsch gasoil fraction having: (a) an initial boiling point of at least 250° C.; (b) a final boiling point of at most 350° C.; (c) a kinematic viscosity at 25° C. according to ASTM D445 of from 4.0 to 4.6 cSt; and (d) a flash point according to ASTM D93 of at least 117° C. In another aspect the present invention provides a composition and the use of a Fischer-Tropsch gasoil fraction according to the invention.

公开(公告)号：US20170190979A1

公开(公告)日：2017-07-06

申请号：US15313711

申请日：2015-05-26

Applicant: SHELL OIL COMPANY

Inventor： Johannes Bernardus Wilhelmus MORSINK ,  Johannes TURFBOER ,  Rendert Jan WIERSMA ,  Ferry WINTER

IPC: C10G2/00 ,  C09D7/00 ,  C09D11/033

CPC classification number: C10G2/332 ,  C09D7/20 ,  C09D11/033 ,  C10G2300/1022 ,  C10G2300/1055 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2400/06 ,  C10L1/04 ,  C10M107/02 ,  C10M2205/173 ,  C10N2240/401

Abstract: The present invention provides a Fischer-Tropsch gasoil fraction having an initial boiling point of at least 200° C. and a final boiling point of at most 300° C. In another aspect the present invention provides a composition and the use of a Fisc- her-Tropsch gasoil fraction according to the invention.

公开(公告)号：US20130137913A1

公开(公告)日：2013-05-30

申请号：US13687556

申请日：2012-11-28

Applicant: SHELL OIL COMPANY

Inventor： Leslie Andrew CHEWTER ,  Marianne Hendrina Francisca KOX ,  Jeroen VAN WESTRENEN ,  Ferry WINTER

IPC: B01J29/90 ,  C07C4/06 ,  C07C1/20

CPC classification number: B01J29/90 ,  B01J21/16 ,  B01J29/40 ,  B01J29/7042 ,  B01J29/7046 ,  B01J29/83 ,  B01J29/85 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0036 ,  B01J38/02 ,  B01J38/12 ,  B01J38/60 ,  B01J2229/37 ,  B01J2229/42 ,  C07C1/20 ,  C07C2/864 ,  C07C2/865 ,  C07C4/06 ,  C07C2529/40 ,  C07C2529/70 ,  C07C2529/80 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/02

Abstract: The present invention relates to a process for the rejuvenation of a spent molecular sieve, comprising at least the steps of: (a) treating the spent molecular sieve catalyst with an aqueous solution comprising at least one acid to provide a rejuvenated molecular sieve catalyst and a spent aqueous solution; (b) removing spent aqueous solution from the rejuvenated molecular sieve catalyst to provide the rejuvenated molecular sieve catalyst.

Abstract translation: 本发明涉及一种用于再分散废分子筛的方法，该方法至少包括以下步骤：（a）用包含至少一种酸的水溶液处理废分子筛催化剂以提供复原的分子筛催化剂和 废水溶液; （b）从复原的分子筛催化剂中除去废水溶液以提供复原的分子筛催化剂。

公开(公告)号：US20170198224A1

公开(公告)日：2017-07-13

申请号：US15313772

申请日：2015-05-26

Applicant: SHELL OIL COMPANY

Inventor： Johannes Bernardus Wilhelmus MORSINK ,  Johannes TURFBOER ,  Rendert Jan WIERSMA ,  Ferry WINTER

IPC: C10G2/00 ,  C09K8/34 ,  C06B43/00 ,  C10G47/00

CPC classification number: C10G2/332 ,  C06B31/285 ,  C06B43/00 ,  C09K8/34 ,  C10G2/30 ,  C10G47/00 ,  C10G2300/1022 ,  C10G2300/1055 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2400/06 ,  C10L1/04

Abstract: The present invention provides a Fischer-Tropsch gasoil fraction having: (a) an initial boiling point of at least 220° C.; (b) a final boiling point of at most 360° C.; (c) a kinematic viscosity at 25° C. according to ASTM D445 of from 3.8 to 4.4 cSt; and (d) of a flash point according to ASTM D93 of at least 100° C. In another aspect the present invention provides a composition and the use of a Fischer-Tropsch gasoil fraction according to the invention.