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    Mayenite-type compound and process for production of same
    3.
    发明授权
    Mayenite-type compound and process for production of same 有权
    钙铝石型复合物及其制造方法

    公开(公告)号：US08454930B2

    公开(公告)日：2013-06-04

    申请号：US13034765

    申请日：2011-02-25

    申请人： Kazuhiro Ito ,  Satoru Watanabe ,  Naomichi Miyakawa ,  Setsuro Ito

    发明人： Kazuhiro Ito ,  Satoru Watanabe ,  Naomichi Miyakawa ,  Setsuro Ito

    IPC分类号： C01G3/00

    CPC分类号： C01F7/164 ,  C01F7/16 ,  C01F7/162 ,  C01F7/166 ,  C01P2002/50 ,  C01P2002/86 ,  C01P2006/40 ,  C01P2006/60 ,  H01J11/40

    摘要： The present invention relates to a mayenite-type compound in which a part of Ca of a mayenite-type compound containing Ca, Al and oxygen is substituted by at least one kind of an atom M selected from the group consisting of Be, Mg and Sr, in which the mayenite-type compound has an atom number ratio represented by M/(Ca+M) of from 0.01 to 0.50, and at least a part of free oxygen ions in a mayenite-type crystal structure are substituted by anions of an atom having electron affinity smaller than that of an oxygen atom.

    摘要翻译： 本发明涉及一种钙铝型化合物，其中含有Ca，Al和氧的钙铝石型化合物的Ca的一部分Ca被选自Be，Mg和Sr中的至少一种原子M所取代 ，其中钙铝石型化合物具有由M /（Ca + M）表示的原子数比为0.01至0.50，并且钙铝石型晶体结构中的至少一部分游离氧离子被阴离子所取代 具有小于氧原子的电子亲和力的原子。

    Method for preparing electroconductive mayenite type compound
    4.
    发明授权
    Method for preparing electroconductive mayenite type compound 有权
    导电钙铝石型化合物的制备方法

    公开(公告)号：US07670585B2

    公开(公告)日：2010-03-02

    申请号：US11948147

    申请日：2007-11-30

    申请人： Hideo Hosono ,  Katsuro Hayashi ,  Sung Wng Kim ,  Masahiro Hirano ,  Satoru Narushima ,  Setsuro Ito

    发明人： Hideo Hosono ,  Katsuro Hayashi ,  Sung Wng Kim ,  Masahiro Hirano ,  Satoru Narushima ,  Setsuro Ito

    IPC分类号： C01F7/16

    CPC分类号： C01F7/164 ,  C01F7/166 ,  C01P2002/50 ,  C01P2002/84 ,  C01P2006/40 ,  C01P2006/60 ,  H01B1/08

    摘要： Provided is a method for preparing an electroconductive mayenite type compound with good properties readily and stably at low cost without need for expensive facilities, a reaction at high temperature and for a long period of time, or complicated control of reaction.A method for preparing an electroconductive mayenite type compound comprises a step of subjecting a precursor to heat treatment, wherein the precursor contains Ca and/or Sr, and Al, a molar ratio of (a total of CaO and SrO:Al2O3) is from (12.6:6.4) to (11.7:7.3) as calculated as oxides, a total content of CaO, SrO and Al2O3 in the precursor is at least 50 mol %, and the precursor is a vitreous or crystalline material; and the method comprises a step of mixing the precursor with a reducing agent and performing the heat treatment of holding the mixture at 600-1,415° C. in an inert gas or vacuum atmosphere with an oxygen partial pressure of at most 10 Pa.

    摘要翻译： 本发明提供一种低成本地容易且稳定地制备具有良好性能的导电性钙铝石型化合物的方法，而不需要昂贵的设备，高温反应和长时间的反应或复杂的反应控制。 制备导电性钙铝石型化合物的方法包括使前体进行热处理的步骤，其中前体含有Ca和/或Sr，和Al，（CaO和SrO：Al 2 O 3的总和）的摩尔比为（ 12.6：6.4）至（11.7：7.3），前体中CaO，SrO和Al2O3的总含量为至少50摩尔％，前体为玻璃态或结晶性材料; 该方法包括将前体与还原剂混合并在氧分压至多10Pa的惰性气体或真空气氛中进行600-1,415℃保持混合物的热处理的步骤。

    Electroconductive 12ca0.7al203 and compound of same type, and method for preparation thereof
    5.
    发明申请
    Electroconductive 12ca0.7al203 and compound of same type, and method for preparation thereof 有权
    导电性12ca0.7al203和同型化合物及其制备方法

    公开(公告)号：US20060151311A1

    公开(公告)日：2006-07-13

    申请号：US10561968

    申请日：2004-02-12

    申请人： Hideo Hosono ,  Masahiro Hirano ,  Katsuro Hayashi ,  Isao Tanaka

    发明人： Hideo Hosono ,  Masahiro Hirano ,  Katsuro Hayashi ,  Isao Tanaka

    IPC分类号： C01B13/00

    CPC分类号： H01B1/08 ,  C01F7/164 ,  C01F7/166 ,  C01P2006/40 ,  C04B35/44 ,  C04B35/653 ,  C04B2235/3208 ,  C04B2235/3213 ,  C04B2235/604 ,  C04B2235/6587 ,  C04B2235/664 ,  C04B2235/787 ,  C04B2235/94

    摘要： In a solid solution system of Al2O3 and CAO or SrO, it has been difficult to obtain a material having a high electrical conductivity (>10−4 S·cm−) at room temperature. A compound is provided in which electrons at a high concentration are introduced into a 12CaO.7Al2O3 compound, a 12SrO.7Al2O3 compound, or a mixed crystal compound containing 12CaO.7Al2O3 and 12SrO.7Al2O3. The compound formed by substituting all the free oxygen ions with electrons is regarded as an electride compound in which [Ca24Al28O64]4+(4e−) or [Sr24Al28O64]4+(4e−) serves as a cation and electrons serve as anions. When a single crystal or a hydrostatic pressure press molded material of a fine powder thereof is held at approximately 700° C. in an alkaline metal vapor or an alkaline earth metal vapor, melt of a hydrostatic pressure press molded material of a powder is held at approximately 1,600° C. in a carbon crucible, followed by slow cooling for solidification, or a thin film of the compound held at approximately 600° C. is implanted with rare gas ions, a great number of the free oxygen ions can be substituted with electrons.

    摘要翻译： 在Al 2 N 3 O 3和CAO或SrO的固溶体系中，难以获得具有高导电性的材料（> 10 -4 S.cm ）在室温下。 提供了一种化合物，其中将高浓度的电子引入12CaO7Al 2 O 3 O 3化合物，12SrO·7H 2 O 2 或者含有12CaO.7Al 2 O 3 3和12SrO 7 Al 2 O 3的混合晶体化合物， SUB> 3 。 通过用电子代替全部游离氧离子而形成的化合物被认为是电化学化合物，其中[Ca 2 H 12 O 12 O 64] （4e-sup） - 或[Sr 2 O 2] 28 O 64] SUP + 4 +（4e - - ）用作阳离子，电子用作阴离子。 当在碱金属蒸气或碱土金属蒸气中将其细粉末的单晶或静水压成型材料保持在约700℃时，将粉末的流体静压加压成型材料的熔体保持在 在碳坩埚中约1600℃，然后缓慢冷却固化，或者在约600℃保持的化合物薄膜注入稀有气体离子，大量的游离氧离子可被 电子。

    METHOD FOR PREPARING ELECTROCONDUCTIVE MAYENITE TYPE COMPOUND
    8.
    发明申请
    METHOD FOR PREPARING ELECTROCONDUCTIVE MAYENITE TYPE COMPOUND 有权
    制备电极型MAYENITE型化合物的方法

    公开(公告)号：US20080095688A1

    公开(公告)日：2008-04-24

    申请号：US11948147

    申请日：2007-11-30

    申请人： Hideo Hosono ,  Katsuro Hayashi ,  Sung Kim ,  Masahiro Hirano ,  Satoru Narushima ,  Setsuro Ito

    发明人： Hideo Hosono ,  Katsuro Hayashi ,  Sung Kim ,  Masahiro Hirano ,  Satoru Narushima ,  Setsuro Ito

    IPC分类号： C01F17/00 ,  C01F11/02 ,  C01F7/00

    CPC分类号： C01F7/164 ,  C01F7/166 ,  C01P2002/50 ,  C01P2002/84 ,  C01P2006/40 ,  C01P2006/60 ,  H01B1/08

    摘要： Provided is a method for preparing an electroconductive mayenite type compound with good properties readily and stably at low cost without need for expensive facilities, a reaction at high temperature and for a long period of time, or complicated control of reaction. A method for preparing an electroconductive mayenite type compound comprises a step of subjecting a precursor to heat treatment, wherein the precursor contains Ca and/or Sr, and Al, a molar ratio of (a total of CaO and SrO:Al2O3) is from (12.6:6.4) to (11.7:7.3) as calculated as oxides, a total content of CaO, SrO and Al2O3 in the precursor is at least 50 mol %, and the precursor is a vitreous or crystalline material; and the method comprises a step of mixing the precursor with a reducing agent and performing the heat treatment of holding the mixture at 600-1,415° C. in an inert gas or vacuum atmosphere with an oxygen partial pressure of at most 10 Pa.

    摘要翻译： 本发明提供一种低成本地容易且稳定地制备具有良好性能的导电性钙铝石型化合物的方法，而不需要昂贵的设备，高温反应和长时间的反应或复杂的反应控制。 制备导电性钙铝石型化合物的方法包括以下步骤：将前体进行热处理，其中前体含有Ca和/或Sr，和Al，（CaO和SrO：Al 2的总和的摩尔比 （12.6:4.4）至（11.7:7.3）按氧化物计算，CaO，SrO和Al 2 O 2的总含量 前体中的3 <3>至少为50摩尔％，前体是玻璃状或结晶的材料; 该方法包括将前体与还原剂混合并在氧分压至多10Pa的惰性气体或真空气氛中进行600-1,415℃保持混合物的热处理的步骤。