VINYL ESTER/ETHYLENE COPOLYMER DISPERSIONS FOR USE IN ADHESIVE FORMULATIONS
    92.
    发明申请
    VINYL ESTER/ETHYLENE COPOLYMER DISPERSIONS FOR USE IN ADHESIVE FORMULATIONS 有权
    醋酸酯/乙烯共聚物用于胶粘剂配方的分散体

    公开(公告)号:US20120316282A1

    公开(公告)日:2012-12-13

    申请号:US13490514

    申请日:2012-06-07

    Abstract: An aqueous dispersion of a vinyl ester/ethylene copolymer is prepared by emulsion copolymerization of a monomer mixture comprising a vinyl ester, ethylene and a polyvinyl alcohol stabilizing system consisting essentially of (a) about 0.5 to about 3 wt % based on the total monomer weight of a first polyvinyl alcohol having a degree of hydrolysis of at least 98 mole % and (b) about 1 to about 4 wt % based on the total monomer weight of a second polyvinyl alcohol having a degree of hydrolysis of about 85 to about 90 mole % and a weight average molecular weight of at least 85,000 g/mol.

    Abstract translation: 乙烯基酯/乙烯共聚物的水分散体通过包含乙烯基酯,乙烯和聚乙烯醇稳定体系的单体混合物的乳液共聚来制备,所述单体混合物基本上由以下组成:(a)基于总单体重量计约0.5至约3重量% 的水解度为至少98摩尔%的第一聚乙烯醇和(b)约1至约4重量%,基于水解度为约85至约90摩尔的第二聚乙烯醇的总单体重量 %,重均分子量至少为85,000g / mol。

    Preparation method of quick oil-absorbent materials
    93.
    发明授权
    Preparation method of quick oil-absorbent materials 有权
    快速吸油材料的制备方法

    公开(公告)号:US08293852B2

    公开(公告)日:2012-10-23

    申请号:US12858763

    申请日:2010-08-18

    Abstract: This invention relates to an oil-absorbent polymer and the preparation method thereof, and disclosed a preparation method of quick oil absorbent material, which comprises: (1) Mixing and stirring well monomer A, vinyl monomer, initiator and vesicant to form a copolymerization system, wherein the amount of monomer A is in the range of approximately 10-50 wt %, the amount of vinyl monomer is in the range of approximately 48-88 wt %, the amount of initiator is in the range of approximately 0.01-5 wt %, the amount of vesicant is in the range of approximately 1-5 wt %; (2) And then immersing fiber carriers into the liquid of above-said copolymerization system to adsorb the liquid on the fiber carriers, then heating the fiber carriers under a temperature between 60˜80° C. for 1˜4 hours to synthesize polymers on the fiber carriers. The quick oil absent material is less dense than water, and has both high adsorption capacity and high adsorption rate, meanwhile it can be repeatedly used and the absorbed valuable oils can be regenerated to reduce cost effectively.

    Abstract translation: 本发明涉及一种吸油聚合物及其制备方法,并公开了一种快速吸油材料的制备方法,其包括:(1)将单体A,乙烯基单体,引发剂和发泡剂混合并搅拌形成共聚体系 ,其中单体A的量在约10-50重量%的范围内,乙烯基单体的量在约48-88重量%的范围内,引发剂的量在约0.01-5重量%的范围内 %,发泡剂的量在约1-5重量%的范围内; (2)然后将纤维载体浸入上述共聚系统的液体中以将液体吸附在纤维载体上,然后在60〜80℃的温度下加热纤维载体1〜4小时,合成聚合物 光纤载体。 快速缺油的材料比水密度低,吸附能力高,吸附率高,同时可以重复使用,可以再生吸收的有价值的油,以降低成本。

    Process for manufacturing composition of solvolysis product of ethylene-vinyl ester copolymer
    94.
    发明授权
    Process for manufacturing composition of solvolysis product of ethylene-vinyl ester copolymer 有权
    乙烯 - 乙烯基酯共聚物溶剂分解产物组成的方法

    公开(公告)号:US08283416B2

    公开(公告)日:2012-10-09

    申请号:US13188973

    申请日:2011-07-22

    Abstract: Processes for manufacturing a composition of a solvolysis product of an ethylene-vinyl ester copolymer, which comprises: conducting solvolysis of an ethylene-vinyl ester copolymer (A′) and a modified ethylene-vinyl ester copolymer (B′) comprising a unit derived from a compound represented by the general formula (2) in one system to manufacture the composition of a solvolysis product of an ethylene-vinyl ester copolymer comprising a solvolysis product (A) of the ethylene-vinyl ester copolymer and a solvolysis product (B) of the modified ethylene-vinyl ester copolymer comprising a unit represented by the general formula (1), wherein a ratio of an ethylene content (B′)/(A′) of copolymer (A′) and copolymer (B′) in conducting solvolysis is 1 or more, and a blending ratio (B′)/(A′) of the ethylene-vinyl ester copolymer (A′) and the modified ethylene-vinyl ester copolymer (B′) is from 50/50 to 1/99 by weight:

    Abstract translation: 制造乙烯 - 乙烯基酯共聚物的溶剂分解产物组合物的方法,其包括:进行乙烯 - 乙烯基酯共聚物(A')和改性乙烯 - 乙烯基酯共聚物(B')的溶剂分解,所述乙烯 - 乙烯基酯共聚物(B')包含衍生自 一种制备乙烯 - 乙烯基酯共聚物的溶剂分解产物组合物的方法,该乙烯 - 乙烯基酯共聚物包含乙烯 - 乙烯基酯共聚物的溶剂分解产物(A)和溶剂分解产物(B)的一种体系中由通式(2)表示的化合物 所述改性乙烯 - 乙烯基酯共聚物包括由通式(1)表示的单元,其中在导电溶剂分解中共聚物(A')和共聚物(B')的乙烯含量(B')/(A')的比例 为1以上,乙烯 - 乙烯基酯共聚物(A')和改性乙烯 - 乙烯基酯共聚物(B')的配合比(B')/(A')为50/50〜1/99 重量:

    Polymerization Process to Make Low Density Polyethylene
    95.
    发明申请
    Polymerization Process to Make Low Density Polyethylene 有权
    制备低密度聚乙烯的聚合方法

    公开(公告)号:US20120252990A1

    公开(公告)日:2012-10-04

    申请号:US13515028

    申请日:2010-12-14

    Abstract: A high pressure polymerization process to form an ethylene-based polymer comprises the steps of: A. Injecting a first feed comprising ethylene and optionally a chain transfer agent system (CTA system) into a first autoclave reactor zone operating at polymerization conditions to produce a first zone reaction product, the CTA system of the first reactor zone having a transfer activity Z1; and B. (1) Transferring at least part of the first zone reaction product to a second reactor zone selected from a second autoclave reactor zone or a tubular reactor zone and operating at polymerization conditions, and, optionally, (2) freshly injecting a second feed into the second reactor zone to produce a second zone reaction product, with the proviso that the second reactor zone contains a CTA system having a transfer activity Z2; and with the proviso that the ratio of Z1/Z2 is less than 1.

    Abstract translation: 形成乙烯基聚合物的高压聚合方法包括以下步骤:A.将包含乙烯和任选的链转移剂体系(CTA体系)的第一种进料注入到在聚合条件下操作的第一高压釜反应器区中,以产生第一 区域反应产物,具有转移活性Z1的第一反应器区域的CTA体系; (1)将至少部分第一区反应产物转移到选自第二高压釜反应器区或管状反应器区并在聚合条件下操作的第二反应器区,以及任选地,(2)新鲜地注入第二个 进料到第二反应器区以产生第二区反应产物,条件是第二反应器区含有具有转移活性Z 2的CTA体系; 并且条件是Z1 / Z2的比率小于1。

    VINYL CHLORIDE-BASED RESIN LATEXES, PROCESSES FOR PRODUCING THE SAME, AND THERMAL TRANSFER IMAGE-RECEIVING SHEET OBTAINED USING THE SAME
    96.
    发明申请
    VINYL CHLORIDE-BASED RESIN LATEXES, PROCESSES FOR PRODUCING THE SAME, AND THERMAL TRANSFER IMAGE-RECEIVING SHEET OBTAINED USING THE SAME 有权
    基于氯乙烯的树脂树脂,其制备方法和使用其获得的热转印图像接收片

    公开(公告)号:US20120244297A1

    公开(公告)日:2012-09-27

    申请号:US13514776

    申请日:2010-12-07

    Abstract: A vinyl chloride-based resin latex which froths little when unreacted monomer remaining in the latex are recovered under heat and reduced-pressure conditions, and a thermal transfer image-receiving sheet which has satisfactory water resistance, does not yellow during storage, and gives images having excellent durability and light resistance. The invention provides a vinyl chloride-based resin latex contains a copolymer containing a vinyl chloride and an epoxy-group-containing vinyl or contains vinyl chloride, an epoxy-group-containing vinyl, and a carboxylic acid vinyl ester, wherein a content of the epoxy-group-containing vinyl is 0.1% by weight or more but less than 3% by weight, and wherein the latex contains no surfactant, and has a solid concentration of 25% by weight or more; a process for producing the latex; and a thermal transfer image-receiving sheet obtained using the latex.

    Abstract translation: 在热和减压条件下回收保留在胶乳中的未反应单体的少量氯乙烯系树脂胶乳,以及耐热性良好的热转印图像接收片材在储存期间不变黄,并且给出图像 具有优异的耐久性和耐光性。 本发明提供一种氯乙烯系树脂胶乳,其含有含有氯乙烯和含环氧基的乙烯基或含有氯乙烯的共聚物,含环氧基的乙烯基和羧酸乙烯基酯,其中, 含有环氧基的乙烯基为0.1重量%以上且小于3重量%,其中,所述胶乳不含表面活性剂,固体成分浓度为25重量%以上。 制备胶乳的方法; 和使用该胶乳获得的热转印图像接收片材。

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