Abstract:
A fuel cell oxidation reduction reaction catalyst comprising a carbon substrate, an amorphous metal oxide intermediate layer on the substrate, and an intertwined matrix of platinum and elemental niobium arranged to form a surface metal layer covering the intermediate layer such that upon oxidation, the niobium binds with oxygen resulting in strengthened bonds between the platinum and the intermediate layer.
Abstract:
Methods and systems are provided for adjusting a rate of change in a reference voltage of an oxygen sensor. In one example, a method may include gradually increasing a reference voltage of an oxygen sensor from a lower first voltage to a higher second voltage at a ramp rate. The ramp rate may be based on engine operating conditions.
Abstract:
Methods and systems are provided for reducing blackening of an oxygen sensor due to voltage excursions into an over-potential region. Before transitioning the sensor from a lower voltage to an upper voltage during variable voltage operation, an operating temperature of the sensor is reduced via adjustments to a sensor heater setting. The reduction in temperature increases the range of temperatures available to the sensor before the over-potential region is entered.
Abstract:
Methods and systems are provided for detecting a temperature of an engine fuel rail at a plurality of locations along the engine fuel rail. In one example, a method may include detecting temperatures along the engine fuel rail with a plurality of metal film thermocouples adhered to the engine fuel rail and arranged proximate to engine fuel injectors, and adjusting fuel injector operation and/or fuel rail pressure in response to the detected fuel rail temperatures.
Abstract:
Methods and systems are provided for estimating an exhaust air/fuel ratio based on outputs from an exhaust oxygen sensor. In one example, a method may include adjusting engine operation based on an air-fuel ratio estimated based on an output of the exhaust oxygen sensor and a learned correction factor. For example, the oxygen sensor may operate in a variable voltage mode in which a reference voltage of the oxygen sensor may be adjusted between a lower first voltage and a higher second voltage, and the learned correction factor is based on the second voltage.
Abstract:
Methods and systems are provided for detecting a temperature of an engine fuel rail at a plurality of locations along the engine fuel rail. In one example, a method may include detecting temperatures along the engine fuel rail with a plurality of metal film thermocouples adhered to the engine fuel rail and arranged proximate to engine fuel injectors, and adjusting fuel injector operation and/or fuel rail pressure in response to the detected fuel rail temperatures.
Abstract:
Methods and systems are provided for adjusting heater power of an oxygen sensor. In one example, a method for an engine includes adjusting heater power of a heating element of the oxygen sensor when the heater power increases by a threshold amount. The method includes subsequently increasing heater power back to a baseline power level responsive to a temperature of the heating element.
Abstract:
Methods and systems are provided for adjusting a reference voltage for an intake manifold oxygen sensor based on ingestion of hydrocarbons from a fuel system canister and/or an engine crankcase. During conditions when purge or crankcase ventilation hydrocarbons are ingested in the intake aircharge, the intake oxygen sensor is transitioned from operating at a lower reference voltage to a higher reference voltage where the effects of the ingested hydrocarbons on the sensor output are nullified. An EGR dilution of the intake aircharge is estimated based on the output of the sensor at the higher reference voltage while an amount of hydrocarbons ingested is estimated based on a difference between sensor outputs at the higher and lower reference voltages.
Abstract:
Methods and systems are provided for estimating an engine exhaust pressure based on outputs from an exhaust oxygen sensor. In one example, a method may include estimating an exhaust pressure of exhaust gas flowing through an engine exhaust passage based on a difference between a first output of an oxygen sensor disposed in the exhaust passage and a second output of the oxygen sensor and then adjusting engine operation based on the estimated exhaust pressure. As one example, both the first and second outputs may be taken while operating the sensor in a variable voltage mode, after increasing a reference voltage of the oxygen sensor from a lower, first voltage to a higher, second voltage.
Abstract:
Methods and systems are provided for adjusting a reference voltage for an intake manifold oxygen sensor based on ingestion of hydrocarbons from a fuel system canister and/or an engine crankcase. During conditions when purge or crankcase ventilation hydrocarbons are ingested in the intake aircharge, the intake oxygen sensor is transitioned from operating at a lower reference voltage to a higher reference voltage where the effects of the ingested hydrocarbons on the sensor output are nullified. An EGR dilution of the intake aircharge is estimated based on the output of the sensor at the higher reference voltage while an amount of hydrocarbons ingested is estimated based on a difference between sensor outputs at the higher and lower reference voltages.