Reticulate polymers based on oligourethanacrylates and method for their
manufacture
    101.
    发明授权
    Reticulate polymers based on oligourethanacrylates and method for their manufacture 失效
    基于低聚氨酯丙烯酸酯的网状聚合物及其制造方法

    公开(公告)号:US4258164A

    公开(公告)日:1981-03-24

    申请号:US40888

    申请日:1979-05-21

    摘要: A method for preparing olegourethanacrylates having the general formula ##STR1## where ##STR2## is a radical of a telogen; X is H, CH.sub.3 or a halide;R is a radical of glycol, bis-phenol, amino alcohol;R' is a radical of polyamine;R" is a radical of polyol;R" is R' if the telogen contains ##STR3## group; R"' is R" if telogen contains - N(Y)H group;n is the number characterizing the degree of polycondensation of the oligourethanacrylate equal to zero, unity, or a whole number greater than unity, consisting in carrying out a reaction of a non-equlibrium polycondensation of chloroformiates of polyols with polyamines and telogens, which are chloroformiates of monoesters of alkyleneglycols and acids of the acrylic series, chloroformiates of monoesters of bis-phenols and acids of the acrylic series, monoaminoalkyl esters of acids of the acrylic series, N-substituted monoaminoalkyl esters of acids of acrylic series, in the medium of organic solvents or in a system of an water-organic solvent, in the presence of acceptors of hydrogen chloride which is liberated in the reaction.

    摘要翻译: 一种制备具有通式 + TR 的烯基聚丙烯酸酯的方法,其中是一个开始的基因; X是H,CH 3或卤素; R是乙二醇,双酚,氨基醇; R'是多胺的基团; R“是多元醇的基团; 如果前辈包含组,R“是R' 如果休止期包含-N(Y)H基团,则R“'是R” n是表示低聚氨基甲酸丙酯的缩聚度等于零,单数或大于1的整数的数字,其包括进行多元醇的氯甲酸酯与多胺和前体的非均衡缩聚反应,所述多胺和前体是氯甲酸酯 的亚烷基二醇和丙烯酸系列酸的单酯,双酚的单酯和丙烯酸系列的酸的氯甲酸酯,丙烯酸系的酸的单氨基烷基酯,丙烯酸系的酸的N-取代的单氨基烷基酯,在有机介质中 溶剂或在水 - 有机溶剂的体系中,在反应中释放的氯化氢的受体存在下进行。

    PREPARATION OF N-VINYL CARBOXAMIDES IN A SERIES OF REACTOR UNITS

    公开(公告)号:US20180208691A1

    公开(公告)日:2018-07-26

    申请号:US15746462

    申请日:2016-07-19

    申请人: BASF SE

    摘要: Disclosed herein is a process for producing polymers of an N-vinyl carboxamide, including the steps of flowing a reaction mixture containing an aqueous liquid containing at least one polymerisation initiator, N-vinyl carboxamide monomer or a monomer mixture containing N-vinyl carboxamide into a reactor system, and polymerising the monomer or monomer mixture to produce the polymer of a N-vinyl carboxamide. The polymers resulting therefrom may be hydrolysed to provide polymers containing vinyl amine units. Also disclosed herein is an apparatus suitable for producing the polymers.

    LONG-CHAIN BRANCHED POLYMERS AND PRODUCTION PROCESSES

    公开(公告)号:US20170145127A1

    公开(公告)日:2017-05-25

    申请号:US15426863

    申请日:2017-02-07

    IPC分类号: C08F126/02 C08F110/06

    摘要: This invention relates to a process for forming a long-chain branched polymer and a long-chain branched polymer resulting from the process. The process comprises reacting (a) a polyolefin base polymer with (b) a coupling agent comprising a polymeric coupling agent, optionally blended with a molecular coupling agent, the polymeric coupling agent being a modified polyolefin having a reactive coupling group at one or more terminal ends of the modified polyolefin chain, to couple the polyolefin base polymer (a) with the coupling agent (b) to form a long-chain branched polymer having a long-chain branching and/or higher surface energy relative to the polyolefin base polymer.