公开(公告)号：US20180079835A1

公开(公告)日：2018-03-22

申请号：US15703346

申请日：2017-09-13

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Wei Gao

IPC: C08F2/24 ,  C08F2/00 ,  C08F230/02 ,  C08F220/18 ,  C08F220/06 ,  C08F212/36 ,  C08K3/22 ,  C08L33/04 ,  C08L33/02 ,  C09D143/02

CPC classification number: C08F2/24 ,  C08F2/001 ,  C08F212/36 ,  C08F220/06 ,  C08F220/18 ,  C08F230/02 ,  C08F265/06 ,  C08F285/00 ,  C08K3/22 ,  C08K2003/2241 ,  C08L33/02 ,  C08L33/04 ,  C08L51/003 ,  C08L2201/54 ,  C08L2207/53 ,  C09D143/02 ,  C08F2220/1825 ,  C08F2220/1808 ,  C08F220/14 ,  C08F2220/283 ,  C08F220/34 ,  C08F212/14

Abstract: The present invention relates to an in situ preparation of a redox initiated bimorphological aqueous dispersion of first polymer particles with protuberating phosphorus acid cores and second polymer particles without protuberating cores. The method provides a more efficient way of making compositions for pigmented coating formulations.

公开(公告)号：US09828509B1

公开(公告)日：2017-11-28

申请号：US15196099

申请日：2016-06-29

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  David G. Kelly ,  Pu Luo ,  Yogesh Tiwary

IPC: C09D7/12 ,  C09D133/06 ,  C08K3/22 ,  C08K5/25

CPC classification number: C09D133/06 ,  C08K3/22 ,  C08K5/25 ,  C08K9/10 ,  C08K2003/2241 ,  C09D5/028 ,  C09D7/62

Abstract: The present invention is a composition comprising a) an aqueous dispersion of TiO2 particles encapsulated with an encapsulating acrylic or styrene-acrylic polymer comprising from structural units of diacetone acrylamide; and b) adipic acid dihydrazide. The composition is useful in coatings applications and shows a surprising improvement in gloss over compositions that do not include diacetone acrylamide functionalized encapsulating polymer and adipic acid dihydrazide.

公开(公告)号：US20170174905A1

公开(公告)日：2017-06-22

申请号：US15373609

申请日：2016-12-09

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Jocelyn Gruver ,  Danniebelle Haase ,  Ann R. Hermes ,  Wenqin Wang

IPC: C09D5/02 ,  C09D133/08

CPC classification number: C09D5/027 ,  C08F265/06 ,  C08K5/25 ,  C09D5/022 ,  C09D133/08 ,  C09D151/003 ,  C08L51/003 ,  C08F220/06 ,  C08F2220/1825 ,  C08F220/14 ,  C08F230/02 ,  C08F220/58

Abstract: The present invention provides aqueous compositions for use in coating wood joinery, especially for exterior use, comprising (a) one or more dihydrazide compounds in a total amount of from 0.5 to 4 wt. %, based on the total weight of composition solids and (b) of one or more aqueous multistage emulsion copolymers containing, as (i) a first stage, an emulsion copolymer having a glass transition temperature (Tg) via differential scanning calorimetry (DSC) of from −50 to 30° C., and containing, in copolymerized form one or more monoethylenically unsaturated phosphorous acid monomers and, one or more keto group containing amide monomers, and, as (ii) a second stage, an emulsion copolymer having a DSC Tg of at least 50° C. to 125° C., wherein the weight ratio of (i) the first stage to (ii) the second stage, based on copolymer solids, ranging from 50:50 to 90:10.

公开(公告)号：US20170152379A1

公开(公告)日：2017-06-01

申请号：US15320519

申请日：2015-06-10

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Michael D. Kelly

IPC: C08L61/24 ,  D06M15/432 ,  D04H1/587 ,  D04H1/64 ,  C08F220/18 ,  D04H1/4218

CPC classification number: C08L61/24 ,  C08F2/001 ,  C08F2/24 ,  C08F2/26 ,  C08F30/02 ,  C08F36/20 ,  C08F220/18 ,  C08F290/00 ,  C08F2220/1825 ,  C08L43/02 ,  C08L61/06 ,  C08L2201/52 ,  C08L2201/54 ,  C09J161/24 ,  D04H1/4218 ,  D04H1/587 ,  D04H1/64 ,  D06M15/432 ,  D10B2101/06 ,  C08F212/08 ,  C08F220/06 ,  C08F212/14 ,  C08F2230/085

Abstract: The present invention provides polymer modified aqueous urea formaldehyde resin (UF resin) binder compositions useful in making a treated glass mat, e.g., for roofing shingles, wherein the polymer modifier is an multistage aqueous emulsion acorn copolymer comprising one protuberant polymer stage containing phosphorous acid groups and one or more other polymer stage comprising an addition copolymer incompatible with the protuberant polymer stage, wherein the multistage aqueous emulsion copolymer has a measured Tg of from −60 to 25° C., or, preferably from 31 30 to 12° C. and, further wherein the weight ratio of the total of monomers used to make the one or more other polymer stage to the total amount of monomers used to make the protuberant polymer stage ranges from 3:1 to 50:1, or, preferably, from 3:1 to 30:1 or, more preferably, from 3:1 to 20:1, or, even more preferably, from 8:1 to 12:1.

公开(公告)号：US20170121517A1

公开(公告)日：2017-05-04

申请号：US15338530

申请日：2016-10-31

Applicant: Rohm and Haas Company

Inventor： Kebede Beshah ,  James C. Bohling ,  Pu Luo

IPC: C08L31/04 ,  C08F218/08

CPC classification number: C08L31/04 ,  C08F218/08 ,  C08F230/02 ,  C08L2201/52 ,  C08L2205/025 ,  C09D131/04 ,  C08K5/37 ,  C08K3/32

Abstract: The present invention relates to a process for preparing an aqueous dispersion of a vinyl acetate polymer comprising the step of polymerizing vinyl acetate under emulsion polymerization conditions in the presence of a chain transfer agent which is a hypophosphite salt or X—R1—SH, where R1 is a C1-C4 alkyl group and X is sulfonate, hydroxyl, sulfate, phosphate, phosphonate, carboxylic acid or a salt thereof, or C1-C3-alkyl carboxylate. The process provides a way of lowering the viscosity of the vinyl acetate polymer at a given solids content.

公开(公告)号：US20160340539A1

公开(公告)日：2016-11-24

申请号：US15156390

申请日：2016-05-17

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  David G. Kelly ,  Pu Luo ,  Yogesh Tiwary

IPC: C09D133/08

CPC classification number: C09D133/08 ,  C08F220/18 ,  C09C1/3676 ,  C09D4/00 ,  C08F220/06

Abstract: The present invention relates to a process for preparing an aqueous dispersion of polymer encapsulated TiO2 particles, comprising a multistage polymerization steps that includes a relatively large amount of low Tg first monomers and a relatively small amount of high Tg second monomers that comprise a relatively high concentration of an acid monomer. The dispersion of encapsulated TiO2 particles shows significantly improved freeze-thaw stability as compared with prior art processes that do not include staging with the second monomers described herein.

Abstract translation: 本发明涉及一种制备聚合物包封的TiO 2颗粒的水分散体的方法，其包括多阶段聚合步骤，其包括相对大量的低Tg第一单体和相对少量的高Tg第二单体，其包含相对高的浓度 的酸单体。 与现有技术的方法相比，包封的TiO 2颗粒的分散体显示出显着改善的冻融稳定性，其不包括用本文所述的第二单体进行分级。

公开(公告)号：US20160177081A1

公开(公告)日：2016-06-23

申请号：US14969087

申请日：2015-12-15

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Kebede Beshah ,  Pu Luo

IPC: C08L31/04

CPC classification number: C08L31/04 ,  C08F218/08 ,  C08F2220/1825 ,  C08F230/02

Abstract: The present invention relates to a process for preparing an aqueous dispersion of a vinyl acetate polymer comprising the step of polymerizing vinyl acetate under emulsion polymerization conditions in the presence of a chain transfer agent which is a hypophosphite salt or X—R1—SH, where R1 is a C1-C4 alkyl group and X is sulfonate, hydroxyl, sulfate, phosphate, phosphonate, carboxylic acid or a salt thereof, or C1-C3-alkyl carboxylate. The process provides a way of lowering the viscosity of the vinyl acetate polymer at a given solids content.

Abstract translation: 本发明涉及一种制备乙酸乙烯酯聚合物的水性分散体的方法，其包括在乳液聚合条件下，在链转移剂（次磷酸盐或X-R1-SH）的存在下聚合乙酸乙烯酯的步骤，其中R 1 是C 1 -C 4烷基，X是磺酸盐，羟基，硫酸盐，磷酸盐，膦酸盐，羧酸或其盐，或C 1 -C 3烷基羧酸盐。 该方法提供了一种降低乙酸乙烯酯聚合物在给定固体含量下的粘度的方法。

公开(公告)号：US09273221B2

公开(公告)日：2016-03-01

申请号：US14169504

申请日：2014-01-31

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Beth Cooper ,  Wei Gao ,  Linus W. Linder ,  Alvin M. Maurice

IPC: C09D133/10 ,  C08F220/14 ,  C09D133/14

CPC classification number: C09D133/10 ,  C08F220/14 ,  C09D133/14 ,  C08F220/06 ,  C08F230/02 ,  C08F2220/1825 ,  C08F2220/283

Abstract: The present invention relates to a process comprising contacting methyl methacrylate or styrene; a C1-C10-alkyl acrylate; and a polymerizable carboxylic acid monomer with a stable aqueous dispersion of first polymer particles, under emulsion polymerization conditions, to form a stable aqueous dispersion of second polymer particles. The first polymer particles have a Tg in the range of from −30° C. to 30° C., and the monomers have a calculated Tg in the range of 50° C. to 120° C. The present invention also relates to the dispersion of second polymer particles, which is useful as a binder to improve freeze-thaw stability in a coatings formulation.

Abstract translation: 本发明涉及一种使甲基丙烯酸甲酯或苯乙烯接触的方法; 丙烯酸C1-C10烷基酯; 和具有稳定的第一聚合物颗粒的水分散体的可聚合羧酸单体，在乳液聚合条件下，形成稳定的第二聚合物颗粒的水分散体。 第一聚合物颗粒的Tg在-30℃至30℃的范围内，单体的计算Tg在50℃至120℃的范围内。本发明还涉及 第二聚合物颗粒的分散体，其可用作粘合剂以改善涂料配方中的冻融稳定性。

公开(公告)号：US20150175838A1

公开(公告)日：2015-06-25

申请号：US14565914

申请日：2014-12-10

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Kevin J. Henderson

IPC: C09D135/02

CPC classification number: C09D135/02 ,  C08K2003/2241 ,  C09D1/00 ,  C09D4/00 ,  C09D5/00 ,  C09D133/14

Abstract: The present invention is a composition comprising a) a stable aqueous dispersion of polymer particles functionalized with structural units of itaconic acid or a salt thereof and; b) a water-soluble polymer functionalized with structural units of a sulfonic acid monomer or a salt thereof as well as a method comprising mixing the stable aqueous dispersion of the itaconic acid functionalized polymer particles with the sulfonic acid functionalized polymer, and TiO2. The composition of the present invention is useful a coatings formulation that provides surprisingly good hiding.

Abstract translation: 本发明是一种组合物，其包含：a）用衣康酸或其盐的结构单元官能化的聚合物颗粒的稳定水性分散体; b）用磺酸单体或其盐的结构单元官能化的水溶性聚合物以及包含将所述衣康酸官能化聚合物颗粒的稳定水分散体与磺酸官能化聚合物和TiO 2混合的方法。 本发明的组合物可用于提供惊人的良好隐藏的涂料制剂。

公开(公告)号：US20140329957A1

公开(公告)日：2014-11-06

申请号：US14365673

申请日：2012-12-17

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Catherine A. Finegan

IPC: C08L33/08 ,  C08K3/22

CPC classification number: C08L43/02 ,  C08F220/18 ,  C08F228/00 ,  C08F230/02 ,  C08F265/04 ,  C08F275/00 ,  C08K3/22 ,  C08K5/42 ,  C08K5/521 ,  C08K2003/2241 ,  C08L33/08 ,  C08L2201/54 ,  C09D143/02 ,  C08F212/14 ,  C08F220/34

Abstract: The present invention is a process for preparing a multistage polymer by contacting under emulsion polymerization conditions an acrylic monomer, a sulfur acid monomer, and a phosphorous acid monomer as described herein. The present invention is also a composition comprising a nonionic surfactant and a stable aqueous dispersion of polymer particles comprising structural units of butyl acrylate, methyl methacrylate, a sodium vinylbenzenesulfonate, and phosphoethyl methacrylate; wherein the polymer particles have a Tg of less than 10° C. The composition of the present invention is useful as a binder for coatings compositions.

Abstract translation: 本发明是一种通过在乳液聚合条件下与本文所述的丙烯酸类单体，硫酸单体和亚磷酸单体接触来制备多级聚合物的方法。 本发明还是一种包含非离子表面活性剂和稳定的聚合物颗粒的水性分散体的组合物，其包含丙烯酸丁酯，甲基丙烯酸甲酯，乙烯基苯磺酸钠和甲基丙烯酸磷酸乙酯的结构单元; 其中聚合物颗粒具有小于10℃的Tg。本发明的组合物可用作涂料组合物的粘合剂。