Method of Fabricating Medium-High Temperature CO2 Sorbents Made of Alkali Metal Promoted Calcium Aluminate Carbonates
    141.
    发明申请
    Method of Fabricating Medium-High Temperature CO2 Sorbents Made of Alkali Metal Promoted Calcium Aluminate Carbonates 失效
    由碱金属促进碳酸铝碳酸盐制成的中高温二氧化碳吸附剂的制备方法

    公开(公告)号:US20130015399A1

    公开(公告)日:2013-01-17

    申请号:US13179699

    申请日:2011-07-11

    Abstract: A dry material is synthesized by alkali metal (Li, Na and K) promoted calcium aluminate carbonates to obtain a CO2 sorbent used at a temperature higher than 600 Celsius degrees (° C.). The key composition of the sorbents is 52˜69% of CaO, which is beneficial to capture CO2 at 400˜800° C. A breakthrough result is achieved by using this sintering-resistant sorbent, which includes the features of 50% initial carbonation capacity and 20 folds CO2 capturing performance maintained after 40˜60 hours. Besides, alkali bearing material provides good velocity in CO2 capturing/releasing cycles; for example, by using Li and K series sorbents, 40 hours is required for 40 cycles only.

    Abstract translation: 通过碱金属(Li,Na和K)促进的碳酸钙铝合成干燥材料,以获得在高于600摄氏度(℃)的温度下使用的CO 2吸附剂。 吸附剂的关键组成为CaO的52〜69%,有利于在400〜800℃下捕获CO2。通过使用该耐烧结吸附剂,实现了突破性的成果,其包括50%初始碳酸化能力的特征 并在40〜60小时后保持20倍的CO2捕获性能。 此外,碱性轴承材料在CO2捕集/释放循环中提供良好的速度; 例如,通过使用Li和K系列吸附剂,只需要40个小时才能进行40个循环。

    Microporous aluminophosphate molecular sieve membranes for highly selective separations
    144.
    发明授权
    Microporous aluminophosphate molecular sieve membranes for highly selective separations 有权
    用于高选择性分离的微孔磷酸铝分子筛膜

    公开(公告)号:US08262779B2

    公开(公告)日:2012-09-11

    申请号:US12857308

    申请日:2010-08-16

    Abstract: The present invention discloses microporous aluminophosphate (AlPO4) molecular sieve membranes and methods for making and using the same. The microporous AlPO4 molecular sieve membranes, particularly small pore microporous AlPO-14 and AlPO-18 molecular sieve membranes, are prepared by three different methods, including in-situ crystallization of a layer of AlPO4 molecular sieve crystals on a porous membrane support, coating a layer of polymer-bound AlPO4 molecular sieve crystals on a porous membrane support, and a seeding method by in-situ crystallization of a continuous second layer of AlPO4 molecular sieve crystals on a seed layer of AlPO4 molecular sieve crystals supported on a porous membrane support. The microporous AlPO4 molecular sieve membranes have superior thermal and chemical stability, good erosion resistance, high CO2 plasticization resistance, and significantly improved selectivity over polymer membranes for gas and liquid separations, including carbon dioxide/methane (CO2/CH4), carbon dioxide/nitrogen (CO2/N2), and hydrogen/methane (H2/CH4) separations.

    Abstract translation: 本发明公开了微孔磷酸铝(AlPO4)分子筛膜及其制造和使用方法。 微孔AlPO 4分子筛膜,特别是小孔微孔AlPO-14和AlPO-18分子筛膜通过三种不同的方法制备,包括在多孔膜载体上原位结晶一层AlPO 4分子筛晶体, 多孔膜载体上的聚合物结合的AlPO 4分子筛晶体层,以及通过在多孔膜载体上负载的AlPO 4分子筛晶体的种子层上原位结晶连续的第二层AlPO 4分子筛晶体的接种方法。 微孔AlPO4分子筛膜具有优异的耐热和化学稳定性,良好的耐侵蚀性,高的二氧化碳增塑性,并且对于气体和液体分离,包括二氧化碳/甲烷(CO2 / CH4),二氧化碳/氮气 (CO2 / N2)和氢/甲烷(H2 / CH4)分离。

    Miniature oxygen concentrators and methods
    145.
    发明授权
    Miniature oxygen concentrators and methods 有权
    微型氧气浓缩器和方法

    公开(公告)号:US08226745B2

    公开(公告)日:2012-07-24

    申请号:US12769283

    申请日:2010-04-28

    Abstract: Provided herein are new compact and miniature oxygen concentrator apparatus, as well as methods incorporating use of the apparatus. The apparatus and methods utilize selected cycle times, adsorbent specifications and novel conditions to produce a fast Pressure Swing Adsorption (“PSA”) system. The oxygen concentrator apparatus and methods herein have significant utility in the fields of biotechnology, engineering, and medicine. A particularly advantageous use of this invention is as a “snap on” portable oxygen concentrator, where piped compressed air is already available such as in civil and military hospitals, ambulances, air craft cabins, mobile fish tanks, etc. Those embodiments eliminate the need for dedicated moving machinery (blower, compressor, vacuum pump) normally associated with a conventional PSA oxygen concentrator.

    Abstract translation: 本文提供了新的紧凑型和微型氧气浓缩装置,以及结合使用该装置的方法。 该设备和方法利用选择的循环时间,吸附剂规格和新条件来产生快速压力摆动吸附(“PSA”)系统。 本发明的氧气浓缩装置和方法在生物技术,工程,医药领域具有重要的实用价值。 本发明的特别有利的用途是作为“快速”便携式氧气浓缩器,其中管道压缩空气已经可用,例如在民用和军用医院,救护车,飞机舱,移动鱼缸等中。这些实施例消除了需要 通常与常规PSA氧浓缩器相关联的专用移动机械(鼓风机,压缩机,真空泵)。

    Obtaining multimetallic oxides derived from hydrotalcite type compounds
    147.
    发明授权
    Obtaining multimetallic oxides derived from hydrotalcite type compounds 有权
    获得源自水滑石型化合物的多金属氧化物

    公开(公告)号:US08211395B2

    公开(公告)日:2012-07-03

    申请号:US13106015

    申请日:2011-05-12

    Abstract: A procedure for obtaining mixed multimetallic oxides derived from hydrotalcite type compounds, characterized in that the laminar metallic hydroxides obtained are constituted by three or four metallic cations, forming part of the sheets of the hydrotalcite type material represented by the formula: [M(II)1−x−y−zM(II)′xM(III)yM(III)′z(OH)2](An−y+z/n).mH2O. by a process comprising: (1) preparing an aqueous or organic solution containing three or more cations; (2) preparing an alkaline solution; (3) slowly combining solutions (1) and (2) to cause the co-precipitation of the cations in the form of hydroxides; (4) washing the precipitate containing the hydrotalcites with water, until removal of the non-precipitated ions; (5) drying; and (6) calcining the hydrotalcites.

    Abstract translation: 一种获得由水滑石型化合物衍生的混合多金属氧化物的方法,其特征在于所得到的层状金属氢氧化物由三种或四种金属阳离子构成,形成由下式表示的水滑石型材料片材的一部分:[M(II) 1-x-y-zM(II)'xM(III)yM(III)'z(OH)2](An-y + z / n) 通过一种方法包括:(1)制备含有三种或更多种阳离子的水溶液或有机溶液; (2)制备碱性溶液; (3)缓慢地混合溶液(1)和(2)以使阳离子以氢氧化物的形式共沉淀; (4)用水洗涤含有水滑石的沉淀物,直到除去非沉淀离子; (5)干燥; 和(6)煅烧水滑石。

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