Peroxyoxalates derived from hydroxy-hydroperoxides
    11.
    发明授权
    Peroxyoxalates derived from hydroxy-hydroperoxides 失效
    衍生自羟基氢过氧化物的过氧草酸盐

    公开(公告)号:US5981787A

    公开(公告)日:1999-11-09

    申请号:US946751

    申请日:1997-10-10

    CPC分类号: C07C409/38

    摘要: Novel peroxyoxalate compositions of Structure A, ##STR1## and use of the novel monoperoxyoxalates of Structure A as initiators for polymerizing ethylenically unsaturated monomers and for curing of unsaturated polyester resins are disclosed.

    摘要翻译: 公开了结构A的新型过氧草酸酯组合物,并且公开了结构A的新型单过氧化物作为用于聚合烯属不饱和单体和固化不饱和聚酯树脂的引发剂的用途。

    Device for performing thermodynamic measurements on multiphase fluids at
very high pressures and temperatures
    12.
    发明授权
    Device for performing thermodynamic measurements on multiphase fluids at very high pressures and temperatures 失效
    用于在非常高的压力和温度下对多相流体进行热力学测量的装置

    公开(公告)号:US5747674A

    公开(公告)日:1998-05-05

    申请号:US640740

    申请日:1996-05-06

    摘要: The fluids to be studied are placed in a chamber (13) of variable volume delimited by a piston (5) that can be moved by hydraulic device (24) in a cavity of a body (1). An endoscope (18) allowing to view the inside of the chamber and notably to see the orifices of two diametrically opposite pipes (14, 15) that communicate the cell with the outside is placed behind a transparent porthole (8) closing the end of the chamber opposite the piston. The body (1) can swivel about a pin (26), which allows achievement of equilibrium and also to draw off a particular phase of a stratified multiphase fluid by placing the orifice of one of pipes (14, 15) within this phase. A pressure detector (19) is included in the wall of the piston so as to decrease practically any dead volume likely to distort the measurements. A single body can contain two cells placed side by side, at least one having a transparent wall. The device can be used for studying fluids, notably petroleum fluids.

    摘要翻译: PCT No.PCT / FR95 / 01146 Sec。 371日期:1996年5月6日 102(e)日期1996年5月6日PCT提交1995年9月4日PCT公布。 出版物WO96 / 07902 日期:1996年3月14日将要研究的流体被放置在由可由液压装置(24)在主体(1)的空腔中移动的活塞(5)限定的可变容积的腔室(13)中。 一种内窥镜(18),其允许观察腔室的内部,并且特别地看到将细胞与外部连通的两个直径相对的管道(14,15)的孔放置在透明孔口(8)的后面, 与活塞相对的腔室。 主体(1)可以围绕销(26)旋转,这允许实现平衡,并且还可以通过将管道(14,15)中的一个的孔口放置在该阶段内来抽出分层的多相流体的特定阶段。 压力检测器(19)被包括在活塞的壁中,以便实际上减少可能使测量变形的任何死体积。 单体可以包含并排放置的两个电池,至少一个具有透明壁。 该装置可用于研究流体,特别是石油流体。

    Organoclay compositions manufactured with organic acid derived ester
quaternary ammonium compounds
    13.
    发明授权
    Organoclay compositions manufactured with organic acid derived ester quaternary ammonium compounds 失效
    有机粘土组合物用有机酸衍生的酯季铵化合物制成

    公开(公告)号:US5718841A

    公开(公告)日:1998-02-17

    申请号:US621932

    申请日:1996-03-26

    摘要: A novel organophilic clay comprising the reaction product of: (a) a smectite-type clay; and (b) a quaternary ammonium compound or compounds selected from the group consisting of: ##STR1## wherein R.sub.1 is an unsaturated alkyl-ester group having 8 to 30 carbon atoms as described below and R.sub.2, R.sub.3 and R.sub.4 are independently selected from the group consisting of (i) R.sub.1, (ii) long chain linear or branched alkyl (including methyl), aliphatic or aromatic groups having 1 to 30 carbon atoms (such groups can also include hydroxylated groups); (iii) aralkyl groups, which are benzyl and substituted benzyl moieties, including such groups having fused ring moieties having linear chains or branches of 1 to 30 carbon atoms; (iv) aryl groups such as phenyl and substituted phenyl including fused ring aromatic substituents; (v) beta, gamma unsaturated groups having six or less carbon atoms or hydroxyalkyl groups having 2 to 6 carbon atoms; and (vi) hydrogen and M.sup.- is an anion selected from the group consisting of chloride, methylsulfate, acetate, iodide and bromide. The organophilic clay is used in a non-aqueous fluid system such as paints, inks, and coatings to provide improved rheological properties.

    摘要翻译: 一种新颖的有机粘土,其包含以下反应产物:(a)蒙脱石型粘土; 和(b)季铵化合物或选自以下的化合物:其中R1是如下所述的具有8至30个碳原子的不饱和烷基酯基,R2,R3和R4独立地选自下列基团: 由(i)R 1,(ii)长链直链或支链烷基(包括甲基),具有1至30个碳原子的脂族或芳族基团(这些基团也可以包括羟基化基团); (iii)芳烷基,其为苄基和取代的苄基部分,包括具有1至30个碳原子的直链或支链的稠环部分的基团; (iv)芳基如苯基和取代的苯基,包括稠环芳香族取代基; (v)具有6个或更少碳原子的β,γ不饱和基团或具有2至6个碳原子的羟烷基; 和(vi)氢和M-是选自氯化物,甲基硫酸盐,乙酸盐,碘化物和溴化物的阴离子。 有机粘土用于非水性流体体系如油漆,油墨和涂料中以提供改善的流变性能。

    System for transferring samples under pressure
    14.
    发明授权
    System for transferring samples under pressure 失效
    用于在压力下转移样品的系统

    公开(公告)号:US5536474A

    公开(公告)日:1996-07-16

    申请号:US258384

    申请日:1994-06-10

    IPC分类号: G01N1/10 G01N33/24 B01L3/00

    摘要: Fluids kept under high pressure in one or several balancing cells (C1, C2) inside a thermostat-controlled enclosure (14) at about 200.degree. C. are extracted by introducing into the enclosure a sampling cell (1) capable of withstanding pressures of the order of 150 MPa, fastening cell (1) to a connection element (24) linked to balancing cells, taking samples and removing the cell from the thermostat-controlled enclosure, with all of these operations being easily conducted from outside. After possible weighing of the sampling cell, a transfer device thereafter allows the sampling cell to be communicated with measuring and analysis devices such as a gasometer associated with a separating bottle, a solvent injection means, etc. Operations are synchronized by a programmed microcomputer (MC). The preferred application is processing geological samples.

    摘要翻译: 在约200℃的温控器外壳(14)内的一个或多个平衡池(C1,C2)中保持高压的流体通过将包含能够承受压力的压力的取样池(1) 将紧固单元(1)连接到连接到平衡单元的连接元件(24)上,从恒温器控制的外壳中取出样品并移除电池,所有这些操作都容易从外部进行。 在可能称取采样单元之后,转移装置此后允许采样单元与诸如与分离瓶相关联的气量计,溶剂注入装置等的测量和分析装置连通。操作由编程的微机(MC )。 优选的应用是处理地质样品。

    Hydroxy-peroxides and their uses
    16.
    发明授权
    Hydroxy-peroxides and their uses 失效
    羟基过氧化物及其用途

    公开(公告)号:US5451654A

    公开(公告)日:1995-09-19

    申请号:US344310

    申请日:1994-11-22

    CPC分类号: C07D211/44 C07D317/24

    摘要: Novel hydroxy peroxides of the Structure AHO--R.sub.11 --X--OO--R (A)[wherein R--, --R.sub.11 -- and --X-- are as defined in the Summary of the Invention Section], having 10 hour half-life temperatures of 85.degree.-100.degree. C., the processes for their preparation, and the use of these novel compositions in curing of unsaturated polyester resins and in initiating polymerization of ethylenically unsaturated monomers.

    摘要翻译: 结构A的新型羟基过氧化物HO-R11-X-OO-R(A)[其中R-,-R11-和-X-如发明概述部分所定义],具有10小时的半衰期温度 85℃-100℃,其制备方法,以及这些新型组合物在不饱和聚酯树脂的固化和烯属不饱和单体引发聚合中的用途。

    Hydroxy-peroxides and their uses
    18.
    发明授权
    Hydroxy-peroxides and their uses 失效
    羟基过氧化物及其用途

    公开(公告)号:US5387654A

    公开(公告)日:1995-02-07

    申请号:US205273

    申请日:1994-03-02

    CPC分类号: C07D211/44 C07D317/24

    摘要: Novel hydroxy peroxides of the Structure AHO--R.sub.11 --X--OO--R (A)[wherein R--, --R.sub.11 -- and --X-- are as defined in the Summary of the Invention Section], having 10 hour half-life temperatures of 85.degree.-100.degree. C., the processes for their preparation, and the use of these novel compositions in curing of unsaturated polyester resins and in initiating polymerization of ethylenically unsaturated monomers.

    摘要翻译: 结构A的新型羟基过氧化物HO-R11-X-OO-R(A)[其中R-,-R11-和-X-如发明概述部分所定义],具有10小时的半衰期温度 85℃-100℃,其制备方法,以及这些新型组合物在不饱和聚酯树脂的固化和烯属不饱和单体引发聚合中的用途。