摘要:
A method for facilitating reducing mercury in a fluid stream using a catalytic bed assembly including at least a first catalytic bed. The method includes receiving a flow of fluid including mercury at the catalytic bed assembly; injecting a flow of a compound including ammonia and a first mercury oxidizer upstream of the first catalytic bed; and oxidizing the mercury using the mercury oxidizer and the catalytic bed assembly.
摘要:
In one embodiment, a catalyst composition comprises from about 5 weight percent to about 70 weight percent of silica-alumina; from about 30 weight percent to about 90 weight percent alumina; and from about 0.01 weight percent to about 2.0 weight percent of a group VIII metal. In another embodiment, a method for processing hydrocarbons comprises hydro-treating the hydrocarbons in the presence of a catalyst composition, wherein the catalyst comprises from about 5 weight percent to about 70 weight percent silica-alumina; from about 30 weight percent to about 90 weight percent alumina; and from about 0.01 weight percent to about 2.0 weight percent of a group VIII metal.
摘要:
A method of removing at least nitrogen oxides from an exhaust gas comprises producing reducing agents including at least hydrogen gas upstream of a conversion catalyst; diverting a portion of the exhaust gas to a location upstream of the conversion catalyst; reacting the reducing agents with nitrogen oxides present in the portion of the exhaust gas to produce a nitrogen-containing compound reducing agent using the conversion catalyst; introducing the nitrogen-containing compound reducing agent upstream of a SCR catalyst; mixing the nitrogen-containing compound reducing agent with a second portion of the exhaust gas upstream of the SCR catalyst; and reacting the nitrogen-containing compound reducing agent with nitrogen oxides present in the second portion of the exhaust gas at the SCR catalyst.
摘要:
In one embodiment, a catalyst composition comprises from about 5 weight percent to about 70 weight percent of silica-alumina; from about 30 weight percent to about 90 weight percent alumina; and from about 0.01 weight percent to about 2.0 weight percent of a group VIII metal. In another embodiment, a method for processing hydrocarbons comprises hydro-treating the hydrocarbons in the presence of a catalyst composition, wherein the catalyst comprises from about 5 weight percent to about 70 weight percent silica-alumina; from about 30 weight percent to about 90 weight percent alumina; and from about 0.01 weight percent to about 2.0 weight percent of a group VIII metal.
摘要:
A system is provided for the on-board production of reductants. The system comprises a fuel tank adapted to directly or indirectly supply a first fuel stream and a second fuel stream. An engine is in fluid communication with the fuel tank, and is configured to receive the first fuel stream and create an exhaust stream. The system further includes an emission treatment unit to treat the exhaust stream. A fuel conversion unit is configured to receive the second fuel stream, and also receive a stream comprising oxygen to partially oxidize at least a portion of the second fuel stream thereby forming reductants. In addition, the fuel conversion unit is configured to supply a reductant stream comprising the reductants to the exhaust stream. The invention further provides a method for the on-board production of reductants including supplying a first fuel stream to an engine, wherein the engine is configured to create an exhaust stream. A second fuel stream and a stream comprising oxygen are supplied to a fuel conversion unit. At least a portion of the second fuel stream is partially oxidized in the fuel conversion unit to form reductants, and a reductant stream comprising the reductants is supplied to the exhaust stream. The selective catalytic reduction of NOx present in the exhaust stream is performed.
摘要:
A method for the gasification of biomass, wherein the biomass feedstock is combined with a light hydrocarbon composition to form a slurry; followed by feeding the slurry to a gasifier to produce a fuel gas. In another embodiment, a method for the gasification of biomass is described. The method includes the steps of combining a biomass feedstock with water to form a slurry; feeding the slurry to a gasifier to produce a fuel gas; and injecting a light hydrocarbon into the gasifier, to generate gasification temperatures greater than about 900° C., by partial or complete combustion of the light hydrocarbon. In some other embodiments, the biomass gasifier product gas is coupled to a reformer, wherein a light hydrocarbon is injected to generate high temperatures.
摘要:
A process for the plasma-assisted treatment of coal in which coal is directly converted to heavy hydrocarbons. The first step in the process is direct conversion of coal to aliphatic hydrocarbons under plasma conditions in the presence of light hydrocarbons, such as natural gas. In the second process step, the aliphatic hydrocarbons are upgraded to a liquid fuel. The energy for the process can be provided by radio frequency energy, such as microwave energy, that is powered by a renewable energy source. The process has flexibility to adjust aromatic content in the fuel to match fuel specification requirements.
摘要:
A method of forming a catalyst is provided. The method comprises reacting a reactive solution comprising at least one alumina precursor, at least one silica precursor, a templating agent, a solvent, a catalytic metal precursor, and a modifier, to form a gel. The method can also include calcining the gel to form a catalyst composition comprising a pore-containing, homogeneous solid mixture which comprises at least one catalytic metal and an inorganic support comprising alumina and silica. The pores of the homogenous solid mixture have an average diameter in a range of about 1 nanometer to about 200 nanometers. A method of upgrading a hydrocarbon feedstock to a liquid fuel in the presence of the catalyst composition is also provided.
摘要:
A method for preparing a fuel composition is described, and includes the step of preparing a bio-derived fuel component that contains a mixture of iso-saturated alkanes and normal-saturated alkanes. The method further includes the step of determining if the ratio of iso-saturated alkanes to normal-saturated alkanes is at least about 2.0. If that requirement is met, the bio-derived fuel component is usually combined with a petroleum-derived component, resulting in the fuel composition. Related compositions are also described, in which the weight ratio of iso-saturated alkanes to normal-saturated alkanes is at least about 2.0; and the composition has a freeze point less than about −50° C.
摘要:
A method is provided for operating a diesel engine with reduced emissions. The method comprises combusting a first biodiesel blend fuel in a diesel engine resulting in the production of diesel exhaust gases containing NOx. The diesel exhaust gases are admixed with a second biodiesel blend fuel, and the second biodiesel blend fuel is hydrolyzed to form reducing agents. The diesel exhaust gases containing NOx are passed through an NOx-reducing catalyst to reduce the NOx through a selective catalytic reduction reaction with the reducing agents. The invention further provides a method for operating a diesel engine with reduced emissions, comprising combusting a first biodiesel blend fuel in a diesel engine resulting in the production of diesel exhaust gases containing NOx. A second biodiesel blend fuel is converted in a fuel processor thereby forming reducing agents, and the diesel exhaust gases are admixed with the reducing agents. The diesel exhaust gases containing NOx are passed through an NOx-reducing catalyst to reduce the NOx through a selective catalytic reduction reaction with the reducing agents.