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    USE OF A CO-FEED IN THE COUPLING OF TOLUENE WITH A CARBON SOURCE
    11.
    发明申请
    USE OF A CO-FEED IN THE COUPLING OF TOLUENE WITH A CARBON SOURCE 审中-公开
    在碳氢化合物与碳源的联合中使用CO

    公开(公告)号：US20140257004A1

    公开(公告)日：2014-09-11

    申请号：US14282165

    申请日：2014-05-20

    Applicant: FINA TECHNOLOGY, INC.

    Inventor： Sivadinarayana Chinta ,  Joseph L. Thorman ,  James R. Butler

    IPC: C07C2/86

    CPC classification number: C07C2/862 ,  C07C2/864 ,  C07C2521/02 ,  C07C2529/06 ,  C07C2529/08 ,  C07C15/073 ,  C07C15/46

    Abstract: A process for making styrene is disclosed that includes providing toluene, a co-feed, and a C1 source to a reactor containing a catalyst, reacting toluene with the C1 source in the presence of the catalyst and the co-feed to form a product stream containing ethylbenzene and styrene. The co-feed can be selected from the group of water, carbon monoxide, hydrogen, and combinations thereof.

    Abstract translation: 公开了一种制备苯乙烯的方法，其包括向含有催化剂的反应器提供甲苯，共进料和C1源，在催化剂和共进料存在下使甲苯与C1源反应以形成产物流 含乙苯和苯乙烯。 共进料可以选自水，一氧化碳，氢气及其组合。

    Process for the oxidative coupling of hydrocarbons
    15.
    发明授权
    Process for the oxidative coupling of hydrocarbons 有权
    碳氢化合物的氧化偶合方法

    公开(公告)号：US08796497B2

    公开(公告)日：2014-08-05

    申请号：US14072971

    申请日：2013-11-06

    Applicant: Fina Technology, Inc.

    Inventor： Sivadinarayana Chinta ,  Joseph L. Thorman ,  James R. Butler ,  Joe Hunter ,  Taylor Rives

    IPC: C07C2/84 ,  C07C2/66

    CPC classification number: C07C2/84 ,  C07C2521/00 ,  C07C2521/10 ,  C07C2523/00 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/36 ,  C07C15/073 ,  C07C15/46

    Abstract: A method for the oxidative coupling of hydrocarbons, such as the oxidative coupling of methane to toluene, includes providing an oxidative catalyst inside a reactor, and carrying out the oxidative coupling reaction under a set of reaction conditions. The oxidative catalyst includes (A) at least one element selected from the group consisting of the Lanthanoid group, Mg, Ca, and the elements of Group 4 of the periodic table (Ti, Zr, and Hf); (B) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements of Group 3 (including La and Ac) and Groups 5-15 of the periodic table; (C) at least one element selected from the group consisting of the Group 1 elements of Li, Na, K, Rb, Cs, and the elements Ca, Sr, and Ba; and (D) oxygen.

    Abstract translation: 烃的氧化偶合的方法，例如甲烷氧化偶联甲苯，包括在反应器内提供氧化催化剂，并在一组反应条件下进行氧化偶联反应。 氧化催化剂包括（A）选自镧系元素，Mg，Ca和元素周期表第4族元素（Ti，Zr和Hf）中的至少一种元素; （B）选自Li，Na，K，Rb，Cs的第1族元素和第3族元素（包括La和Ac）和元素周期表第5-15族中的至少一种元素; （C）选自Li，Na，K，Rb，Cs族元素和元素Ca，Sr和Ba中的至少一种元素; 和（D）氧气。

    Addition of a Base to Enhance Product Yield in Alkylation Reactions
    19.
    发明申请
    Addition of a Base to Enhance Product Yield in Alkylation Reactions 审中-公开
    添加碱以提高烷基化反应中的产物产率

    公开(公告)号：US20140256537A1

    公开(公告)日：2014-09-11

    申请号：US14282624

    申请日：2014-05-20

    Applicant: FINA TECHNOLOGY, INC.

    Inventor： Sivadinarayana Chinta ,  Joseph L. Thorman

    IPC: B01J31/26

    CPC classification number: B01J31/26 ,  B01J29/061 ,  B01J29/86 ,  B01J2229/38 ,  C07C2/864 ,  C07C2529/70 ,  C07C15/46 ,  C07C15/073

    Abstract: A process for making styrene including providing toluene, a co-feed, and a C1 source to a reactor containing a catalyst having acid sites and reacting toluene with the C1 source in the presence of the catalyst and the co-feed to form a product stream containing ethylbenzene and styrene, wherein the C1 source is selected from methanol, formaldehyde, formalin, trioxane, methylformcel, paraformaldehyde, methylal, dimethyl ether, and wherein the co-feed removes at least a portion of the acid sites on the catalyst. The co-feed can be selected from the group of aniline, amines, cresol, anisol, and combinations thereof.

    Abstract translation: 一种制备苯乙烯的方法，包括在含有具有酸性位点的催化剂的反应器中提供甲苯，共进料和C1源，并在催化剂和共进料存在下使甲苯与C1源反应形成产物流 含有乙苯和苯乙烯，其中C1源选自甲醇，甲醛，福尔马林，三恶烷，甲基甲缩醛，多聚甲醛，甲缩醛，二甲醚，并且其中所述共进料除去催化剂上至少一部分酸性位点。 共进料可以选自苯胺，胺，甲酚，茴香醚及其组合。

    Method for Providing a Co-Feed in the Coupling of Toluene with a Carbon Source
    20.
    发明申请
    Method for Providing a Co-Feed in the Coupling of Toluene with a Carbon Source 审中-公开
    在甲苯与碳源偶联时提供共进料的方法

    公开(公告)号：US20140107384A1

    公开(公告)日：2014-04-17

    申请号：US14105381

    申请日：2013-12-13

    Applicant: FINA TECHNOLOGY, INC.

    Inventor： Joseph E. Pelati ,  James R. Butler ,  Sivadinarayana Chinta

    IPC: C07C2/86

    CPC classification number: C07C2/864 ,  C07C2/865 ,  C07C2/867 ,  C07C2529/08 ,  Y02P30/42 ,  C07C15/46

    Abstract: A process for making styrene is disclosed that includes reacting toluene with a C1 source and a co-feed in the presence of a catalyst in a reactor to form a first product stream comprising styrene, ethylbenzene, carbon monoxide, and hydrogen; separating the hydrogen and carbon monoxide from the first product stream to form a second stream; separating the hydrogen from the second stream to form a third stream comprising hydrogen and a fourth stream comprising carbon monoxide; wherein the fourth stream is recycled to the reactor and forms at least a portion of the co-feed.

    Abstract translation: 公开了一种制备苯乙烯的方法，其包括在反应器中在催化剂存在下使甲苯与C1源和共进料反应以形成包含苯乙烯，乙苯，一氧化碳和氢的第一产物流; 将氢和一氧化碳与第一产物流分离以形成第二流; 从第二流分离氢气以形成包含氢的第三料流和包含一氧化碳的第四料流; 其中第四料流被再循环到反应器中并形成共进料的至少一部分。

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