摘要:
The invention relates to a process for the production of (meth)acrylic acid esters of polyhydric alcohols by reaction of the reactants with acrylic acid and/or methacrylic acid in the presence of acidic esterification catalysts with addition of sterically hindered phenolic compounds as polymerization inhibitors. The process is characterized in that tocopherols are used as the sterically hindered phenolic compounds and .alpha.-tocopherol is preferably at least partly used. The process is preferably carried out using reaction mixtures which are liquid at room temperature and which are at least substantially free from solvents and/or azeotropic entraining agents; more particularly, the water of condensation formed is removed from the gas phase of the reaction zone.
摘要:
The invention relates to a process for the production of (meth)acrylic acid esters of polyhydric alcohols by reaction of the reactants in the presence of acidic esterification catalysts with addition of .alpha.-substituted phenolic compounds, more particularly di-tert.-butyl hydroquinone, as polymerization inhibitors. The new process is characterized in that the reaction mixtures used are liquid at room temperature and are at least substantially free from solvents and/or azeotropic entraining agents and in that the water of condensation formed is removed from the gas phase of the reaction zone.
摘要:
Polymeric pour point depressants are described which are prepared from new esters of .alpha.,.beta.-olefinically unsaturated carboxylic acids of the formulaR.sub.1 --CO--[--O--A--CO--]--.sub.n ORwhereinR.sub.1 --CO-- is an .alpha.,.beta.-olefinically unsaturated carboxylic acid residue containing from 3 to 6 carbon atoms,R is a saturated or unsaturated hydrocarbon radical containing from 10 to 24 carbon atoms,--[--O--A--CO--]-- is a residue of a hydroxycarboxylic acid having from 2 to 6 carbon atoms,A is an aliphatic radical having from 1 to 5 carbon atoms, andn is a number having a value of from 1 to 18.
摘要:
A modified hydrophobic colored or magnetic pigment or filler comprising a hydrophobic pigment or filler containing from 0.05 to 10% by weight, based on the weight of the pigment or filler, of an organopolysiloxane corresponding to the formula ##STR1## wherein x=0 to 500,y=5 to 500,z=5 to 500,R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 denote, independently of one another, a saturated and/or unsaturated, unbranched or branched alkyl group haviang 1 to 4 carbon atoms and/or an aryl group having 6 to 9 carbon atoms, said aryl group being unsubstituted or alkyl substituted,R.sup.7 is a straight chained or branched alkyl group having 6 to 18 carbon atoms and R.sup.7 and H each amount to at least 3% of the number of groups attached to Si.
摘要:
(Meth)-acrylate compounds having one or two terminal (meth)-acrylic acid groups on an oligomer chain which have low volatility and are liquid to solid at room temperature, wherein the oligomer chain is mainly in the form of a polyester oligomer formed from one or more hydroxycarboxylic acids. The preferred (meth)-acrylate compounds are based on polyester-oligomers with a mean molecular weight in the range of about 200 to 600. The invention also relates to the use of these new reactive (meth)-acrylate compounds in construction adhesives.
摘要:
The aerobically hardenable compositions which comprise polymerizable systems containing components having some degree of ethylenic unsaturation and an oxygen-stable polymerization initiator of at least one organo-boron compound containing at least a major portion of boron to carbon bonds and possibly some boron to hydrogen bonds in the molecule and the boron containing radials are bound to an organic polymer matrix which is oxygen stable, the compositions being useful as casting resins, fillers and adhesives.
摘要:
A stable, fluid or spreadable, aerobically-hardening adhesive, storable without hardening under exclusion of oxygen, containing polymerizable olefinically-unsaturated compounds and an amount sufficient to initiate polymerization of an organoboron compound initiator, in the form of an aerobically-hardening single-component mixture, consisting essentially of:(a) at least one organoboron compound capable of initiating the polymerization of ethylenically-unsaturated compounds in the presence of oxygen, in an amount sufficient to initiate the polymerization,(b) at least one polymerizable compound containing at least one ethylenic double bond with a molecular weight of between 63 and 10,000(c) at least one compound capable of inhibiting and/or stabilizing anionic polymerization, in an amount sufficient to inhibit and/or stabilize anionic polymerization, and(d) optionally, other conventional auxiliary substances for aerobically-hardening adhesives.The adhesives harden spontaneously in the presence of oxygen in a short time to give stable adhesive bonds, even in the presence of moisture.
摘要:
A guitar case comprising a resiliently flexible first teardrop oval shell defining a guitar receptacle for operatively receiving a guitar, the first shell including a guitar suspension arrangement comprising a body strap configured to operatively secure a body of the guitar away from a side of the receptacle, and a neck strap configured to operatively secure a neck of the guitar within the receptacle. Case 10 also includes a resiliently flexible second teardrop oval shell configured to operatively complementarily engage the first shell in a clamshell manner, and fastening means configured to fasten the shells together such that at least the upper shell elastically deforms over the guitar receptacle to sandwich the guitar suspended within the receptacle between the shells.
摘要:
A drum brake module for motor vehicles operable by electric motor and performs at least one parking brake function, having an electromechanical actuator mounted on one side of the armature plate and a rotational-translational movement converter converting a rotational drive rotational movement into a translational activation movement of brake shoes arranged on a side of the armature plate facing away from the actuator in a brake drum, and including at least one supporting device between the brake shoes such that the latter can carry out an activation movement in the direction of the brake drum. A drive nut is supported by the rotational-translational movement converter in an axially secure and rotatable fashion on the armature plate to assist the braking force. The drive nut drives a spindle arrangement mounted in a rotationally fixed and axially displaceable fashion and engages with an activation cable on at least one brake shoe.
摘要:
An aqueous printing ink composition containing finely dispersed pigments and a synthetic polymer binder, the binder containing: (a) finely dispersed, aqueous-basic insoluble emulsion (co)polymers having a number average molecular weight of from about 10,000 to 1,000,000 and a glass transition temperature of up to 0.degree. C., in intimate admixture with (b) aqueous-basic soluble or dispersible (co) polymers having a number average molecular weight lower than that of the (co)polymers of component (a) and a glass transition temperature of at least 0.degree. C.