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    Nitrogen oxide reduction system
    11.
    发明授权
    Nitrogen oxide reduction system 失效
    氮氧化物还原系统

    公开(公告)号：US3972831A

    公开(公告)日：1976-08-03

    申请号：US409263

    申请日：1973-10-24

    申请人： Harold Beuther ,  Thaddeus P. Kobylinski ,  Harold E. Swift

    发明人： Harold Beuther ,  Thaddeus P. Kobylinski ,  Harold E. Swift

    IPC分类号： B01D53/92 ,  B01J23/46 ,  B01J21/02

    CPC分类号： B01D53/927 ,  B01J23/462

    摘要： A system is proposed for the purification of exhaust gases from internal combustion engines, preferably the reduction of nitrogen oxides in exhaust gases from internal combustion engines in which nitrogen is selectively formed as substantially the only nitrogen-containing product. The exhaust gas is contacted at an elevated temperature with a noble metal in a reducing atmosphere, wherein nitrogen oxides are selectively converted to nitrogen as substantially the only nitrogen containing product, and/or is contacted with a noble metal in an oxidizing atmosphere, wherein carbon monoxide and unburned hydrocarbons are converted to carbon dioxide and water, said noble metal being distended on a microporous glass body. In a preferred embodiment the exhaust gas is contacted at an elevated temperature in a reducing atmosphere with ruthenium supported on a microporous glass body comprising a leached, phase-separated alkali borosilicate.

    摘要翻译： 提出了一种用于净化来自内燃机的废气的系统，优选地将来自内部选择性地形成氮的内燃机的废气中的氮氧化物还原为基本上唯一的含氮产物。 废气在升高的温度下与还原气氛中的贵金属接触，其中氮氧化物选择性地转化为氮气，基本上仅含有氮的产物，和/或在氧化气氛中与贵金属接触，其中碳 一氧化碳和未燃碳氢化合物被转化为二氧化碳和水，所述贵金属膨胀在微孔玻璃体上。 在优选的实施方案中，废气在还原气氛中在升高的温度下与负载在包含沥滤的相分离的碱金属硼硅酸盐的微孔玻璃体上的钌接触。

    Coal liquefaction process using low grade crude oil
    12.
    发明授权
    Coal liquefaction process using low grade crude oil 失效
    采用低档原油的煤液化工艺

    公开(公告)号：US4541916A

    公开(公告)日：1985-09-17

    申请号：US662357

    申请日：1984-10-18

    申请人： Harold Beuther ,  Thaddeus P. Kobylinski ,  Win-Chung Lee ,  Bruce K. Schmid

    发明人： Harold Beuther ,  Thaddeus P. Kobylinski ,  Win-Chung Lee ,  Bruce K. Schmid

    IPC分类号： C10G1/04 ,  C10G1/00 ,  C10G47/00

    CPC分类号： C10G1/042

    摘要： A process for converting coal to liquid hydrocarbonaceous products involving a liquefaction reaction in the presence of a coal derived recycle slurry and a non-coal derived solvent comprising a hydrocarbonaceous oil or distillation bottom residue thereof intrinsically contaminated with greater than 300 ppm total of vanadium and nickel. The liquefaction reaction is performed under hydrogen pressure (approximately 500-4000 psi) and under elevated temperature (approximately 300.degree.-500.degree. C.) using a weight ratio of non-coal derived solvent to coal of about 1/1 or less. The conversion of coal to liquids is greatly enhanced by the use of such a non-coal derived solvent under these conditions.

    摘要翻译： 在煤衍生的再循环浆料和非煤衍生的溶剂的存在下，将煤转化为液化烃产物的方法，该方法包括含烃油或蒸馏塔底残余物，其本身被大于总共含有的钒和镍总量的300ppm污染 。 液化反应在氢气压力（约500-4000psi）和升高的温度（约300-500℃）下进行，使用非煤衍生的溶剂与煤的重量比约为1/1以下。 在这些条件下，通过使用这种非煤衍生的溶剂，大大提高了煤到液体的转化。

    Process for the oligomerization of ethylene
    14.
    发明授权
    Process for the oligomerization of ethylene 失效
    乙烯低聚方法

    公开(公告)号：US4288648A

    公开(公告)日：1981-09-08

    申请号：US151961

    申请日：1980-05-21

    申请人： David L. Beach ,  Thaddeus P. Kobylinski

    发明人： David L. Beach ,  Thaddeus P. Kobylinski

    IPC分类号： B01J31/20 ,  C07C2/34 ,  C07C2/02 ,  C07C2/26

    CPC分类号： B01J31/1616 ,  B01J31/20 ,  B01J31/2295 ,  C07C2/34 ,  B01J21/12 ,  B01J2231/20 ,  B01J2531/0211 ,  B01J2531/847 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2531/22 ,  Y02P20/588

    摘要： Ethylene is oligomerized by contacting ethylene with a catalyst produced by contacting (a) a refractory metal oxide/silica support such as alumina/silica wherein the silica content of the support is from about 2 to about 95 weight percent and the metal oxide content of the support is from about 5 to about 98 percent with (b) a tris(cyclopentadienyl)trinickel dicarbony. This process is characterized by a relatively high reaction rate at moderate temperatures and pressures and results in the production of relatively high proportions of desirable trimer, tetramer, pentamer, and higher olefinic products.

    摘要翻译： 通过使乙烯与通过使（a）难熔金属氧化物/二氧化硅载体如氧化铝/二氧化硅接触而制备的催化剂使乙烯低聚，其中载体的二氧化硅含量为约2至约95重量％，金属氧化物含量为 载体为约5至约98％，（b）三（环戊二烯基）三铁。 该方法的特征在于在中等温度和压力下具有相对较高的反应速率，并且导致产生相对高比例的所需三聚体，四聚体，五聚体和更高级烯烃产物。

    Process for producing acetaldehyde
    16.
    发明授权
    Process for producing acetaldehyde 失效
    乙醛生产方法

    公开(公告)号：US4239704A

    公开(公告)日：1980-12-16

    申请号：US42330

    申请日：1979-05-25

    申请人： Wayne R. Pretzer ,  Thaddeus P. Kobylinski ,  John E. Bozik

    发明人： Wayne R. Pretzer ,  Thaddeus P. Kobylinski ,  John E. Bozik

    IPC分类号： B01J31/18 ,  B01J31/20 ,  C07C45/49 ,  C07C47/06

    CPC分类号： B01J31/20 ,  B01J31/1895 ,  C07C45/49 ,  B01J2531/845

    摘要： A process for selectively producing acetaldehyde which comprises introducing into a reaction zone (1) methanol, (2) hydrogen, (3) carbon monoxide, (4) a cobalt carbonyl, a hydrido cobalt carbonyl or a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, (5) an arsenic or antimony base ligand and (6) an iodine compound and then subjecting the contents of said reaction zone to an elevated temperature and an elevated pressure for a time sufficient to convert methanol to acetaldehyde.

    摘要翻译： 一种选择性生产乙醛的方法，其中包括将甲醇，（2）氢气，（3）一氧化碳，（4）羰基钴，羰基钴或可转化为钴的钴的材料引入反应区 羰基或羰基碳氢化合物，（5）砷或锑碱配体和（6）碘化合物，然后使所述反应区的内容物在升高的温度和升高的压力下进行足以将甲醇转化为乙醛的时间。

    Metal chrysotile methane synthesis catalyst
    18.
    发明授权
    Metal chrysotile methane synthesis catalyst 失效
    金属温石棉甲烷合成催化剂

    公开(公告)号：US3947483A

    公开(公告)日：1976-03-30

    申请号：US532848

    申请日：1974-12-16

    申请人： Thaddeus P. Kobylinski ,  Harold E. Swift

    发明人： Thaddeus P. Kobylinski ,  Harold E. Swift

    IPC分类号： C07C1/04 ,  C07C9/04

    CPC分类号： B01J21/16 ,  B01J23/755 ,  B01J23/892 ,  C07C1/0435 ,  C07C2521/16

    摘要： The conversion of carbon monoxide and hydrogen to produce methane is catalyzed by a layered complex metal silicate composition characterized as having repeating units of the structural formula[(1-x)Ni.sup.a + xRu.sup.b ].sub.n (OH).sub.4 Si.sub.2 O.sub.5.wH.sub.2 Owhere x is a number from 0 to 1, this number expressing the atomic fraction of the metals nickel and ruthenium, a is the valence of nickel, b is the valence of ruthenium, n is a number equal in value to that defined by the ratio6/[a(1-x) + bx]And w is a number ranging from 0 to 4. Nickel chrysotile is the preferred catalyst.

    摘要翻译： 通过层状复合金属硅酸盐组合物催化一氧化碳和氢气转化产生甲烷的催化剂，其特征在于具有结构式[（1-X）N y + x（OH）4 Si 2 O 5·wH 2 O的重复单元，其中x是数 从0到1，这个数字表示金属镍和钌的原子分数，a是镍的化合价，b是钌的化合价，n是数值等于6 / [A（ 1-X）+ BX]，W是从0到4的范围。镍温石棉是优选的催化剂。