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29 条记录 (耗时 0.037 秒)

    Enhanced crystal acidity exchange method
    13.
    发明授权
    Enhanced crystal acidity exchange method 失效
    增强晶体酸度交换方法

    公开(公告)号：US07553790B2

    公开(公告)日：2009-06-30

    申请号：US11258440

    申请日：2005-10-25

    申请人： Jean W. Beeckman ,  Glenn R. Sweeten ,  Daria N. Lissy ,  David L. Stern ,  Stephen J. McCarthy ,  Dominick N. Mazzone ,  Christine N. Elia

    发明人： Jean W. Beeckman ,  Glenn R. Sweeten ,  Daria N. Lissy ,  David L. Stern ,  Stephen J. McCarthy ,  Dominick N. Mazzone ,  Christine N. Elia

    IPC分类号： B01J29/06

    CPC分类号： B01J29/40 ,  B01J2229/42

    摘要： The present invention describes a method to increase the activity of a catalyst by first performing an ion exchange step with a potassium ion, followed by performing an ion-exchange step with an ammonium ion. Specifically, the present invention describes a method to increase the acidity of a zeolite by incorporating a potassium salt ion-exchange prior to an ammonium salt ion-exchange step. Even more specifically, the present invention is drawn to a method of increasing the activity of a zeolite by employing more than one potassium ion exchanges followed by at least one ammonium ion exchange. The present invention also describes a method to reduce the amount of sodium normally found in commercially produced zeolite by employing any of these methods. The present invention is also drawn to the catalysts produced by any of these methods.

    摘要翻译： 本发明描述了通过首先用钾离子进行离子交换步骤，然后用铵离子进行离子交换步骤来提高催化剂活性的方法。 具体地，本发明描述了通过在铵盐离子交换步骤之前引入钾盐离子交换来提高沸石的酸度的方法。 更具体地说，本发明涉及通过使用多于一种的钾离子交换，然后进行至少一种铵离子交换来提高沸石的活性的方法。 本发明还描述了一种通过使用任何这些方法来减少通常在商业生产的沸石中发现的钠的量的方法。 本发明还涉及通过任何这些方法制备的催化剂。

    Catalyst and process for isoparaffin-olefin alkylation
    15.
    发明授权
    Catalyst and process for isoparaffin-olefin alkylation 失效
    用于异链烷烃烯烃烷基化的催化剂和方法

    公开(公告)号：US5354718A

    公开(公告)日：1994-10-11

    申请号：US42907

    申请日：1993-04-05

    申请人： Cynthia T-W. Chu ,  Altaf Husain ,  Kathleen M. Keville ,  Daria N. Lissy

    发明人： Cynthia T-W. Chu ,  Altaf Husain ,  Kathleen M. Keville ,  Daria N. Lissy

    IPC分类号： B01J29/04 ,  B01J29/28

    CPC分类号： B01J29/04

    摘要： There are provided a catalyst, a method for making this catalyst, and a process for using this catalyst in the alkylation of an isoparaffin with an olefin to provide an alkylate. The catalyst may be made from an as-synthesized material which, upon calcination, is capable of generating zeolites designated MCM-22. The as-synthesized material is then combined with a binder material, such as alumina, by an extrusion process. The uncalcined bound material may then be ammonium exchanged, followed by a calcination treatment. The as-synthesized material may also be swollen with a suitable swelling agent, such as a cetyltrimethylammonium compound, prior to the binding process.

    摘要翻译： 提供催化剂，制备该催化剂的方法，以及使用该催化剂将异链烷烃与烯烃烷基化以提供烷基化物的方法。 催化剂可以由合成原料制成，其在煅烧时能够产生称为MCM-22的沸石。 然后通过挤出方法将合成后的材料与粘合剂材料如氧化铝组合。 然后将未煅烧的结合材料进行铵交换，随后进行煅烧处理。 在结合过程之前，合成的材料也可以用合适的溶胀剂如十六烷基三甲基铵化合物溶胀。

    Gasoline upgrading process
    16.
    发明授权
    Gasoline upgrading process 失效
    汽油升级过程

    公开(公告)号：US5326462A

    公开(公告)日：1994-07-05

    申请号：US929543

    申请日：1992-08-13

    申请人： Stuart S-S. Shih ,  Kathleen M. Keville ,  Daria N. Lissy

    发明人： Stuart S-S. Shih ,  Kathleen M. Keville ,  Daria N. Lissy

    IPC分类号： C10G35/095 ,  C10G53/16 ,  C10G67/00 ,  C10G67/16 ,  C10G69/08 ,  C10G45/00

    CPC分类号： C10G35/095 ,  C10G53/16 ,  C10G67/00 ,  C10G67/16 ,  C10G69/08 ,  C10G2300/70

    摘要： Low sulfur gasoline of relatively high octane number is produced from a catalytically cracked, sulfur-containing naphtha by hydrodesulfurization followed by treatment over an acidic catalyst system comprising a zeolite having the topology of ZSM-5 and a zeolite sorbing 10 to 40 mg 3-methylpentane at 90.degree. C., 90 torr, per gram dry zeolite in the hydrogen form, e.g., ZSM-22, ZSM-23, or ZSM-35. The treatment over the acidic catalyst system in the second step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the feed naphtha.

    摘要翻译： 相对高辛烷值的低硫汽油由催化裂化的含硫石脑油通过加氢脱硫然后在酸性催化剂体系上进行处理，酸性催化剂体系包含具有ZSM-5拓扑结构的沸石和吸附10-40mg 3-甲基戊烷的沸石 在90℃，90托，每克氢形式的干沸石，例如ZSM-22，ZSM-23或ZSM-35。 在第二步骤中对酸性催化剂体系的处理恢复了由于氢化处理而发生的辛烷值损失，并导致具有与进料石脑油相当的辛烷值的低硫汽油产物。

    Preparation Of Molecular Sieve Catalysts And Their Use In The Production Of Alkylaromatic Hydrocarbons
    18.
    发明申请
    Preparation Of Molecular Sieve Catalysts And Their Use In The Production Of Alkylaromatic Hydrocarbons 有权
    分子筛催化剂的制备及其在烷基芳烃生产中的应用

    公开(公告)号：US20110118521A1

    公开(公告)日：2011-05-19

    申请号：US12997339

    申请日：2009-06-19

    申请人： Carolyn B. Duncan ,  Jon E.R. Stanat ,  Daria N. Lissy ,  Jane C. Cheng

    发明人： Carolyn B. Duncan ,  Jon E.R. Stanat ,  Daria N. Lissy ,  Jane C. Cheng

    IPC分类号： C07C2/08 ,  B01J29/04 ,  B01J37/02 ,  B01J37/08

    CPC分类号： B01J29/7038 ,  B01J29/06 ,  B01J29/7046 ,  B01J33/00 ,  B01J35/023 ,  B01J37/0221 ,  C07C2/66 ,  C07C15/107

    摘要： A method is described for preparing a molecular sieve-containing catalyst for use in a catalytic process conducted in a stirred tank reactor. The method comprises providing a mixture comprising a molecular sieve crystal and forming the mixture into catalyst particles having an average cross-sectional dimension of between about 0.01 mm and about 3.0 mm. The mixture may include a binder and the catalyst particles are then calcined to remove water therefrom and, after calcination and prior to loading the catalyst particles into a reactor for conducting the catalytic process, the catalyst particles are coated with a paraffin inert to the conditions employed in the catalytic process.

    摘要翻译： 描述了一种用于制备用于在搅拌釜反应器中进行的催化方法中的含分子筛的催化剂的方法。 该方法包括提供包含分子筛晶体并将该混合物形成的平均横截面尺寸为约0.01mm至约3.0mm的催化剂颗粒的混合物。 混合物可以包括粘合剂，然后煅烧催化剂颗粒以从其中除去水，并且在煅烧之后并且在将催化剂颗粒装载到用于进行催化方法的反应器中之前，催化剂颗粒用对所用条件惰性的链烷烃涂覆 在催化过程中。