公开(公告)号：US5071960A

公开(公告)日：1991-12-10

申请号：US578341

申请日：1990-09-06

申请人： Angelika Turowski ,  Jochen M. Quack ,  Alwin Reng ,  Arno Holst

发明人： Angelika Turowski ,  Jochen M. Quack ,  Alwin Reng ,  Arno Holst

IPC分类号： A61K8/00 ,  A61K8/64 ,  A61K8/65 ,  A61Q5/02 ,  A61Q19/10 ,  B01F17/30 ,  C07K1/113 ,  C07K14/00 ,  C08H1/06 ,  C11D1/32

CPC分类号： C11D1/32 ,  A61K8/64 ,  A61K8/645 ,  A61K8/65 ,  A61Q19/10 ,  A61Q5/02 ,  Y10S516/06

摘要： High molecular weight protein/fatty acid condensation products obtained by reaction of one mole of a protein hydrolysate of average molecular mass 3,000 to 7,000 with 0.5 to 3, preferably 2 to 2.5, moles of a C.sub.12 -C.sub.18 -fatty acid chloride in aqueous medium at a pH of 7 to 12. These protein/fatty acid condensation products are distinguished by eliciting no mucosal irritation whatever. They are therefore outstandingly suitable as surfactants for mild washing and cleansing agents.

摘要翻译： 通过将1摩尔平均分子量为3,000至7,000的蛋白质水解产物与0.5至3，优选2至2.5摩尔的水性介质中的C 12 -C 18脂肪酰氯反应获得的高分子量蛋白质/脂肪酸缩合产物 pH为7〜12。这些蛋白质/脂肪酸缩合产物的区别在于不引起任何粘膜刺激。 因此，它们非常适合用作温和洗涤和清洁剂的表面活性剂。

公开(公告)号：US4600539A

公开(公告)日：1986-07-15

申请号：US661004

申请日：1984-10-15

申请人： Udo Hoppe ,  Jochen M. Quack ,  Alwin Reng ,  Herbert Stuhler ,  Klaus-Peter Wittern

发明人： Udo Hoppe ,  Jochen M. Quack ,  Alwin Reng ,  Herbert Stuhler ,  Klaus-Peter Wittern

IPC分类号： C07C69/66 ,  A61K8/06 ,  A61K8/37 ,  A61K8/92 ,  A61K8/96 ,  A61Q17/04 ,  A61Q19/00 ,  B01F17/34 ,  B01F17/42 ,  C07C67/29 ,  C11C3/02

CPC分类号： A61K8/06 ,  A61K8/062 ,  A61K8/925 ,  A61Q19/00 ,  C07C67/29 ,  A61Q17/04

摘要： The invention relates to novel O/W emulsifiers obtainable by reacting one mole of esters of wool wax acids and glycerol, in particular partial esters, with 0.5 to 30 moles of ethylene oxide, a process for the preparation of these novel products and cosmetic agents containing these in an amount of 1 to 15% by weight, based on the total formulation.

摘要翻译： 本发明涉及通过使一摩尔羊毛蜡酸酯和甘油（特别是偏酯）与0.5至30摩尔环氧乙烷反应得到的新型O / W乳化剂，制备这些新产品的方法和含有 这些量基于总配方为1至15重量％。

公开(公告)号：US4588522A

公开(公告)日：1986-05-13

申请号：US484528

申请日：1983-04-13

申请人： Gunter Blaschke ,  Alwin Reng ,  Jochen M. Quack

发明人： Gunter Blaschke ,  Alwin Reng ,  Jochen M. Quack

IPC分类号： B01F17/18 ,  C07C291/04 ,  C11D1/75 ,  C11D1/90 ,  C11D1/42 ,  C07C101/24 ,  C07C135/02 ,  C11D1/18

CPC分类号： C11D1/90 ,  C07C291/04 ,  C11D1/75

摘要： Betaine-amine oxides of the formula ##STR1## in which R denotes alkyl, alkenyl or hydroxyalkyl, each of which has 8-22 carbon atoms, R.sup.1 denotes hydrogen or methyl, R.sup.2 denotes ethylene, propylene or 2-hydroxypropylene, R.sup.3, R.sup.4 and R.sup.5 can be identical or different and denote C.sub.1 -C.sub.3 -alkyl or a group of the formula ##STR2## or R.sup.3 denotes a group of the formula --R.sup.2 --BR.sup.4 R.sup.5, X denotes a direct bond or a group of the formula--CO--,A and B denote a group of the formulae ##STR3## it being necessary for at least one amine oxide group and at least one betaine group to be present, a denotes 0 or 1, b denotes 1, 2 or 3, n denotes a number from 0 to 10 and m denotes 1, 2 or 3. These compounds are obtained by partially quaternizing the parent polyamines with the alkali metal salt of an .omega.-halogenocarboxylic acid and then oxidizing the non-quaternized nitrogen atoms. These betaine-amine oxides are suitable for use as surfactants in cleansing agents.

摘要翻译： 其中R表示烷基，烯基或羟烷基，其中每一个具有8-22个碳原子，R1表示氢或甲基，R2表示乙烯，丙烯或2-羟基亚丙基，R3，R4和 R 5可以相同或不同，表示C 1 -C 3 - 烷基或式“基团”或R 3表示式-R 2 -BR 4 R 5的基团，X表示直接键或式-CO-的基团， A和B表示至少一个氧化胺基团和至少一个甜菜碱基团所需的一组式（IMAGE），a表示0或1，b表示1,2或3，n表示数 0至10，m表示1,2或3.这些化合物通过将母体多胺与ω-卤代羧酸的碱金属盐部分季铵化，然后氧化未季铵化的氮原子而获得。 这些甜菜碱 - 胺氧化物适合用作清洁剂中的表面活性剂。

公开(公告)号：US4564520A

公开(公告)日：1986-01-14

申请号：US423271

申请日：1982-09-24

申请人： Winfried Ehrl ,  Alwin Reng ,  Jochen M. Quack

发明人： Winfried Ehrl ,  Alwin Reng ,  Jochen M. Quack

IPC分类号： A61K8/00 ,  A61K8/46 ,  A61Q5/02 ,  C07C305/06 ,  C07C309/14 ,  C11D1/18 ,  C11D1/92 ,  A61K7/06 ,  C07C143/00

CPC分类号： A61K8/463 ,  A61Q19/10 ,  A61Q5/00 ,  A61Q5/02 ,  C11D1/92 ,  A61Q5/006 ,  A61Q5/12

摘要： Hair shampoo and body cleansing agent having a content of alkyl-sulfatobetaine of the formula ##STR1## wherein R.sub.1 is C.sub.8 -C.sub.22 alkyl or C.sub.8 -C.sub.22 alkenyl, preferably C.sub.12 -C.sub.18 alkyl, R.sub.2 is C.sub.1 -C.sub.4 alkyl, preferably methyl, R.sub.3 is C.sub.1 -C.sub.4 hydroxyalkyl or a group of the formula --(CH.sub.2 CH.sub.2 O).sub.n H and n is an integer of from 1 to 10.

摘要翻译： 其中R1是C8-C22烷基或C8-C22链烯基，优选C 12 -C 18烷基，R 2是C 1 -C 4烷基，优选甲基，R 3是C 1 -C 4羟烷基或C 1 -C 4烷氧基烷基， 式 - （CH 2 CH 2 O）n H的基团，n为1〜10的整数。

公开(公告)号：US4237243A

公开(公告)日：1980-12-02

申请号：US10519

申请日：1979-02-09

申请人： Jochen M. Quack ,  Alwin Reng ,  Juliane Balzer ,  Friedrich Engelhardt ,  Joachim Ribka

发明人： Jochen M. Quack ,  Alwin Reng ,  Juliane Balzer ,  Friedrich Engelhardt ,  Joachim Ribka

IPC分类号： A61K8/02 ,  A61K8/06 ,  A61K8/72 ,  A61K8/81 ,  A61K8/89 ,  A61K8/891 ,  A61K9/00 ,  A61K9/06 ,  A61K47/32 ,  A61Q1/00 ,  A61Q1/02 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/06 ,  A61Q11/00 ,  A61Q17/02 ,  A61Q17/04 ,  A61Q19/00 ,  A61Q19/10 ,  C08F8/00 ,  C08F8/28 ,  C08F8/44 ,  C08F8/12

CPC分类号： A61K9/0014 ,  A61K47/32 ,  A61K8/06 ,  A61K8/8158 ,  A61K8/817 ,  A61K8/8182 ,  A61Q1/00 ,  A61Q19/00 ,  C08F8/00 ,  C08F8/28 ,  A61Q1/02 ,  A61Q11/00 ,  A61Q17/02 ,  A61Q17/04 ,  A61Q19/002 ,  A61Q19/10 ,  A61Q5/02 ,  A61Q5/06

摘要： Use of cross-linked polymers for increasing the viscosity in cosmetic, pharmaceutical and technical compositions, wherein the polymer chains have the following composition:k - p molar % of groups of the formula ##STR1## p molar % of groups of the formula ##STR2## from 0 to 45 molar % of groups of the formula ##STR3## and from 0.1 to 20 molar % of a cross-linking agent, whereinR.sup.1 represents as a statistical mean value from 0 to 100 molar % of hydrogen and from 100 to 0 molar %, each calculated on the proportion of (k-p) molar %, of CH.sub.2 OH groups,R.sup.2 and R.sup.3 are hydrogen, or one of the radicals R.sup.2 and R.sup.3 is methyl, the other being hydrogen,X is cyano, alkoxycarbonyl with from 1 to 8 carbon atoms altogether, whose alkoxy radical may also be substituted by --OH, alkanoyloxy with from 2 to 6 carbon atoms, alkanoylamino with 2 to 8 carbon atoms which--if they have at least 4 carbon atoms--may also be cyclic and then form a pyrrolidone or caprolactam ring, phenyl, carboxyl or trialkoxysilyl with 1 to 2 carbon atoms in the alkoxy groups,M is an alkali metal cation, andk stands for the range of from 99.9 to 50,p stands for the range of from 5 to k,said products being prepared by copolymerizing, calculated on the total molar amount of all monomers,k molar % of acrylamide, k being defined as above, from 0 to 45 molar % of a compound of the formula I ##STR4## in which R.sup.2, R.sup.3 and X are defined as above, and from 0.1 to 20 molar % of a cross-linking agent in the presence of a radical initiator in a water-miscible alkanol, mixing the polymer dispersion obtained under the action of strong shearing forces with p molar % of an alkali metal hydroxide of the formula MOH, p being defined as above, heating the mixture at a temperature of from 30 to 150.degree. C. up to the saponification of p molar % of amide groups to form --COOM-- groups, and either isolating the copolymer obtained or methylolating the same, after removing the ammonia, in a lower alkanol with from 0 to (k-p) molar % of paraformaldehyde, k and p being defined as above, at a temperature of from 10.degree. C. to the boiling point of the lower alkanol employed.

公开(公告)号：US4722958A

公开(公告)日：1988-02-02

申请号：US8261

申请日：1987-01-29

申请人： Josef Sauer ,  Friedrich Engelhardt ,  Kerstine Rabas ,  Ulrich Karsunky ,  Wolfram Schidlo ,  Jochen M. Quack ,  Alwin K. Reng ,  Werner Skrypzak

发明人： Josef Sauer ,  Friedrich Engelhardt ,  Kerstine Rabas ,  Ulrich Karsunky ,  Wolfram Schidlo ,  Jochen M. Quack ,  Alwin K. Reng ,  Werner Skrypzak

IPC分类号： C08F220/00 ,  A61K8/81 ,  A61K9/06 ,  A61K47/32 ,  A61Q5/02 ,  A61Q5/06 ,  A61Q19/00 ,  C08F2/14 ,  C08F26/00 ,  C08F30/00 ,  C08F30/02 ,  C08F220/04 ,  C08F220/06 ,  C08F220/10 ,  C08F220/42 ,  C08F220/56 ,  C08F226/00 ,  C08F226/02 ,  C08F230/02 ,  C09F11/00 ,  C11D3/37 ,  C08F2/06 ,  C08F2/10 ,  C08F20/58 ,  C08K5/05

CPC分类号： A61K8/8158 ,  A61K47/32 ,  A61Q19/00 ,  C08F220/06 ,  C08F220/56 ,  A61Q5/02 ,  A61Q5/06

摘要： Process for the preparation of copolymers from acrylamide and acrylic or methacrylic acid, wherein to prepare 100 parts by weight of the copolymer, (A) 10-90 parts by weight of acrylamide, (B) 90-100 parts by weight of acrylic acid and/or methacrylic acid or of a salt thereof, (C) 0-40 parts by weight of another copolymerizable monomer and (D) 0-5 parts by weight of a copolymerizable crosslinking agent which has two or more olefinic double bonds are polymerized in an alcohol having 1-4 carbon atoms by precipitation polymerization such that 10-90% by weight of the alcohol, 10-90% by weight of the total amount of monomers (A), (B) and (C) together with 100% by weight of the crosslinker substance are initially mixed, polymerization is started with 10-100% by weight of the initiator and then the remainder of the solvent, monomers, crosslinking agent and initiator to make up to 100% is metered in, as individual components or as a mixture, after the polymerization has started.

摘要翻译： 丙烯酰胺和丙烯酸或甲基丙烯酸制备共聚物的方法，其中制备100重量份共聚物，（A）10-90重量份丙烯酰胺，（B）90-100重量份丙烯酸和 /或甲基丙烯酸或其盐，（C）0-40重量份的另一种可共聚单体和（D）0-5重量份具有两个或多个烯属双键的可共聚交联剂在 通过沉淀聚合使具有1-4个碳原子的醇，使得10-90重量％的醇，10-90重量％的单体（A），（B）和（C）的总量与100重量％ 首先混合交联剂物质的重量，以10-100重量％的引发剂开始聚合，然后将剩余的溶剂，单体，交联剂和引发剂配制成100％作为单独的组分或 作为混合物，聚合开始后。

公开(公告)号：US4742039A

公开(公告)日：1988-05-03

申请号：US778567

申请日：1985-09-20

申请人： Johann F. Hanauer ,  Hans-Peter Rieck ,  Hans-Jurgen Kalz ,  Jochen M. Quack ,  Armin Weiss

发明人： Johann F. Hanauer ,  Hans-Peter Rieck ,  Hans-Jurgen Kalz ,  Jochen M. Quack ,  Armin Weiss

IPC分类号： B01J20/22 ,  B01J20/10 ,  B01J20/28 ,  C01B33/12 ,  C01B33/44 ,  C11D3/00 ,  C11D3/12

CPC分类号： C01B33/44 ,  B01J20/10 ,  C01B33/12 ,  C11D3/001 ,  C11D3/1273

摘要： Adsorbents for polar organic compounds can be prepared by reacting 5-80% of an organic ammonium compound with 20-95% of a crystalline alkali metal phyllosilicate belonging to the group comprising phyllosilicates of the formulaMe.sub.2 Si.sub.x O.sub.2x+1.yH.sub.2 Oin which Me denotes an alkali metal ion or a proton, x denotes a number greater than 7, in particular from 7.5 to 23, and y denotes a number smaller than 7x. These organophilic phyllosilicic acids are capable of binding considerable amounts of organic compounds, such as, for example, fats or softeners. They are, therefore, excellently suitable for use as additives for enhancing the washing action in detergents or as a depot for organic compounds.

摘要翻译： 极性有机化合物的吸附剂可以通过使5-80％的有机铵化合物与20-95％的属于式Me2SixO2x + 1.yH2O的页硅酸盐的结晶性碱金属页硅酸盐反应来制备，其中Me表示碱 金属离子或质子，x表示大于7的数，特别是7.5至23的数，y表示小于7x的数。 这些亲有机硅酸能够结合大量的有机化合物，例如脂肪或软化剂。 因此，它们非常适合用作增加洗涤剂中的洗涤作用的添加剂或作为有机化合物的贮存库。

公开(公告)号：US4589988A

公开(公告)日：1986-05-20

申请号：US729650

申请日：1985-05-02

申请人： Hans-Peter Rieck ,  Hans-Jurgen Kalz ,  Adolf May ,  Jochen M. Quack ,  Hans-Walter Bucking

发明人： Hans-Peter Rieck ,  Hans-Jurgen Kalz ,  Adolf May ,  Jochen M. Quack ,  Hans-Walter Bucking

IPC分类号： C11D1/65 ,  C11D1/62 ,  C11D3/00 ,  C11D3/08 ,  C11D3/12 ,  D06M11/00 ,  D06M11/77 ,  D06M11/79 ,  D06M13/02 ,  D06M13/322 ,  D06M13/325 ,  D06M13/328 ,  D06M13/35 ,  D06M13/352 ,  D06M13/372 ,  D06M13/402 ,  D06M13/405 ,  D06M13/46 ,  D06M13/463 ,  D06M23/02 ,  D06M23/08 ,  D06M1/02

CPC分类号： C11D3/124 ,  C11D3/001 ,  C11D3/08 ,  C11D3/1273

摘要： Softener-containing washing agents which, in addition to the customary components of washing agents, contain 0 to 10% by weight of a quaternary ammonium compound and 1 to 30% by weight of a softener system which comprises 10 to 90% by weight of a tertiary amine and 90 to 10% by weight of a crystalline sheet-silicate of the formulaMe.sub.2 Si.sub.x O.sub.2x+1 .multidot. yH.sub.2 Oin which Me denotes an alkali metal ion or a proton, x denotes a number greater than 7, in particular from 7.5 to 23, and y denotes a number smaller than 7 x, in particular smaller than x. In the softener system, the tertiary amine is in a state of adsorption on the alkali metal silicate. The ammonium compounds, which are adsorbed on said silicate, produce a softening effect in the washing agent but on the other hand are compatible with anionic surfactants in the washing agent. produce a softening effect in the washing agent but on the other hand are compatible with anionic surfactants in the washing agent.

摘要翻译： 含有洗涤剂的常规成分除外的含软化剂的洗涤剂含有0〜10重量％的季铵化合物和1〜30重量％的软化剂体系，其包含10〜90重量％的 叔胺和90〜10重量％的式Me2SixO2x + 1×yH2O的结晶性硅酸盐，其中Me表示碱金属离子或质子，x表示大于7，特别是7.5〜23的数，以及 y表示小于7×，特别是小于x的数字。 在软化剂体系中，叔胺处于碱金属硅酸盐上的吸附状态。 吸附在所述硅酸盐上的铵化合物在洗涤剂中产生软化作用，但另一方面与洗涤剂中的阴离子表面活性剂相容。 在洗涤剂中产生软化作用，另一方面与洗涤剂中的阴离子表面活性剂相容。