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    Metal cation-modified alkylation catalysts
    13.
    发明授权
    Metal cation-modified alkylation catalysts 失效
    金属阳离子改性烷基化催化剂

    公开(公告)号：US5739074A

    公开(公告)日：1998-04-14

    申请号：US453044

    申请日：1995-05-30

    申请人： Joseph A. Kocal ,  Anil R. Oroskar

    发明人： Joseph A. Kocal ,  Anil R. Oroskar

    IPC分类号： B01J23/02 ,  B01J23/04 ,  B01J27/08 ,  C07C2/58 ,  B01J27/135

    CPC分类号： B01J23/02 ,  B01J23/04 ,  B01J27/08 ,  C07C2/58 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/12 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/755 ,  C07C2527/125 ,  C07C2527/126

    摘要： A catalytic composite of a refractory inorganic oxide whose bound surface hydroxyl group has reacted with a Friedel-Crafts type metal halide and whose acidity has been modified by the deposition of a monovalent metal cation, especially an alkali metal cation, or alkaline earth metal cation shows superior selectivity and a significantly decreased cracking tendency relative to similar catalysts without the monovalent metal or alkaline earth metal cation. The resulting alkylate from an isobutane-butene feedstock shows a substantial increase in research octane number relative to the alkylate formed by a similar catalyst which has not been so modified by an alkali or alkaline earth metal cation.

    摘要翻译： 结合表面羟基与Friedel-Crafts型金属卤化物反应并且酸性已经通过沉积一价金属阳离子，特别是碱金属阳离子或碱土金属阳离子而改性的耐火无机氧化物的催化复合物显示出 优异的选择性和相对于没有一价金属或碱土金属阳离子的类似催化剂显着降低的开裂趋势。 从异丁烷 - 丁烯原料得到的烷基化物相对于由未被碱金属或碱土金属阳离子改性的类似催化剂形成的烷基化物，研究辛烷值显着增加。

    Alkylation of aromatics using a metal cation-modified friedel-crafts type catalyst
    14.
    发明授权
    Alkylation of aromatics using a metal cation-modified friedel-crafts type catalyst 失效
    使用金属阳离子改性的Friedel-Crafts型催化剂烷基化芳族化合物

    公开(公告)号：US5672797A

    公开(公告)日：1997-09-30

    申请号：US533576

    申请日：1995-09-25

    申请人： Joseph A. Kocal

    发明人： Joseph A. Kocal

    IPC分类号： B01J23/02 ,  B01J23/04 ,  B01J27/08 ,  C07C2/66 ,  C07C2/68 ,  C07C2/86 ,  C07C29/44 ,  C07C41/30 ,  C07C2/70

    CPC分类号： B01J27/08 ,  B01J23/02 ,  B01J23/04 ,  C07C2/66 ,  C07C2/68 ,  C07C2/861 ,  C07C2/864 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/26 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/755 ,  C07C2527/125 ,  C07C2527/126

    摘要： A process for the alkylation of aromatic compounds with an olefin, alcohol, or alkyl halide having from 1 to 24 carbon atoms comprising reacting in the liquid phase the aromatic and alkylating agent under alkylation conditions in the presence of a novel catalyst comprising: a) a refractory inorganic oxide, b) the reaction product of a first metal halide and bound surface hydroxyl groups of the refractory inorganic oxide, c) a second metal cation, and d) optionally a zerovalent third metal. The refractory inorganic oxide is selected from the group consisting of alumina, titania, zirconia, chromia, silica, boria, silica-alumina, and combinations thereof and the first metal halide is a fluoride, chloride, or bromide of aluminum. The second metal cation is selected from the group consisting of: monovalent metal cations in an amount from 0.0026 up to about 0.20 gram atoms per 100 grams refractory inorganic oxide for lithium, potassium, cerium, rubidium, silver, and copper, and from 0.009 to about 0.20 gram atoms for sodium; and alkaline earth metal cations in an mount from about 0.0013 up to about 0.01 gram atoms per 100 grams of refractory inorganic oxide for beryllium; strontium, and barium; and in an amount from about 0.004 up to about 0.1 gram atoms per 100 grams support for magnesium and calcium, or combinations thereof. The third metal is selected from the group consisting of platinum, palladium, nickel ruthenium, rhodium, osmium and iridium, and any combination thereof.

    摘要翻译： 一种用烯烃，醇或具有1至24个碳原子的烷基卤烷基化芳族化合物的方法，包括在烷烃化条件下在液相中使芳族和烷基化剂在新催化剂存在下反应，包括：a） 耐火无机氧化物，b）第一金属卤化物和耐火无机氧化物的结合表面羟基的反应产物，c）第二金属阳离子，和d）任选的零价第三金属。 耐火无机氧化物选自氧化铝，二氧化钛，氧化锆，氧化铬，二氧化硅，氧化硼，二氧化硅 - 氧化铝及其组合，第一种金属卤化物是铝的氟化物，氯化物或溴化物。 第二金属阳离子选自：一价金属阳离子，其量为0.0026至约0.20克原子/ 100克锂，钾，铈，铷，银和铜的难熔无机氧化物，和0.009至 钠约0.20克原子; 和碱土金属阳离子的量为约0.0013至约0.01克原子/ 100克用于铍的耐火无机氧化物; 锶和钡; 并且其量为约0.004至约0.1克原子/ 100克镁和钙的载体或其组合。 第三种金属选自铂，钯，镍钌，铑，锇和铱，以及它们的任何组合。

    Detergent alkylation process using a fluorided silica-alumina
    15.
    发明授权
    Detergent alkylation process using a fluorided silica-alumina 失效
    使用氟化二氧化硅 - 氧化铝的洗涤剂烷基化方法

    公开(公告)号：US5196574A

    公开(公告)日：1993-03-23

    申请号：US816341

    申请日：1991-12-23

    申请人： Joseph A. Kocal

    发明人： Joseph A. Kocal

    IPC分类号： C07C2/66 ,  C07C309/31

    CPC分类号： C07C309/31 ,  C07C2/66 ,  C07C2521/12

    摘要： A fluorided silca-alumina catalyst, particularly one with a silica:alumina ratio in the range of 1:1-9:1 containing from 1 to 6 weight percent fluoride, is particularly effective in the liquid phase alkylation of benzene to produce linear alkyl benzenes at temperatures no greater than 140.degree. C. Conversions in excess of 98% with selectivity exceeding 85% and linearity exceeding 90% may be achieved readily.

    摘要翻译： 氟化硅铝氧化物催化剂，特别是含有1至1：1：1重量百分比氟化物的二氧化硅：氧化铝比为1：1-9：1的氟硅烷氧化铝催化剂在苯的液相烷基化中特别有效，生成直链烷基苯 在不大于140℃的温度下，可以容易地实现超过98％的转化率，选择性超过85％，线性超过90％。

    Hydrocarbon conversion process using alumina clay compositions
    16.
    发明授权
    Hydrocarbon conversion process using alumina clay compositions 失效
    使用氧化铝粘土组合物的烃转化方法

    公开(公告)号：US5160032A

    公开(公告)日：1992-11-03

    申请号：US808136

    申请日：1991-12-16

    申请人： Jennifer S. Holmgren ,  Stanley A. Gembicki ,  Michael W. Schoonover ,  Joseph A. Kocal

    发明人： Jennifer S. Holmgren ,  Stanley A. Gembicki ,  Michael W. Schoonover ,  Joseph A. Kocal

    IPC分类号： B01J21/16 ,  B01J29/04 ,  C07C4/06 ,  C10G47/12

    CPC分类号： C10G47/12 ,  B01J21/16 ,  B01J29/049 ,  C07C4/06 ,  B01J2229/42 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/16 ,  C07C2527/16

    摘要： This invention relates to hydrocarbon conversion process using a catalyst consisting essentially of a layered clay homogeneously dispersed in an inorganic oxide matrix. The clay is dispersed in such a way that the clay layers are completely surrounded by the inorganic oxide matrix. The inorganic oxide is selected from the group consisting of alumina, titania, silica, zirconia, P.sub.2 O.sub.5 and mixtures thereof. The clay can be a natural clay such as montmorillonite, a metal exchanged clay (Fe.sup.+3 exchanged) or a pillared clay such as aluminum chlorohydrate (ACH) pillared clay. The hydrocarbon conversion process is carried out by contacting a hydrocarbon feed with the catalyst at hydrocarbon conversion conditions to give a hydroconverted product. Examples of the hydrocarbon conversion processes are alkylation and hydrocracking.

    摘要翻译： 本发明涉及使用基本上由均匀分散在无机氧化物基质中的层状粘土组成的催化剂的烃转化方法。 粘土以这样的方式分散，即粘土层被无机氧化物基体完全包围。 无机氧化物选自氧化铝，二氧化钛，二氧化硅，氧化锆，P 2 O 5及其混合物。 粘土可以是天然粘土，例如蒙脱石，金属交换的粘土（Fe + 3交换的）或柱状粘土如水合氯化铝（ACH）柱状粘土。 烃转化过程是通过在烃转化条件下使烃进料与催化剂接触以得到加氢转化产物来进行的。 烃转化方法的实例是烷基化和加氢裂化。

    Hydrocarbon conversion process
    17.
    发明授权
    Hydrocarbon conversion process 失效
    烃转化过程

    公开(公告)号：US4921946A

    公开(公告)日：1990-05-01

    申请号：US265729

    申请日：1988-11-01

    申请人： Joseph A. Kocal ,  David C. Martindale ,  Paul J. Kuchar

    发明人： Joseph A. Kocal ,  David C. Martindale ,  Paul J. Kuchar

    IPC分类号： B01J29/90 ,  B01J38/12 ,  C07C2/76

    CPC分类号： B01J29/90 ,  B01J38/12 ,  C07C2/76 ,  C07C2529/40 ,  Y02P20/584

    摘要： A hydrocarbon conversion process is disclosed which extends the useful life of a regenerable zeolite-containing hydrocarbon conversion catalyst. In one aspect of this process, a hydrocarbon feed containing fluorides is passed through a fluoride removal system which reduces the fluoride concentration of the feed to below 100 ppb. The hydrocarbon feed containing less than 100 ppb fluorine is then converted over a regenerable zeolite-containing hydrocarbon conversion catalyst. The zeolite-containing hydrocarbon conversion catalyst is regenerated with an oxygen-containing gas stream as necessary to burn off carbonaceous deposits on the catalyst so as to return the zeolite catalyst to a high level of activity.

    摘要翻译： 公开了一种延长可再生沸石烃转化催化剂的使用寿命的烃转化方法。 在该方法的一个方面，含氟化物的烃进料通过氟化物去除系统，其将进料的氟化物浓度降低至低于100ppb。 然后将含有少于100ppb氟的烃原料转化为可再生的含沸石的烃转化催化剂。 含有沸石的烃转化催化剂根据需要用含氧气体气流再生，以将催化剂上的碳质沉积物烧掉，使沸石催化剂回复到高水平的活性。

    PROCESS FOR PRODUCING TEREPHTHALIC ACID
    19.
    发明申请
    PROCESS FOR PRODUCING TEREPHTHALIC ACID 有权
    生产过敏性酸的方法

    公开(公告)号：US20120004450A1

    公开(公告)日：2012-01-05

    申请号：US13155553

    申请日：2011-06-08

    申请人： Alakananda Bhattacharyya ,  Joseph A. Kocal ,  Joel T. Walenga ,  Nikolay Y. Adonin ,  Nina I. Kuznetsova ,  Bair S. Bal'zhinimaev

    发明人： Alakananda Bhattacharyya ,  Joseph A. Kocal ,  Joel T. Walenga ,  Nikolay Y. Adonin ,  Nina I. Kuznetsova ,  Bair S. Bal'zhinimaev

    IPC分类号： C07C51/265 ,  C07C51/16

    CPC分类号： C07C51/265 ,  C07C51/42 ,  Y02P20/52 ,  Y02P20/542 ,  C07C63/26

    摘要： A solid terephthalic acid composition and a process for producing terephthalic acid from para-xylene. The process comprises forming a mixture comprising the para-xylene, a solvent, a bromine source, and a catalyst; and oxidizing the para-xylene by contacting the mixture with an oxidizing agent at oxidizing conditions to produce a solid oxidation product comprising terephthalic acid, para-toluic acid, 4-carboxybenzaldehyde. The solvent comprises a carboxylic acid having from 1 to 7 carbon atoms and an dialkyl imidazolium ionic liquid; and the catalyst comprises at least one of cobalt, titanium, manganese, chromium, copper, nickel, vanadium, iron, molybdenum, tin, cerium, and zirconium. The solid terephthalic acid composition comprises, less than about 4,000 ppm-wt 4-carboxybenzaldehyde content, and more than about 2,000 ppm-wt a para-toluic acid.

    摘要翻译： 固体对苯二甲酸组合物和由对二甲苯生产对苯二甲酸的方法。 该方法包括形成包含对二甲苯，溶剂，溴源和催化剂的混合物; 并通过在氧化条件下将氧化剂与氧化剂接触来氧化对二甲苯以产生包含对苯二甲酸，对甲苯甲酸，4-羧基苯甲醛的固体氧化产物。 溶剂包括具有1至7个碳原子的羧酸和二烷基咪唑鎓离子液体; 催化剂包括钴，钛，锰，铬，铜，镍，钒，铁，钼，锡，铈和锆中的至少一种。 固体对苯二甲酸组合物包含小于约4,000ppm重量的4-羧基苯甲醛含量和大于约2,000ppm重量的对甲苯甲酸。