Methods and systems for acidizing subterranean formations
    12.
    发明授权
    Methods and systems for acidizing subterranean formations 有权
    酸化地下地层的方法和系统

    公开(公告)号:US09540560B2

    公开(公告)日:2017-01-10

    申请号:US14394826

    申请日:2013-12-13

    CPC classification number: C09K8/74 C02F11/06 E21B43/25

    Abstract: A method for acidizing subterranean formations may include providing a treatment fluid comprising an aqueous carrier fluid, an acid, and a chelating agent comprising N-(phosphonomethyl)iminodiacetic acid, the treatment fluid having a pH at or below that at which carboxylic or phosphonic acid groups of the N-(phosphonomethyl)iminodiacetic acid are protonated and the chelating agent is ineffective for complexing a metal ion; introducing the treatment fluid into a wellbore penetrating a subterranean formation comprising a carbonate mineral; reacting the acid with the carbonate mineral in the presence of the chelating agent, such that the acid at least partially spends as the pH of the treatment fluid rises; and complexing a metal ion with the chelating agent once the pH of the treatment fluid rises above a pKa value for one or more of the carboxylic or phosphonic acid groups of the N-(phosphonomethyl)iminodiacetic acid.

    Abstract translation: 用于酸化地下地层的方法可以包括提供包含含水载体流体,酸和包含N-(膦酰基甲基)亚氨基二乙酸的螯合剂的处理流体,所述处理流体的pH等于或低于羧酸或膦酸 N-(膦酰基甲基)亚氨基二乙酸的基团被质子化,螯合剂对金属离子络合是无效的; 将处理流体引入渗透包含碳酸盐矿物的地下地层的井眼; 在螯合剂存在下使酸与碳酸盐矿物反应,使得当处理液的pH升高时,酸至少部分地消耗; 并且一旦处理液的pH升高到N-(膦酰基甲基)亚氨基二乙酸的一个或多个羧酸或膦酸基团的pKa值以上,就将金属离子与螯合剂络合。

    WASTE SLUDGE INCINERATOR USING PYROLYSIS AND GASIFICATION, AND RELATIVE PROCESS

    公开(公告)号:US20160245508A1

    公开(公告)日:2016-08-25

    申请号:US15025835

    申请日:2014-10-02

    Applicant: ENI S.P.A.

    Abstract: The present invention relates to reaction equipment for the treatment of organic and/or inorganic waste of refineries or petrochemical plants comprising: •—a drying and pyrolysis device (4) which rotates around its longitudinal, tilted rotation axis (A), •—a gasification device (6) which rotates around its longitudinal, horizontal rotation axis (B), •—a combustion device (14) comprising a burner (13) having a longitudinal horizontal axis (C), •—at least one settling chamber (15) for the collection of intermediate solid residues and the accumulation of intermediate gaseous reaction products, •—at least one outlet duct of the gaseous end-products (16), at least one outlet duct of the solid end-products (7), and at least one inlet duct of the feedstock (2) •—said combustion device (14), drying and pyrolysis device (4), gasification device (6) are physically separated and positioned on three different levels, •—the longitudinal rotation axis (A) of the drying and pyrolysis device (4) is tilted with respect to both the longitudinal rotation axis (B) of the gasification device (6) and also with respect to the longitudinal axis (C) of the combustion device (14), •—the longitudinal rotation axis (B) of the gasification device (6) is parallel to the longitudinal axis (C) of the combustion device (14), •—the combustion device (14) is in fluid communication with the drying and pyrolysis device (4), •—the drying and pyrolysis device (4) comprises, in its interior, a first indirect heat exchange device (3) in which the combustion fumes coming from the combustion device (14) flow, •—at least one settling chamber (15) in fluid communication with said drying and pyrolysis device (4) and with said gasification device (6) and with said combustion device (14), •—conveying means (5) are positioned in the settling chamber (15) and put the drying and pyrolysis device (4) in fluid communication with the gasification device, •—it comprises a second heat exchange device (12) in fluid communication with the first indirect heat exchange device (3) and the combustion device (14), •—it comprises means for the suction of the intermediate gaseous reaction products, said means being positioned in the settling chamber (15).

    PRODUCTION OF NUTRIENT-RICH BIOCHAR FROM A RESIDUAL MATERIAL
    15.
    发明申请
    PRODUCTION OF NUTRIENT-RICH BIOCHAR FROM A RESIDUAL MATERIAL 审中-公开
    从残留物中生产营养丰富的生物

    公开(公告)号:US20160075608A1

    公开(公告)日:2016-03-17

    申请号:US14888751

    申请日:2014-04-30

    Inventor: Gunnar THELIN

    Abstract: The present invention describes a process for the treatment of a residual product for the production of a biochar, said process comprising: —providing a residual product material comprising at least phosphorous; said process also involving —performing a thermal treatment of the residual product material in a temperature of 800-1100° C. in at least a low oxygen containing environment, for the for the separation of volatiles in a stream also comprising at least cadmium (Cd), if present, and for the production of a nutrient-rich biochar comprising phosphorous.

    Abstract translation: 本发明描述了一种用于处理用于生产生物炭的残留产物的方法,所述方法包括: - 提供至少包含磷的残余产物; 所述方法还涉及在至少含氧低的环境中在800-1100℃的温度下进行残余产物材料的热处理,以便在还包含至少镉(Cd)的流中分离挥发物 ),如果存在,以及用于生产包含磷的营养丰富的生物炭。

    Sludge processing system and storage medium storing a program for controlling operation of a sludge processing system based on moisture content of concentrated sludge
    16.
    发明授权
    Sludge processing system and storage medium storing a program for controlling operation of a sludge processing system based on moisture content of concentrated sludge 有权
    污泥处理系统和存储介质,其存储基于浓缩污泥含水量控制污泥处理系统的操作的程序

    公开(公告)号:US09212076B2

    公开(公告)日:2015-12-15

    申请号:US13932229

    申请日:2013-07-01

    Inventor: Tatsuo Hiramatsu

    Abstract: Disclosed is a sludge processing system having a centrifugal separator which concentrates the sludge and a furnace which heat-treats the concentrated sludge, and allows the automatic control in which the operational condition of the centrifugal separator is set to the optimal condition in accordance with the operational state of the furnace. The control device sets a variable range of a differential speed between the bowl and the screw conveyor of the centrifugal separator, and performs a variable control of the differential speed so that the measurements concentration moisture of the concentration sludge achieves a moisture content requested by the furnace within the variable range, when the measurements concentration moisture of the concentration sludge maintains the moisture content requested by the furnace for a certain period of time being previously set, changes a control value of the centrifugal force.

    Abstract translation: 公开了一种污泥处理系统,其具有浓缩污泥的离心分离器和对浓缩污泥进行热处理的炉,并且允许根据操作将离心分离器的操作条件设定为最佳条件的自动控制 炉的状态。 控制装置设定离心分离器的碗和螺旋输送机之间的差速的可变范围,并且对差速进行可变控制,使得浓缩污泥的测量浓度水分达到炉所要求的含水量 在可变范围内,当浓缩污泥的测量浓度水分保持炉所要求的水分含量预先设定一段时间时,改变离心力的控制值。

    Sludge processing system and storage medium storing a program for controlling operation of a sludge processing system based on correlation between moisture content of concentrated sludge, centrifugal force, and concentrated sludge convey torque
    17.
    发明授权
    Sludge processing system and storage medium storing a program for controlling operation of a sludge processing system based on correlation between moisture content of concentrated sludge, centrifugal force, and concentrated sludge convey torque 有权
    污泥处理系统和存储介质,其基于浓缩污泥的含水量,离心力和浓缩污泥输送扭矩之间的相关性来存储用于控制污泥处理系统的操作的程序

    公开(公告)号:US09206064B2

    公开(公告)日:2015-12-08

    申请号:US13921908

    申请日:2013-06-19

    Inventor: Tatsuo Hiramatsu

    Abstract: Disclosed is a sludge processing system having a centrifugal separator concentrating the sludge and a furnace heat-treating the concentrated sludge. It allows automatic control in which the operational condition of the centrifugal separator operates under optimal conditions according to the operational state of the furnace. The control device sets a variable range of a differential speed between the bowl and screw conveyor of the centrifugal separator, and variably controls the differential speed so concentrated sludge convey torque of the screw conveyor achieves a torque corresponding to a moisture content requested by the furnace within the variable range, when the differential speed varies within a certain previously set range and the concentrated sludge convey torque of the screw conveyor maintains the torque corresponding to the moisture content requested by the furnace for a certain period of time being previously set, changes a control value of the centrifugal force and the torque.

    Abstract translation: 公开了一种具有浓缩污泥的离心分离器和对浓缩污泥进行热处理的炉的污泥处理系统。 它允许自动控制,其中离心分离器的操作条件根据炉的操作状态在最佳条件下操作。 控制装置设置离心分离器的碗和螺旋输送机之间的差速可变范围,并且可变地控制差速速度,使得螺旋输送机的浓缩污泥输送扭矩达到与炉内所要求的水分含量相对应的转矩 可变范围,当差速在一定的先前设定范围内变化时,螺旋输送机的浓缩污泥输送扭矩保持与炉所要求的水分含量相对应的扭矩在一定时间段内被预先设定,改变控制 离心力和扭矩的值。

    ORGANIC CONTAINING SLUDGE TO FERTILIZER ALKALINE CONVERSION PROCESS
    18.
    发明申请
    ORGANIC CONTAINING SLUDGE TO FERTILIZER ALKALINE CONVERSION PROCESS 有权
    有机污泥对碱性转化过程进行加工

    公开(公告)号:US20150020560A1

    公开(公告)日:2015-01-22

    申请号:US14509223

    申请日:2014-10-08

    Abstract: This invention is directed to systems, devices and methods for treating organic-containing sludges and converting such sludges to high value fertilizers containing both inorganic and organic fertilizer components, which creates an inorganically-augmented bioorganic fertilizer. The invention describes methods to create a thixotropic or paste-like material via the application of mixing energy to the organic sludge followed by an alkaline treatment and a subsequent ammoniation. The invention further describes a method to increase the plant nutrient content in the organic containing product to a level which permits the finished granular fertilizer product to compete in the commercial agricultural fertilizer marketplace. Further, the invention reduces odors associated with said organic-containing sludges.

    Abstract translation: 本发明涉及用于处理含有有机污泥并将这种污泥转化成含有无机和有机肥料成分的高价值肥料的系统,装置和方法,其产生无机增殖的生物有机肥料。 本发明描述了通过向有机污泥施加混合能量然后进行碱处理和随后的氨化来产生触变性或糊状材料的方法。 本发明还描述了一种将含有机物的产品中的植物营养成分增加到允许成品粒状肥料产品在商业农用肥料市场中竞争的水平的方法。 此外,本发明减少与所述含有机污泥相关的气味。

    UTILIZATION OF IRON SALTS TO STABILIZE AND/OR DISINFECT BIOSOLIDS
    19.
    发明申请
    UTILIZATION OF IRON SALTS TO STABILIZE AND/OR DISINFECT BIOSOLIDS 有权
    使用铁盐来稳定和/或消除生物毒性

    公开(公告)号:US20150000358A1

    公开(公告)日:2015-01-01

    申请号:US14215952

    申请日:2014-03-17

    Abstract: In order to render sewage sludge suitable for beneficial purposes, it must be disinfected and stabilized. EDC deactivation is rapidly becoming a desirable result of any sludge or biosolids treatment process. Disclosed herein is a process of treating sewage sludge so as to stabilize the sludge that involves the presence of an iron-containing compound during dewatering of the sludge. Process embodiments described also achieve biosolid samples that have reduced EDC activity, Other embodiments disclosed involve use of a combination of iron salts ferrate and ferric chloride that are added to wastewater sludge in the dewatering step before heat drying. The biosolids resulting from sludge treated with aniron-containing compound are able to resist putrefaction for more than two to three weeks.

    Abstract translation: 为了使污水污泥适合用于有益目的,必须进行消毒和稳定。 EDC失活正迅速成为任何污泥或生物固体处理工艺的理想结果。 本文公开了一种处理污泥的方法,以便在污泥脱水期间稳定涉及含铁化合物的存在的污泥。 所描述的方法实施方案还实现了具有降低的EDC活性的生物固体样品。所公开的其它实施方案涉及在加热干燥之前在脱水步骤中加入到废水污泥中的铁盐和铁氯化物的组合的使用。 由含铁化合物处理的污泥产生的生物固体能够抵抗腐败超过两至三周。

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