公开(公告)号：US4863792A

公开(公告)日：1989-09-05

申请号：US257949

申请日：1988-10-14

Applicant: James S. Mrozinski

Inventor： James S. Mrozinski

IPC: C08J9/26 ,  B01D67/00 ,  B01D69/12 ,  B32B5/32 ,  B32B27/32 ,  C08J5/12 ,  C08J9/28 ,  C08J9/36 ,  H01M2/16

CPC classification number: H01M2/1653 ,  B01D67/0027 ,  B01D67/003 ,  B01D69/12 ,  B01D71/26 ,  B32B27/32 ,  B32B5/32 ,  C08J5/122 ,  C08J9/28 ,  H01M2/1686 ,  B01D2323/16 ,  B01D2325/022 ,  C08J2201/052 ,  C08J2201/0543 ,  C08J2201/0546 ,  Y10T428/249978 ,  Y10T428/249979 ,  Y10T428/249981

Abstract: Multi-layer, microporous polyolefin sheet materials are provided. The sheet materials comprise at least two microporous polyolefin layers, the layers being autogenously bonded and having substantially the same porosity as prior to bonding.

Abstract translation: 提供多层微孔聚烯烃片材。 片材包含至少两个微孔聚烯烃层，这些层是自粘结的并且具有与粘接前基本相同的孔隙率。

公开(公告)号：US4655769A

公开(公告)日：1987-04-07

申请号：US811015

申请日：1985-12-18

Applicant: Anagnostis E. Zachariades

Inventor： Anagnostis E. Zachariades

IPC: A61F2/00 ,  A61L27/16 ,  A61L27/50 ,  B29C43/00 ,  B29C43/20 ,  B29C55/00 ,  C08J9/28 ,  A61F2/06 ,  B29C55/22

CPC classification number: C08J9/28 ,  A61L27/16 ,  A61L27/507 ,  B29C43/203 ,  B29C55/005 ,  B29C43/00 ,  B29K2023/06 ,  C08J2201/052 ,  C08J2201/0543 ,  C08J2201/0546 ,  C08J2323/06

Abstract: A pseudo-gel comprising a suitable solvent in an amount of 99 to 90 percent by weight and an ultra-high-molecular-weight polyethylene in an amount of 1 to 10 percent by weight, said polyethylene being a semicrystalline network with adjustable crystalline morphology comprising randomly dispersed and oriented chain-folded single crystals, stacks of single crystals, spherulite crystals, and extended-chain shish-kebab-type of fibrils with lengths up to a few millimeters and widths up to 20 .mu.m. Also, the semicrystalline ultra-high molecular-weight polyethylene obtained by removal of said solvent from the pseudo-gel. Further, a method for making the pseudo-gel and the ultra-high-molecular-weight polyethylene product.

Abstract translation: 一种假凝胶，其包含99至90重量％的合适溶剂和1-10重量％的超高分子量聚乙烯，所述聚乙烯是具有可调结晶形态的半结晶网络，包括 随机分散和取向的链折叠单晶，单晶的堆叠，球晶，延伸链条的肠丝织物型原纤维，长度可达几毫米，宽度可达20微米。 此外，通过从假凝胶中除去所述溶剂获得的半结晶超高分子量聚乙烯。 另外，制造假凝胶和超高分子量聚乙烯制品的方法。

公开(公告)号：US4391920A

公开(公告)日：1983-07-05

申请号：US283675

申请日：1981-07-15

Applicant: Wolfgang Lange

Inventor： Wolfgang Lange

IPC: A01N25/10 ,  B01J20/26 ,  B01J20/30 ,  C04B16/08 ,  C08J3/12 ,  C08J9/28 ,  C09D7/00 ,  C09D7/12 ,  C09K3/32 ,  C09K17/00 ,  C08J9/26

CPC classification number: C09D7/125 ,  A01N25/10 ,  B01J20/26 ,  C04B16/08 ,  C08J3/12 ,  C08J9/28 ,  C09D7/1291 ,  C09K17/00 ,  C09K3/32 ,  C08J2201/0444 ,  C08J2201/0543 ,  C08J2201/0546 ,  C08J2323/12 ,  C08L23/12

Abstract: The invention relates to a process producing porous powdery polymer particles. A homogeneous mixture having two components minimum, one a meltable polymer, the other fluid inert to the polymer, both forming a system having a range of complete miscibility and a miscibility gap are introduced to a bed of solid-substance particles, then cooling the mixture to below solidification of the polymer and comminuting the obtained cake-like mass. The polymer is separated then from the inert fluid and solid-like substance particles.

Abstract translation: 本发明涉及一种生产多孔粉状聚合物颗粒的方法。 将具有两个组分最小的均匀混合物，一个可熔融聚合物，另一个对聚合物惰性的流体，两者都形成具有一系列完全混溶性和可混合性间隙的体系，将其引入固体物质颗粒床中，然后冷却混合物 将聚合物固化成低聚物，粉碎得到的饼状物质。 然后将聚合物与惰性流体和固体样物质颗粒分离。

公开(公告)号：US4335193A

公开(公告)日：1982-06-15

申请号：US16176

申请日：1979-02-28

Applicant: Yoshinao Doi ,  Shigeo Kaneko ,  Takeo Hanamura ,  Osamu Fujii ,  Katsumi Yoshitake ,  Tetsuhiko Hirata ,  Yasuhiro Tanabe

Inventor： Yoshinao Doi ,  Shigeo Kaneko ,  Takeo Hanamura ,  Osamu Fujii ,  Katsumi Yoshitake ,  Tetsuhiko Hirata ,  Yasuhiro Tanabe

IPC: B01D71/06 ,  C08J9/00 ,  C08J9/26 ,  C08J9/28 ,  C25B13/08 ,  H01M2/16

CPC classification number: C08J9/0066 ,  C08J9/28 ,  C08K3/00 ,  H01M2/1653 ,  C08J2201/0543 ,  C08J2201/0546 ,  C08J2323/02

Abstract: This invention is directed to a microporous film comprising a 40 to 90 volume percent polyolefin having a number average molecular weight of 15,000 or more and a weight average molecular weight of less than 300,000 and a 10 to 60 volume percent inorganic filler and having a void space rate or porosity of 30 to 75 volume percent based on the volume of the film. The microporous film of such specific composition and structure has a desired wettability and a much reduced electrical resistance. Said resistance being as low as 0.0006 .OMEGA.dm.sup.2 /sheet. Said film has sufficient flexibility and mechanical strength to make it useful in wide variety of applications, especially as separators in batteries or electrolytical apparatuses etc. Such microporous material is prepared by: (a) blending a specified polyolefin, an inorganic filler and an organic liquid in amounts of 10 to 60 volume percent, 6 to 35 volume percent and 30 to 75 volume percent, respectively, based on the total volume of the blend, the amount of the polyolefin being 2/3 to 9 times the amount of the inorganic filler; (b) molding the blend to form a film; and (c) extracting said organic liquid from the molded film.

Abstract translation: 本发明涉及一种微孔薄膜，其包含数均分子量为15,000以上且重均分子量小于300,000的40〜90体积％的聚烯烃和10〜60体积％的无机填料，并具有空隙空间 速率或孔隙率基于膜的体积为30至75体积％。 这种具体组成和结构的微孔膜具有所需的润湿性和大大降低的电阻。 所述电阻低至0.0006欧姆dm2 /片。 所述膜具有足够的柔韧性和机械强度，使其可用于各种应用中，特别是作为电池或电解装置等中的分离器。这种微孔材料通过以下制备：（a）将指定的聚烯烃，无机填料和有机液体 分别为10至60体积％，6至35体积％和30至75体积％，基于共混物的总体积，聚烯烃的量为无机填料量的2/3至9倍 ; （b）将共混物模制成膜; 和（c）从模塑膜中提取所述有机液体。

公开(公告)号：US4247498A

公开(公告)日：1981-01-27

申请号：US963628

申请日：1978-11-24

Applicant: Anthony J. Castro

Inventor： Anthony J. Castro

IPC: A01N25/10 ,  B41N7/00 ,  C08J9/28 ,  C09K3/14 ,  B29D27/04

CPC classification number: C09K3/149 ,  A01N25/10 ,  B41N7/00 ,  C08J9/28 ,  B41N2207/02 ,  B41N2207/14 ,  C08J2201/052 ,  C08J2201/0543 ,  C08J2201/0546

Abstract: Novel microporous polymers in forms ranging from films to blocks and intricate shapes from synthetic thermoplastic polymers, such as, olefinic, condensation, and oxidation polymers, are disclosed. In one embodiment the microporous polymers are characterized by a relatively homogeneous, three-dimensional cellular structure having cells connected by pores of smaller dimension. Also disclosed is a process for making microporous polymers from such thermoplastic polymers by heating a mixture of the polymer and a compatible liquid to form a homogeneous solution, cooling said solution under non-equilibrium thermodynamic conditions to initiate liquid-liquid phase separation, and continuing said cooling until the mixture achieves substantial handling strength. Also disclosed are microporous polymer products which contain relatively large amounts of functionally useful liquids and behave as solids.

Abstract translation: 公开了从合成热塑性聚合物（例如烯烃，缩合和氧化聚合物）的薄膜到块状和复杂形状的新型微孔聚合物。 在一个实施方案中，微孔聚合物的特征在于具有通过较小尺寸的孔连接的细胞的相对均匀的三维细胞结构。 还公开了一种通过加热聚合物和相容液体的混合物以形成均匀溶液从这种热塑性聚合物制备微孔聚合物的方法，在非平衡热力学条件下冷却所述溶液以引发液 - 液相分离，并且继续所述 冷却直到混合物达到显着的处理强度。 还公开了含有相对大量功能上有用的液体并表现为固体的微孔聚合物产品。

公开(公告)号：US4002177A

公开(公告)日：1977-01-11

申请号：US555988

申请日：1975-03-06

Applicant: Norman B. Rainer ,  Peter Allen Wilson

Inventor： Norman B. Rainer ,  Peter Allen Wilson

IPC: A24D3/08 ,  C08J3/02 ,  C08J9/28 ,  A24B15/00

CPC classification number: C08J3/02 ,  A24D3/08 ,  C08J9/28 ,  C08J2201/0543 ,  C08J2201/0546 ,  C08J2325/04

Abstract: Microporous styrene polymers are provided having randomly interconnected open network of irregularly shaped pores whose walls consist of cohered spherical particles of the polymer. These microporous styrene polymers are produced by mixing styrene polymer latex with a water-soluble ether, casting, molding, or impregnating the resulting mixture into a fibrous material, heating same to a temperature of from about 80.degree. C to about 120.degree. C and removing the ether.

Abstract translation: 提供微孔苯乙烯聚合物，其具有随机互连的不规则形状的孔的开放网络，其壁由聚合物的聚焦球形颗粒组成。 这些微孔苯乙烯聚合物通过将苯乙烯聚合物胶乳与水溶性醚混合，将所得混合物浇铸，模塑或浸渍成纤维材料，将其加热至约80℃至约120℃的温度并除去 以太。

公开(公告)号：US3856914A

公开(公告)日：1974-12-24

申请号：US39397773

申请日：1973-09-04

Applicant: KINYOSHA KK

Inventor： MAEDA M ,  ONUKI A ,  KUSANO K

IPC: C08J9/28 ,  B29D27/00

CPC classification number: C08J9/28 ,  C08J2201/0543 ,  C08J2201/0546

Abstract: A method of making a porous polymeric material comprising a plurality of interconnected cells, comprising mixing together 100 parts of a liquid prepolymer, at least 40 parts of an inert organic liquid and 1.5 to 15 parts of an emulsifier to form a stable emulsion of dispersed liquid prepolymer in the organic liquid, heating the emulsion to at least 90* C in the presence of a cross-linking agent to form a porous polymeric material with a plurality of interconnected cells filled with the organic liquid, and extracting the organic liquid from the cells.

Abstract translation: 一种制备包含多个互连电池的多孔聚合材料的方法，包括将100份液体预聚物，至少40份惰性有机液体和1.5至15份乳化剂混合在一起以形成分散液体的稳定乳液 预聚物在有机液体中，在交联剂存在下将乳液加热到至少90℃，以形成多孔聚合物材料，其中多个互相连接的细胞填充有机液体，并从细胞中提取有机液体 。

公开(公告)号：US20180223067A1

公开(公告)日：2018-08-09

申请号：US15751718

申请日：2016-08-05

Applicant: KYOTO UNIVERSITY ,  EMAUS KYOTO, INC. ,  KOSEN NATIONAL INSTITUTE OF TECHNOLOGY

Inventor： Norio ISHIZUKA ,  Kyoko KONISHI ,  Toshikazu ODA ,  Yoshinobu TSUJII ,  Keita SAKAKIBARA ,  Takaya SATO

IPC: C08J9/28 ,  C08G59/50 ,  C08G59/32 ,  C08F22/20 ,  C08F293/00 ,  C01B33/155

CPC classification number: C08J9/286 ,  C01B33/155 ,  C01P2002/32 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/34 ,  C01P2004/60 ,  C01P2004/61 ,  C01P2004/62 ,  C08F22/20 ,  C08F293/00 ,  C08G59/18 ,  C08G59/3227 ,  C08G59/3245 ,  C08G59/5026 ,  C08J9/0061 ,  C08J2201/026 ,  C08J2201/0543 ,  C08J2205/05 ,  C08J2335/02 ,  C08J2363/00 ,  C08J2453/00 ,  C08L63/00 ,  C08L63/06 ,  C08L71/02

Abstract: The present invention provides porous particles uniform in shape and having through holes that are not closed. The porous particles according to the present invention are porous particles having a substantially spherical shape. Each of the porous particles has an interconnected pore structure in which through holes provided inside the porous particle communicate with each other, and ends of the through holes are open toward an outside of the porous particle.

公开(公告)号：US20170137593A1

公开(公告)日：2017-05-18

申请号：US15417752

申请日：2017-01-27

Applicant: NeXolve Corporation

Inventor： David L. Rodman ,  Garrett D. Poe ,  Brandon S. Farmer ,  Joseph C. Smith

IPC: C08J9/28

CPC classification number: C08J9/286 ,  C08J9/28 ,  C08J2201/0482 ,  C08J2201/0502 ,  C08J2201/0543 ,  C08J2205/026 ,  C08J2379/08

Abstract: The present disclosure provides a method of producing a aerogel comprising of reacting first monomer with a second monomer in a reaction solvent to form a composition comprising a precursor polymer; forming a gel; conducting a solvent exchange process on the gel such that the resulting gel comprises an exchange solvent that has a freezing point; cooling the gel to a temperature below the freezing point of the exchange solvent; and subjecting the cooled gel to vacuum conditions to obtain the aerogel.

公开(公告)号：US20150057380A1

公开(公告)日：2015-02-26

申请号：US14357142

申请日：2012-11-07

Applicant: KANEKA CORPORATION

Inventor： Hiroshi Uyama ,  Wataru Mio ,  Yusuke Hirai ,  Kazuhiro Fuke

IPC: C08J9/28 ,  C08J9/36

CPC classification number: C08J9/28 ,  B01J20/264 ,  B01J20/265 ,  B01J20/28085 ,  B01J20/28095 ,  B01J2220/58 ,  C08F8/32 ,  C08F214/06 ,  C08F214/08 ,  C08F220/44 ,  C08F2810/50 ,  C08J9/36 ,  C08J2201/0522 ,  C08J2201/0543 ,  C08J2205/044 ,  C08J2205/05 ,  C08J2327/06 ,  C08J2327/08 ,  C08J2333/20

Abstract: A vinyl chloride-based copolymer porous body contains a vinyl chloride-based copolymer as the main component. The vinyl chloride-based copolymer porous body has continuous pores having a pore size of 0.1 to 40 μm, the pores have a skeletal diameter of 0.1 to 20 μm, and the vinyl chloride-based copolymer has a thickness of 1 mm or more. Such a vinyl chloride-based copolymer porous body can be produced by a production method including the steps of: heating and dissolving the vinyl chloride-based copolymer in a solvent to obtain a vinyl chloride-based copolymer solution; cooling the vinyl chloride-based copolymer solution to obtain a precipitated product; and separating and drying the product to obtain a porous body containing the vinyl chloride-based copolymer as the main component.

Abstract translation: 氯乙烯系共聚物多孔体含有氯乙烯系共聚物作为主要成分。 氯乙烯类共聚物多孔体具有孔径为0.1〜40μm的连续孔，孔的骨架直径为0.1〜20μm，氯乙烯系共聚物的厚度为1mm以上。 这样的氯乙烯类共聚物多孔体可以通过以下的制造方法制造，包括以下步骤：将氯乙烯系共聚物加热溶解在溶剂中，得到氯乙烯类共聚物溶液; 冷却氯乙烯基共聚物溶液，得到沉淀产物; 并分离和干燥该产物以获得含有氯乙烯基共聚物作为主要成分的多孔体。