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公开(公告)号：US20090171129A1
公开(公告)日：2009-07-02
申请号：US12342992
申请日：2008-12-23
Applicant: William A. Evanko , Aharon M. Eyal , David A. Glassner , Fudu Miao , Aristos A. Aristidou , Kent Evans , Patrick R. Gruber , Andrew C. Hawkins
Inventor： William A. Evanko , Aharon M. Eyal , David A. Glassner , Fudu Miao , Aristos A. Aristidou , Kent Evans , Patrick R. Gruber , Andrew C. Hawkins
CPC classification number: C12M43/00 , C07C29/80 , C07C29/86 , C12C11/11 , C12M45/20 , C12P7/04 , C12P7/16 , Y02E50/10 , Y02E50/17 , Y10T29/49826 , C07C31/12
Abstract: This invention is directed to methods for recovery of C3-C6 alcohols from dilute aqueous solutions, such as fermentation broths. Such methods provide improved volumetric productivity for the fermentation and allows recovery of the alcohol. Such methods also allow for reduced energy use in the production and drying of spent fermentation broth due to increased effective concentration of the alcohol product by the simultaneous fermentation and recovery process which increases the quantity of alcohol produced and recovered per quantity of fermentation broth dried. Thus, the invention allows for production and recovery of C3-C6 alcohols at low capital and reduced operating costs.
Abstract translation: 本发明涉及从稀释的水溶液如发酵液中回收C3-C6醇的方法。 这样的方法提供了用于发酵的改进的体积生产率并允许酒精回收。 由于通过同时发酵和回收过程增加了醇产物的有效浓度，所以这种方法还允许在用过的发酵液的生产和干燥中减少能量消耗，这增加了每一批发酵液干燥产生和回收的醇的量。 因此，本发明允许以低资本生产和回收C3-C6醇，降低运行成本。
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22.发明授权Melt-stable lactide polymer nonwoven fabric and process for manufacture thereof 有权熔融稳定丙交酯聚合物无纺布及其制造方法公开(公告)号：US06355772B1
公开(公告)日：2002-03-12
申请号：US09568188
申请日：2000-05-09
Applicant: Patrick R. Gruber , Jeffrey J. Kolstad , Christopher M. Ryan , Robin S. Eichen Conn , Eric S. Hall
Inventor： Patrick R. Gruber , Jeffrey J. Kolstad , Christopher M. Ryan , Robin S. Eichen Conn , Eric S. Hall
IPC: C08G6308
CPC classification number: C08J5/18 , A61L15/26 , A61L31/06 , C08G63/08 , C08G63/90 , C08G2230/00 , C08J2367/04 , C08L67/04 , C09D167/04 , D01F6/625 , D04H1/435 , D04H1/4382 , D21H19/28 , D21H19/62 , Y10T428/31786 , Y10T428/31808 , Y10T442/60 , Y10T442/622 , Y10T442/637 , Y10T442/642 , Y10T442/68 , A61L15/62 , C08L2666/02 , A61L31/148 , A61B46/00
Abstract: A nonwoven fabric comprised of a lactide polymer. The lactide polymer comprises a plurality of poly(lactide) polymer chains, residual lactide in concentration of less than about 2 percent and water in concentration of less than about 2000 parts-per-million. A process for manufacturing a nonwoven fabric with the lactide polymer composition is also disclosed.
Abstract translation: 由丙交酯聚合物构成的非织造布。 丙交酯聚合物包含多个聚（丙交酯）聚合物链，浓度小于约2％的残余丙交酯和浓度小于约2000ppm的水。 还公开了用丙交酯聚合物组合物制造非织造织物的方法。
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公开(公告)号：US6111060A
公开(公告)日：2000-08-29
申请号：US2461
申请日：1998-01-02
Applicant: Patrick R. Gruber , Jeffrey J. Kolstad , Christopher M. Ryan , Robin S. Eichen Conn , Eric S. Hall
Inventor： Patrick R. Gruber , Jeffrey J. Kolstad , Christopher M. Ryan , Robin S. Eichen Conn , Eric S. Hall
IPC: A61L15/26 , A61L31/06 , C08G63/08 , C08G63/90 , C08J5/18 , C08K5/1575 , C08L67/00 , C08L67/04 , C09D167/04 , D01F6/62 , D01F6/84 , D01F6/92 , D03D15/00 , D04H1/42 , D21H19/28 , D21H19/62 , D03D3/00
CPC classification number: C08J5/18 , A61L15/26 , A61L31/06 , C08G63/08 , C08G63/90 , C08L67/04 , C09D167/04 , D01F6/625 , D04H1/435 , D04H1/4382 , D21H19/28 , D21H19/62 , C08G2230/00 , C08J2367/04 , Y10T428/31786 , Y10T428/31808 , Y10T442/60 , Y10T442/622 , Y10T442/637 , Y10T442/642 , Y10T442/68
Abstract: A nonwoven fabric comprised of a lactide polymer. The lactide polymer comprises a plurality of poly(lactide) polymer chains, residual lactide in concentration of less than about 2 percent and water in concentration of less than about 2000 parts-per-million. A process for manufacturing a nonwoven fabric with the lactide polymer composition is also disclosed.
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24.发明授权Viscosity-modified lactide polymer composition and process for manufacture thereof 失效粘度改性丙交酯聚合物组合物及其制造方法
公开(公告)号：US5594095A
公开(公告)日：1997-01-14
申请号：US279732
申请日：1994-07-27
Applicant: Patrick R. Gruber , Jeffrey J. Kolstad , David R. Witzke , Mark H. Hartmann , Andrea L. Brosch
Inventor： Patrick R. Gruber , Jeffrey J. Kolstad , David R. Witzke , Mark H. Hartmann , Andrea L. Brosch
IPC: A61F13/15 , A61F13/49 , A61F13/551 , B29C45/00 , B29C49/00 , B29C51/00 , B29K67/00 , C08F290/00 , C08F299/04 , C08G18/42 , C08G59/40 , C08G63/08 , C08G63/78 , C08G63/91 , C08J3/24 , C08J5/18 , C08L67/04 , D04H1/42 , D21H19/24
CPC classification number: C08G63/08 , Y10T428/31786 , Y10T428/3179 , Y10T442/60
Abstract: A composition comprising a polylactide polymer with improved extensional viscosity and methods of making the same are disclosed. The polylactide polymer composition is prepared by providing in the composition polylactide polymer molecules which have been modified, relative to linear non-substituted polylactide, to provide increased molecular interaction among polylactide backbone chains in the composition. The preferred polylactide polymer composition has a number average molecular weight of at least about 10,000 (preferably at least 50,000) and a polydispersity of at least about 2.5. In addition, the polylactide polymer composition should have a neck-in ratio of less than about 0.8.
Abstract translation: 公开了包含具有改进的拉伸粘度的聚丙交酯聚合物的组合物及其制备方法。 聚丙交酯聚合物组合物通过在组合物中提供相对于线性未取代的聚交酯改性的聚丙交酯聚合物分子来制备，以在组合物中的聚交酯骨架链之间提供增加的分子相互作用。 优选的聚丙交酯聚合物组合物具有至少约10,000（优选至少50,000）的数均分子量和至多约2.5的多分散性。 另外，聚丙交酯聚合物组合物的颈缩比应小于约0.8。
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25.发明授权Continuous process for manufacture of lactide polymers with controlled optical purity 失效用于制造具有受控光学纯度的丙交酯聚合物的连续方法
公开(公告)号：US5258488A
公开(公告)日：1993-11-02
申请号：US926901
申请日：1992-08-07
Applicant: Patrick R. Gruber , Eric S. Hall , Jeffrey J. Kolstad , Matthew L. Iwen , Richard D. Benson , Ronald L. Borchardt
Inventor： Patrick R. Gruber , Eric S. Hall , Jeffrey J. Kolstad , Matthew L. Iwen , Richard D. Benson , Ronald L. Borchardt
IPC: C08G63/06 , C08G63/08 , C07D319/12
Abstract: A process for the continuous production of polylactide polymers from lactic acid which incorporates removal of water or a solvent carrier to concentrate the lactic acid feed followed by polymerization to a low-molecular-weight prepolymer. This prepolymer is fed to a reactor in which a catalyst is added to facilitate generation of lactide, the depolymerization product of polylactic acid. The lactide generated is continuously fed to a distillation system as a liquid or vapor wherein water and other impurities are removed. The resultant purified liquid lactide is fed directly to a polymerization process.
Abstract translation: 从乳酸连续生产聚丙交酯聚合物的方法，该方法结合去除水或溶剂载体以将乳酸进料浓缩，然后聚合成低分子量预聚物。 将该预聚物加入反应器中，在该反应器中加入催化剂以促进产生丙交酯，即聚乳酸的解聚产物。 生成的丙交酯以其中除去水和其它杂质的液体或蒸气连续供入蒸馏系统。 将所得纯化液体丙交酯直接进料至聚合过程。
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Patent Agency Ranking
公开(公告)号：US20120107891A1
公开(公告)日：2012-05-03
申请号：US13344464
申请日：2012-01-05
Applicant: William A. Evanko , Aharon M. Eyal , David A. Glassner , Fudu Miao , Aristos A. Aristidou , Kent Evans , Patrick R. Gruber , Andrew C. Hawkins
Inventor： William A. Evanko , Aharon M. Eyal , David A. Glassner , Fudu Miao , Aristos A. Aristidou , Kent Evans , Patrick R. Gruber , Andrew C. Hawkins
IPC: C12P7/16
CPC classification number: C12M43/00 , C07C29/80 , C07C29/86 , C12C11/11 , C12M45/20 , C12P7/04 , C12P7/16 , Y02E50/10 , Y02E50/17 , Y10T29/49826 , C07C31/12
Abstract: This invention is directed to methods for recovery of C3-C6 alcohols from dilute aqueous solutions, such as fermentation broths. Such methods provide improved volumetric productivity for the fermentation and allows recovery of the alcohol. Such methods also allow for reduced energy use in the production and drying of spent fermentation broth due to increased effective concentration of the alcohol product by the simultaneous fermentation and recovery process which increases the quantity of alcohol produced and recovered per quantity of fermentation broth dried. Thus, the invention allows for production and recovery of C3-C6 alcohols at low capital and reduced operating costs.
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公开(公告)号：US20120107890A1
公开(公告)日：2012-05-03
申请号：US13344460
申请日：2012-01-05
Applicant: William A. Evanko , Aharon M. Eyal , David A. Glassner , Fudu Miao , Aristos A. Aristidou , Kent Evans , Patrick R. Gruber , Andrew C. Hawkins
Inventor： William A. Evanko , Aharon M. Eyal , David A. Glassner , Fudu Miao , Aristos A. Aristidou , Kent Evans , Patrick R. Gruber , Andrew C. Hawkins
IPC: C12P7/16
CPC classification number: C12M43/00 , C07C29/80 , C07C29/86 , C12C11/11 , C12M45/20 , C12P7/04 , C12P7/16 , Y02E50/10 , Y02E50/17 , Y10T29/49826 , C07C31/12
Abstract: This invention is directed to methods for recovery of C3-C6 alcohols from dilute aqueous solutions, such as fermentation broths. Such methods provide improved volumetric productivity for the fermentation and allows recovery of the alcohol. Such methods also allow for reduced energy use in the production and drying of spent fermentation broth due to increased effective concentration of the alcohol product by the simultaneous fermentation and recovery process which increases the quantity of alcohol produced and recovered per quantity of fermentation broth dried. Thus, the invention allows for production and recovery of C3-C6 alcohols at low capital and reduced operating costs.
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28.发明申请METHODS FOR THE ECONOMICAL PRODUCTION OF BIOFUEL PRECURSOR THAT IS ALSO A BIOFUEL FROM BIOMASS 审中-公开经济生产生物燃料前体的方法也是生物质的生物燃料公开(公告)号：US20090215137A1
公开(公告)日：2009-08-27
申请号：US12263442
申请日：2008-10-31
Applicant: Andrew C. Hawkins , David A. Glassner , Thomas Buelter , James Wade , Peter Meinhold , Matthew W. Peters , Patrick R. Gruber , William A. Evanko , Aristos A. Aristidou
Inventor： Andrew C. Hawkins , David A. Glassner , Thomas Buelter , James Wade , Peter Meinhold , Matthew W. Peters , Patrick R. Gruber , William A. Evanko , Aristos A. Aristidou
CPC classification number: C12P7/16 , C07K14/245 , C10G1/04 , C10G2300/1014 , C10G2300/4025 , C10L1/02 , C10L2200/0469 , C10L2290/26 , C12N9/0006 , C12N9/0036 , C12N9/2414 , C12N9/2417 , C12N9/2428 , C12N9/2434 , C12P7/04 , C12P7/24 , C12P7/62 , C12Y106/01002 , C12Y302/01001 , C12Y302/01003 , Y02E50/10 , Y02E50/16 , Y02P30/20
Abstract: Methods for producing a biofuel precursor are provided. Also provided are biocatalysts that convert a feedstock to a biofuel precursor.
Abstract translation: 提供生产生物燃料前体的方法。 还提供了将原料转化为生物燃料前体的生物催化剂。
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公开(公告)号：US06320077B1
公开(公告)日：2001-11-20
申请号：US09132720
申请日：1998-08-12
Applicant: Aharon M. Eyal , John N. Starr , Rod Fisher , Betty Hazan , Riki Canari , David R. Witzke , Patrick R. Gruber , Jeffrey J. Kolstad
Inventor： Aharon M. Eyal , John N. Starr , Rod Fisher , Betty Hazan , Riki Canari , David R. Witzke , Patrick R. Gruber , Jeffrey J. Kolstad
IPC: C07C5908
Abstract: The techniques for processing lactic acid/lactate salt mixtures are provided. Preferred mixtures for processing are obtained from fermentation broths, preferably from fermentation processes conducted at a pH of 4.8 or lower. The techniques generally concern the provision of separated lactic acid and lactate streams, from the mixtures. Preferred techniques of separation and processing of each of the streams are provided.
Abstract translation: 提供了乳酸/乳酸盐混合物的加工技术。 优选的用于加工的混合物从发酵液中获得，优选在pH4.8或更低的条件下进行发酵。 这些技术通常涉及从混合物中提供分离的乳酸和乳酸盐流。 提供了每种流的分离和处理的优选技术。
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30.发明授权Compostable multilayer structures, methods for manufacture, and articles prepared therefrom 失效可堆肥多层结构，制造方法和由其制备的制品
公开(公告)号：US5849374A
公开(公告)日：1998-12-15
申请号：US535706
申请日：1995-09-28
Applicant: Patrick R. Gruber , Jeffrey John Kolstad , James Lunt , Christopher M. Ryan , Ali Zakareya El-Afandi , James Nangeroni , Nancy Uzelac Buehler , Mark Hartmann , Jed Richard Randall , Andrea Lee Brosch
Inventor： Patrick R. Gruber , Jeffrey John Kolstad , James Lunt , Christopher M. Ryan , Ali Zakareya El-Afandi , James Nangeroni , Nancy Uzelac Buehler , Mark Hartmann , Jed Richard Randall , Andrea Lee Brosch
CPC classification number: B32B27/08 , B32B27/22 , B32B27/306 , B32B27/32 , B32B27/36 , B32B2250/24 , B32B2250/244 , B32B2307/7163 , B32B2367/00 , Y10T428/1303 , Y10T428/1307 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383 , Y10T428/24942 , Y10T428/254 , Y10T428/265 , Y10T428/269 , Y10T428/31786 , Y10T428/3179
Abstract: A compostable multilayer structure in the form of a film, sheet, laminate, and the like, which comprises a core layer having a first surface and a second surface, a first blocking reducing layer covering the first surface of the core layer, and a second blocking reducing layer covering the second surface of the core layer. The core layer contains a lactic acid residue-containing polymer and has a glass transition temperature (T.sub.g) below about 20.degree. C. The first and second blocking reducing layers include a polymer composition of a hydrolyzable polymer and have a T.sub.g above about 50.degree. C. The multilayer structure can be used for preparing bags and wrappers.
Abstract translation: 包括具有第一表面和第二表面的芯层，覆盖芯层的第一表面的第一阻挡降低层的第一和第二封装层的形式的可堆叠多层结构体， 覆盖芯层的第二表面的阻挡降低层。 核心层含有含乳酸残基的聚合物，玻璃化转变温度（Tg）低于约20℃。第一和第二封闭还原层包括可水解聚合物的聚合物组合物，其Tg高于约50℃ 该多层结构可用于制备袋和包装纸。
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